Citation: JI Qin, CHEN Li-Zhuang. Syntheses, Characterization and Fluorescence Properties Analysis of Two Lanthanide Coordination Polymers Based on Axial Chirality Ligand 2, 2'-Dinitro-4, 4'-biphenyldicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(5): 874-880. doi: 10.11862/CJIC.2017.099 shu

Syntheses, Characterization and Fluorescence Properties Analysis of Two Lanthanide Coordination Polymers Based on Axial Chirality Ligand 2, 2'-Dinitro-4, 4'-biphenyldicarboxylic Acid

JI Qin ,
CHEN Li-Zhuang ^*,,

School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China

Corresponding author: CHEN Li-Zhuang, clz1977@sina.com
Received Date: 14 November 2016
Revised Date: 9 March 2017

Figures(7)

Two lanthanide coordination polymers, La (nbpdc)(phen)(FA) (1), Eu (nbpdc)(phen)(FA) (2) (FA=formic acid ion) based on bridging ligand 2, 2'-dinitro-4, 4'-biphenyldicarboxylic acid (H₂nbpdc) and 1, 10-Phenanthroline monohydrate (phen), have been synthesized by the hydrothermal method and characterized by IR, single-crystal X-ray structure analysis, thermogravimetric analysis, luminescent properties, circular dichroism (CD) analysis and dielectric properties. Complexes 1 and 2 exhibited a rare three-interlude 3D structure with the same topology structure of (4⁴·6²). In addition, the two complexes exhibit fluorescent emissions in the solid state at room temperature. Fluorescent analysis of complexes 1 and 2 showed an intense emission band at 606 nm (λ_ex=495 nm) and 615.5 nm (λ_ex=395.5 nm), respectively. Moreover, the circular dichroism analysis of complexes 1 and 2 was measured with chirality.
- coordination polymer,
- hydrothermal condition,
- fluorescence,
- chirality
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