Citation: WANG Ping-Ping, CHEN Dan-Ping, WANG Shu-Hua, CHEN Chao. Chiral Postsynthetic Modification of Cr-MIL-101-NH₂[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(5): 817-822. doi: 10.11862/CJIC.2017.095 shu

Chiral Postsynthetic Modification of Cr-MIL-101-NH₂

WANG Ping-Ping ^1,2,*,, ,
CHEN Dan-Ping ² ,
WANG Shu-Hua ² ,
CHEN Chao ^2,*,,

1.
Zunyi Medical College, Zunyi, Guizhou 563000, China
2.
Institute of Applied Chemistry, Nanchang University, Nanchang 330031, China

Corresponding author: WANG Ping-Ping, chouchongbaobao@163.com CHEN Chao, chaochen@ncu.edu.cn
Received Date: 28 December 2016
Revised Date: 22 March 2017

Figures(10)

By postsynthetic modification method (PSM), chiral metal-organic frameworks (MOFs) were designed and synthesized. The L-proline derivative (Boc-L-ProCl) was anchored on the pore of Cr-MIL-101-NH₂ by PSM method to gain a chiral MOFs (Cr-MIL-101-PaB₂). ¹H NMR spectra confirmed the yield up to 64% by twice process of PSM, and solid circular dichroism (CD) result showed that Cr-MIL-101-PaB₂ was a chiral compound. Their structures were characterized by infrared spectroscopy (IR), nitrogen desorption-adsorption, thermogravimetry (TGA), powder X-ray diffraction (PXRD). The experimental results confirmed that synthesized chiral MOFs by PSM method for the needed purpose can avoid the self-assembly uncertainty of MOFs.
- MOFs,
- PSM,
- Cr-MIL-101-NH₂,
- chiral
1. [1]
  Zhang J P, Zhang Y B, Lin J B, et al. Chem. Rev., 2012, 112(2):1001-1033 doi: 10.1021/cr200139g
2. [2]
  Férey G. Chem. Soc. Rev., 2008, 37(1):191-214 doi: 10.1039/B618320B
3. [3]
  Ma L Q, Abneya C, Lin W B. Chem. Soc. Rev., 2009, 38(1):1248-1256
4. [4]
  An H Y, Wang E B, Xiao D R, et al. Angew. Chem., 2006, 118:918-922 doi: 10.1002/(ISSN)1521-3757
5. [5]
  Liu T F, Liu Y, Xuan W M, et al. Angew. Chem. Int. Ed., 2010, 49:4121-4124 doi: 10.1002/anie.201000416
6. [6]
  Gao Q, Jang F L, Wu M Y, et al. Cryst. Growth Des., 2010, 10(1):184-190 doi: 10.1021/cg9008366
7. [7]
  Chen B L, Eddaoudi M. Science, 2001, 291(9):1021-1023 doi: 10.1126/science.1056598
8. [8]
  Liu Y, Xi X B, Ye C C, et al. Angew. Chem. Int. Ed., 2014, 53:13821-13825 doi: 10.1002/anie.201408896
9. [9]
  Lun D, Waterhouse G, et al. J. Am. Chem. Soc., 2011, 133:5806-5809 doi: 10.1021/ja202223d
10. [10]
  Peng Y W, Gong T F, Zhang K, et al. Nat. Commun., 2014, 5:4406
11. [11]
  Mo K, Yang Y H, Cui Y. J. Am. Chem. Soc., 2014, 136:1746-1749 doi: 10.1021/ja411887c
12. [12]
  Prior T, Rosseinsky M. Inorg. Chem., 2003, 42(5):1564-1575 doi: 10.1021/ic025775i
13. [13]
  Tian G, Zhu G S, Yang X Y. Chem. Commun., 2005:1396-1398
14. [14]
  Tan R, Li C Y, Luo J Q, et al. J. Catal., 2013, 298:138-147 doi: 10.1016/j.jcat.2012.11.024
15. [15]
  Zhu W T, Wu X, He C, et al. Tetrahedron, 2013, 69:1047-10481
16. [16]
  Fotaras S, Kokotos C, Kototos G. Org. Biomol. Chem., 2012, 10:5613-5619 doi: 10.1039/c2ob25693b
17. [17]
  He L, Tang Z, Cun L F, et al. Tetrahedron, 2006, 62:346-351 doi: 10.1016/j.tet.2005.09.061
18. [18]
  Chen X H, Yu J, Gong L Z. Chem. Comm., 2010, 46:6437-6448 doi: 10.1039/c0cc00754d
19. [19]
  GAO Xin-Qin, WANG Fu-Dong, YANG Jin-Zong. Dyestuff Industy, 1996, 33(4):22-24
20. [20]
  Wu X, He C, Wu X, et al. Chem. Commun., 2011, 47:8415-8417 doi: 10.1039/c1cc11698c
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Chiral Postsynthetic Modification of Cr-MIL-101-NH2

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通讯作者: 陈斌, bchen63@163.com

Chiral Postsynthetic Modification of Cr-MIL-101-NH₂