Citation: LI Shi-Long, LÜ Chao, MIN Xin, FANG Ming-Hao, HUANG Zhao-Hui, LIU Yan-Gai. Preparation and Luminescence Properties of La₇O₆(BO₃)(PO₄)₂: Tb³⁺/Eu³⁺ Phosphors[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(5): 761-768. doi: 10.11862/CJIC.2017.086 shu

Preparation and Luminescence Properties of La₇O₆(BO₃)(PO₄)₂: Tb³⁺/Eu³⁺ Phosphors

Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences (Beijing), Beijing 100083, China

Corresponding author: MIN Xin, minx@cugb.edu.cn
Received Date: 22 December 2016
Revised Date: 13 March 2017

Figures(10)

La₇O₆(BO₃)(PO₄)₂:Tb³⁺ and La₇O₆(BO₃)(PO₄)₂:Eu³⁺ phosphors were prepared by a high-temperature solid state reaction, and the phase behavior, crystal structure, luminescence properties and thermal stability were investigated. The La₇O₆(BO₃)(PO₄)₂:Eu³⁺ phosphors emitted a red light under the ultraviolet excitation. The emission maximum was at 616 nm, corresponding to the ⁵D₀-⁷F₂ transition of Eu³⁺. The concentration quenching pheno-menon was observed when the doping concentration of Eu³⁺ ion was beyond 0.08. The corresponding CIE coordinates were calculated to be (0.610 2, 0.382 3). The La₇O₆(BO₃)(PO₄)₂:Tb³⁺ phosphors emitted a green light under the ultraviolet excitation. The emission maximum was at 544 nm, corresponding to the ⁵D₄-⁷F₅ transition of Tb³⁺. Concentration quenching phenomenon was observed when the concentration of Tb³⁺ ion was beyond 0.15, and its CIE coordinates are calculated to be (0.317 7, 0.535 2). Based on the analysis of temperature-dependent emission spectra of La₇O₆(BO₃)(PO₄)₂:Tb³⁺ and La₇O₆(BO₃)(PO₄)₂:Eu³⁺ phosphors, it can be found that both phosphors possess good thermal stability.
- phosphors,
- photoluminescence properties,
- Eu³⁺,
- Tb³⁺,
- La₇O₆(BO₃)(PO₄)₂
1. [1]
  Wakefield G, Holland E, Dobson P J, et al. Adv. Mater., 2001, 13:1557-1560 doi: 10.1002/1521-4095(200110)13:20<1557::AID-ADMA1557>3.0.CO;2-W
2. [2]
  Min X, Fang M H, Huang Z H, et al. Opt. Mater., 2014, 37:110-114 doi: 10.1016/j.optmat.2014.05.008
3. [3]
  Ji H P, Wang L, Molokeev M S, et al. J. Mater. Chem. C, 2016, 4:2359-2366 doi: 10.1039/C6TC00089D
4. [4]
  Pasiński D, Zych E, Sokolnicki J. J. Alloys Compd., 2015, 653:636-642 doi: 10.1016/j.jallcom.2015.08.277
5. [5]
  Huang H T, Tsai C C, Huang Y P. J. Disp. Technol., 2010, 6:128-134
6. [6]
  Li G, Zhang Y, Geng D, et al. ACS Appl. Mater. Interfaces, 2011, 4:296-305
7. [7]
  TIAN Zhen-Yu. China Light Lighting, 2012, 5:21-23 doi: 10.3969/j.issn.1002-6150.2012.02.005
8. [8]
  Huang C H, Chen T M. J. Phys. Chem. C, 2011, 115:2349-2355 doi: 10.1021/jp107856d
9. [9]
  Hu X Y, Fan J, Li T, et al. Chin. Sci. Bull., 2007, 52:444-449 doi: 10.1007/s11434-007-0094-3
10. [10]
  Li K, Liu X, Zhang Y, et al. Inorg. Chem., 2014, 54:323-333
11. [11]
  Xiao X, Yan B. J. Alloys Compd., 2008, 456:447-451 doi: 10.1016/j.jallcom.2007.02.098
12. [12]
  Kang J G, Hong J P, Yoon S K, et al. J. Alloys Compd., 2002, 339:248-254 doi: 10.1016/S0925-8388(01)02010-2
13. [13]
  CHU Ben-Li, LIU Xing-Ren, WANG Xiao-Jun. Chin. J. Lumin., 2001, 22(3):263-267
14. [14]
  SHI Chun-Ting. Thesis for the Master of Ningxia University. 2006.
15. [15]
  Shi Y, Liang J, Zhang H, et al. J. Solid State Chem., 1997, 129:45-52 doi: 10.1006/jssc.1996.7227
16. [16]
  Min X, Huang Z H, Fang M H, et al. Inorg. Chem., 2014, 53:6060-6065 doi: 10.1021/ic500412r
17. [17]
  Zhu H K, Fang M H, Huang Z H, et al. J. Lumin., 2016, 172:180-184 doi: 10.1016/j.jlumin.2015.12.021
18. [18]
  Min X, Fang M H, Huang Z H, et al. Ceram. Int., 2015, 41:4238-4242 doi: 10.1016/j.ceramint.2014.11.070
19. [19]
  WANG Li. Thesis for the Master of Inner Mongolia Normal University. 2014.
20. [20]
  LI Dan, LÜShao-Zhe, WANG Hai-Ning, et al. Chin. J. Lumin., 2001, 22(3):227-231
21. [21]
  WU Yu-Xiao, SHAN Fa-Xian, ZHANG Guo-Chun, et al. J. Synth. Cryst., 2015, 44(10):2692-2695
1. [1]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
2. [2]
  Gregorio F. Ortiz . Some facets of the Mg/Na₃VCr_0.5Fe_0.5(PO₄)₃ battery. Chinese Chemical Letters, 2024, 35(10): 109391-. doi: 10.1016/j.cclet.2023.109391
3. [3]
  Tong Su , Yue Wang , Qizhen Zhu , Mengyao Xu , Ning Qiao , Bin Xu . Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage. Chinese Chemical Letters, 2024, 35(8): 109191-. doi: 10.1016/j.cclet.2023.109191
4. [4]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
5. [5]
  Dong-Xue Jiao , Hui-Li Zhang , Chao He , Si-Yu Chen , Ke Wang , Xiao-Han Zhang , Li Wei , Qi Wei . Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units. Chinese Journal of Structural Chemistry, 2024, 43(6): 100304-100304. doi: 10.1016/j.cjsc.2024.100304
6. [6]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
7. [7]
  Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi_0.90Co_0.06Mn_0.04O₂ electrode by uniform Li₃PO₄ coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638
8. [8]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
9. [9]
  Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267
10. [10]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
11. [11]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
12. [12]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
13. [13]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
14. [14]
  Zizhuo Liang , Fuming Du , Ning Zhao , Xiangxin Guo . Revealing the reason for the unsuccessful fabrication of Li3Zr2Si2PO12 by solid state reaction. Chinese Journal of Structural Chemistry, 2023, 42(11): 100108-100108. doi: 10.1016/j.cjsc.2023.100108
15. [15]
  Ke-Ai Zhou , Lian Huang , Xing-Ping Fu , Li-Ling Zhang , Yu-Ling Wang , Qing-Yan Liu . Fluorinated metal-organic framework for methane purification from a ternary CH4/C2H6/C3H8 mixture. Chinese Journal of Structural Chemistry, 2023, 42(11): 100172-100172. doi: 10.1016/j.cjsc.2023.100172
16. [16]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
17. [17]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
18. [18]
  Xiaofei NIU , Ke WANG , Fengyan SONG , Shuyan YU . Self-assembly of [Pd₆(L)₄]⁸⁺-type macrocyclic complexes for fluorescent sensing of HSO₃^-. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1233-1242. doi: 10.11862/CJIC.20240057
19. [19]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
20. [20]
  Gengchen Guo , Tianyu Zhao , Ruichang Sun , Mingzhe Song , Hongyu Liu , Sen Wang , Jingwen Li , Jingbin Zeng . Au-Fe₃O₄ dumbbell-like nanoparticles based lateral flow immunoassay for colorimetric and photothermal dual-mode detection of SARS-CoV-2 spike protein. Chinese Chemical Letters, 2024, 35(6): 109198-. doi: 10.1016/j.cclet.2023.109198

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(1042)
HTML views(129)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Luminescence Properties of La7O6(BO3)(PO4)2: Tb3+/Eu3+ Phosphors

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Luminescence Properties of La₇O₆(BO₃)(PO₄)₂: Tb³⁺/Eu³⁺ Phosphors