Citation: GAO Xu-Sheng, LIU Guang, SHI Qin-Fang, WANG Kai-Fang, XU Li-Juan, HE Dong-Ying, LI Jin-Ping. Porous Cobalt-Iron Binary Metal Oxides Nanorods as Efficient Oxygen Evolving Catalysts for Water Splitting[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(4): 623-629. doi: 10.11862/CJIC.2017.080 shu

Porous Cobalt-Iron Binary Metal Oxides Nanorods as Efficient Oxygen Evolving Catalysts for Water Splitting

Research Institute of Fine Chemicals, Tai Yuan University of Technology, Taiyuan 030024, China

Corresponding author: LI Jin-Ping, jpli211@hotmail.com
Received Date: 14 November 2016
Revised Date: 6 January 2017

Figures(8)

A series of porous Co_1-xFe_xO_y(0 ≤ x ≤ 1) nanorods were fabricated by a simple thermal decomposed of CoFe-NTA precursors and were served as oxygen evolving catalysts for water electrolysis in 1 mol·L^-1 KOH solution. It was found that different Fe doping amounts have dramatically effects on the structure and electrocatalytic water oxidation activities and the 16%(n/n) Fe-doping sample exhibited the most excellent oxygen evolving activity. A lowered overpotential of 345 mV was achieved at a current density of 10 mA·cm^-2 with a Tafel slope of 54 mV·dec^-1 for the 16% Fe-doping sample, which suggest that it can be applied as low cost and efficient oxygen catalyst for water splitting.
- water splitting,
- oxygen evolving reaction,
- cobalt-iron metal oxides,
- nanorods
1. [1]
  XU Wei, TAO Zhan-Liang, CHEN Jun. Progress in Chemistry, 2006, 18(2/3):200-210
2. [2]
  WEN Fu-Yu, YANG Jin-Hui, ZONG Xu, et al. Progress in Chemistry, 2009, 21(11):2285-2302
3. [3]
  Joya K S, Joya Y F, Ocakoglu K, et al. Angew. Chem. Int. Ed., 2013, 52(40):10426-10437 doi: 10.1002/anie.201300136
4. [4]
  LI Cao-Long, WANG Fei, TANG Yuan-Yuan, et al. Chinese J. Inorg. Chem., 2016, 32(8):1375-1382
5. [5]
  HE Yang-Hua, XU Jin-Ming, WANG Fa-Nan, et al. Progress in Chemistry, 2016, 35(7):2057-2062
6. [6]
  SHI Hua-Yun, LU Tong-Bu. Chin. Sci. Bull., 2014, 59(17):1603-1616 doi: 10.1360/972013-906
7. [7]
  Singh A, Spiccia L. Coord. Chem. Rev., 2013, 257(17/18):2607-2622
8. [8]
  Xu K, Chen P, Li X, et al. J. Am. Chem. Soc., 2015, 137(12):4119-4125 doi: 10.1021/ja5119495
9. [9]
  Huang J, Chen J, Yao T, et al. Angew. Chem. Int. Ed., 2015, 54(30):8722-8727 doi: 10.1002/anie.201502836
10. [10]
  Liu X, Jia H, Sun Z, et al. Electrochem. Commun., 2014, 46:1-4 doi: 10.1016/j.elecom.2014.05.029
11. [11]
  Zhao Q, Yu Z, Yuan W, et al. Int. J. Hydrogen Energy, 2012, 37(18):13249-13255 doi: 10.1016/j.ijhydene.2012.07.001
12. [12]
  Jiao F, Frei H. ChemInform, 2010, 3(8):1018-1027
13. [13]
  Xu L, Jiang Q, Xiao Z, et al. Angew. Chem. Int. Ed., 2016, 55(17):5277-5281 doi: 10.1002/anie.201600687
14. [14]
  Li L, Tian T, Jiang J, et al. J. Power Sources, 2015, 294:103-111 doi: 10.1016/j.jpowsour.2015.06.056
15. [15]
  Du S, Ren Z, Zhang J, et al. Chem. Commun., 2015, 51(38):8066-8069 doi: 10.1039/C5CC01080B
16. [16]
  Burke M S, Kast M G, Trotochaud L, et al. J. Am. Chem. Soc., 2015, 137(10):3638-3648 doi: 10.1021/jacs.5b00281
17. [17]
  Zhang B, Zheng X, Voznyy O, et al. Science, 2016, 352(6283):333-337 doi: 10.1126/science.aaf1525
18. [18]
  Friebel D, Louie M W, Bajdich M, et al. J. Am. Chem. Soc., 2015, 137(3):1305-1313 doi: 10.1021/ja511559d
19. [19]
  Wang Y, Zhou T, Jiang K, et al. Adv. Energy Mater., 2014, 4(16):1400696 doi: 10.1002/aenm.201400696
20. [20]
  Xiao C, LU X, Zhao C. Chem. Commun., 2014, 50(70):10122-10125 doi: 10.1039/C4CC04922E
21. [21]
  Liang H, Meng F, Caban-Acevedo M, et al. Nano Lett., 2015, 15(2):1421-1427 doi: 10.1021/nl504872s
22. [22]
  Jiang J, Zhang A, Li L, et al. J. Power Sources, 2015, 278:445-451 doi: 10.1016/j.jpowsour.2014.12.085
23. [23]
  Yang X, Li H, Lu A Y, et al. Nano Energy, 2016, 25:42-50 doi: 10.1016/j.nanoen.2016.04.035
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