Citation: XIANG Ying-Qiao, LI Tian-Tian, XU Qing-Hong. Preparation and Catalytic Properties of Au@ZrO₂ Hollow Microspheres[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(4): 615-622. doi: 10.11862/CJIC.2017.078 shu

Preparation and Catalytic Properties of Au@ZrO₂ Hollow Microspheres

State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Corresponding author: XU Qing-Hong, xuqh@mail.buct.edu.cn
Received Date: 9 December 2016
Revised Date: 9 February 2017

Figures(9)

SiO₂ microspheres with different diameters were prepared by Stober method, and the SiO₂ microspheres were uniformly coated with ZrO₂ by adsorption and hydrolysis of ZrOCl₂. The ZrO₂ hollow microspheres were then obtained after SiO₂ was removed by hydrofluoric acid, and Au@ZrO₂ hollow microspheres were finally prepared by deposition-precipitation (DP) method. Catalytic properties of Au@ZrO₂ hollow microspheres in reduction of paranitroaniline were studied carefully. The research results indicate that the SiO₂ microspheres have regular shape and good dispersity. The sizes and the surface areas of the ZrO₂ hollow microspheres could be controlled effectively by the diameters of SiO₂ microspheres. Compared to the solid microsphere Au@ZrO₂, the Au@ZrO₂ hollow microspheres showed good catalytic performance in reduction of p-nitroaniline, and p-nitroaniline was completely reduced to p-phenylenediamine in 7 min at 45℃.
- Au@ZrO₂ hollow microsphere,
- deposition-precipitation method,
- p-nitroaniline,
- catalysis,
- reduction
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Preparation and Catalytic Properties of Au@ZrO₂ Hollow Microspheres