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Citation: GAO Xi-Feng, LIU Jing-Song, YANG Pei-Pei, LIU Yan-Ming, ZHANG Xi-Qi, ZHU Jian-Hua. Syntheses, Crystal Structures and Magnetic Properties of Fe(Ⅲ), Co(Ⅲ) and Mixed Valence Mn(Ⅱ)/Mn(Ⅲ) Complexes Based on a Schiff Base Ligand Derived From Salicylaldehyde[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(4): 630-636. doi: 10.11862/CJIC.2017.074 shu

Syntheses, Crystal Structures and Magnetic Properties of Fe(Ⅲ), Co(Ⅲ) and Mixed Valence Mn(Ⅱ)/Mn(Ⅲ) Complexes Based on a Schiff Base Ligand Derived From Salicylaldehyde

  • 1.

    Shandong Institute for Food and Drug Control, Jinan 250101, China

  • 2.

    Qilu Pharmaceutical Co., LTD., Jinan 250101, China

  • 3.

    Department of Chemical Engineering, Huaibei Normal University, Huaibei, Anhui 235000, China

Figures(8)

  • The Schiff base hmmpH2 (hmmpH2=2-[(2-hydroxyethylimino) methyl]-6-methoxyphenol) was synthesized by o-vanillin and ethanolamine. Complexes[Fe2(hmmp)2(hmmpH)2]·1.5CH3CN·0.5H2O (1) and[Co2Na ((hmmp)2(N3)2(CH3O)(CH3OH)2] (2) were synthesized by using hmmpH2 ligand. The Schiff base hmdbrpH2 (hmdbrpH2=2-[(2-hydroxyethylimino) methyl]-4, 6-dibromophenol) was synthesized by 3, 5-dibromosalicylaldehyde and ethanolamine. Complex[Mn(Ⅱ) Mn(Ⅲ)2(hmdbrp)2(O2CPh)4(CH3OH)2]·2CH3CN·2CH3OH (3) was synthesized by using hmdbrpH2 ligand. These complexes were fully characterized by elemental analysis and X-ray single crystal diffraction, and complexes 1 and 3 were also studied by magnetic investigation. The structural analysis indicates that in complex 1 two six-coordinated Fe(Ⅲ) ions are bridged by two alcoholic hydroxyl atoms to form a dimer structure. In complex 2, Co(Ⅲ) is six-coordinated with an octahedral coordination environment and the two Co(Ⅲ) ions are bridged by two O atoms from CH3OH constructing a binuclear complex. The complex 3 is a mixed valence trinuclear structure, with three Mn ions in linear array. Magnetic study indicates that the antiferromagnetic interaction exist between Fe(Ⅲ) ions in complex 1, and in complex 3 antiferromagnetic interactions exist between the Mn(Ⅱ) and Mn(Ⅲ) ions in the trinuclear manganese unit.
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    1. [1]

      Williams A F, Floriani C, Merbach A E. Perspectives in Coordination Chemistry. Weinheim:VCH Publisher, 1992.

    2. [2]

      Bruce D W, O'Hare D. Inorganic Materials. 2nd Ed. New York:John Wiley & Sons, 1996.

    3. [3]

      Ciardelli F, Tsuchida E, Wohrle D. Macromolecule-Metal Complexes. Berlin:Springer-Verlag, 1996.

    4. [4]

      Kahn O. Molecular Magnetism. New York:VCH Publisher, 1993.

    5. [5]

      Chen C T, Suslick K S. Coord. Chem. Rev., 1993, 128:293-322
       

    6. [6]

      Day P. Coord. Chem. Rev., 1999, 190-192:827-839  doi: 10.1016/S0010-8545(99)00123-X

    7. [7]

    8. [8]

      Lippard S J, Bers J M. Principles of Bioinorganic Chemistry. California:University Science Books, 1994.

    9. [9]

      Hewitt I J, Tang J K, Madhu N T, et al. Chem. Commun., 2006:2650-2652
       

    10. [10]

      Wu G, Hewitt I J, Mameri S, et al. Inorg. Chem., 2007, 46:7229-7231
       

    11. [11]

      Boskovic C, Güdel H U, Labat G, et al. Inorg. Chem., 2005, 44:3181-3189  doi: 10.1021/ic048411u

    12. [12]

      Boskovic C, Russanov E, Stoeckli-Evans H, et al. Inorg. Chem. Commun., 2002, 5:881-886  doi: 10.1016/S1387-7003(02)00595-6

    13. [13]

      Rasler R, Boskovic C, Chaboussant G, et al. ChemPhysChem, 2003, 4:910-926
       

    14. [14]

      Beghidja C, Rogez G, Kortus J. J. Am. Chem. Soc., 2006, 128:3140-3141
       

    15. [15]

      Lin J, Tu C, Lin H. Inorg. Chem. Commun., 2003, 6:262-265  doi: 10.1016/S1387-7003(02)00741-4

    16. [16]

      Boskovic C, Sieber A, Chaboussant G, et al. Inorg. Chem., 2004, 43:5053-5068
       

    17. [17]

      Koizumi S, Nihei M, Shiga T, et al. Chem. Eur. J., 2007, 13:8445-8453  doi: 10.1002/(ISSN)1521-3765

    18. [18]

      Yang E C, Wernsdorfer W, Edward R S, et al. Polyhedron, 2003, 22:1727-1733
       

    19. [19]

      Oshio H, Hoshino N, Ito T. J. Am. Chem. Soc., 2000, 122:12602-12603
       

    20. [20]

      Oshio H, Hoshino N, Ito T. J. Am. Chem. Soc., 2004, 126:8805-8812
       

    21. [21]

      Hazra S, Koner R, Lemoine P, et al. Eur. J. Inorg. Chem., 2009:3458
       

    22. [22]

      Pooransingh N, Pomerantseva E, Ebel M, et al. Inorg. Chem., 2003, 42:1256  doi: 10.1021/ic026141e

    23. [23]

      Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.

    24. [24]

      Li X, Kessissoglou D P, Kirk M L, et al. Inorg. Chem., 1988, 27:1-3  doi: 10.1021/ic00274a001

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    沈阳化工大学材料科学与工程学院 沈阳 110142

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