Citation: LI Jian-Jun, BAO Xu, WU Xian-Feng, Islam Nazrul, LIU Yin, QIAO Shang-Yuan, YU Zhen-Wei, ZHU Jin-Bo. Magnetic Chitosan Micron Spheres: Synthesis and Adsorption Property for Cu²⁺[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(3): 383-388. doi: 10.11862/CJIC.2017.052 shu

Magnetic Chitosan Micron Spheres: Synthesis and Adsorption Property for Cu²⁺

LI Jian-Jun ^1,2,*,, ,
BAO Xu ¹ ,
WU Xian-Feng ¹ ,
Islam Nazrul ² ,
LIU Yin ¹ ,
QIAO Shang-Yuan ¹ ,
YU Zhen-Wei ² ,
ZHU Jin-Bo ¹

1.
Department of Materials Science and Engineering, Anhui University of Science and Technology, Huainan, Anhui 232001, China
2.
Institute for Superconducting and Electronic Materials, University of Wollongong, Wollongong NSW 2500, Australia

Corresponding author: LI Jian-Jun, ljjhero4@gmail.com
Received Date: 8 November 2016
Revised Date: 15 December 2016

Figures(9)

MS@SiO₂@CS magnetic micron spheres were fabricated by successively coating the ball-milled coal fly ash magneticsphere (MS) particles with SiO₂ and chitosan (CS) through a sol-gel and an inverse microemulsion method, respectively. The structures and properties were carefully characterized by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and vibrating sample magnetometer (VSM). The results showed that the MS particles were coated layer by layer of SiO₂ and CS, respectively, and relative evenly distributed in the CS substrate. Since MSs are magnetic, the MS@SiO₂@CS samples also show relatively strong magnetism with a specific saturation magnetization of 7.04 emu·g^-1. Adsorption experiments indicated that the magnetic composite micronspheres showed the good adsorption capability for Cu²⁺ ions, and the adsorption capacity was up to 11.08 mg·g^-1. In addition, after Cu²⁺ adsorption, the adsorbents could be separated effectively from water by magnetic separation. According to the adsorption kinetics simulation, the Cu²⁺ adsorption of MS@SiO₂@CS corresponds to pseudo second order kinetics, which implies a dominant chemical adsorption.
- fly ash magneticspheres,
- magnetic chitosan,
- adsorption,
- heavy metal ions,
- magnetic separation
1. [1]
  Cheng K C, Kong X Y, Goh T L, et al. Carbohydr. Polym., 2016, 138:16-26 doi: 10.1016/j.carbpol.2015.11.060
2. [2]
  Fan C, Li K, Wang Y, et al. RSC Adv., 2015, 6(4):2678-2686
3. [3]
  Ren Y, Abbood H A, He F, et al. Chem. Eng. J., 2013, 226: 300-311 doi: 10.1016/j.cej.2013.04.059
4. [4]
  Zhu Y, Hu J, Wang J. Prog. Nucl. Energy, 2014, 71:172-178 doi: 10.1016/j.pnucene.2013.12.005
5. [5]
  Monier M, Ayad D M, Wei Y, et al. J. Hazard. Mater., 2010, 177(1/2/3):962-970
6. [6]
  Cho D W, Jeon B H, Chon C M, et al. J. Ind. Eng. Chem., 2015, 28:60-66 doi: 10.1016/j.jiec.2015.01.023
7. [7]
  WU Xian-Feng, LI Jian-Jun, ZHU Jin-Bo, et al. Mater. Rev., 2015, 29(23):103-107
8. [8]
  Pan J M, Yao H, Li X X, et al. J. Hazard. Mater., 2011, 190(1/2/3):276-284
9. [9]
  Sun X, Li Q, Yang L, et al. Particuology, 2016, 26:79-86 doi: 10.1016/j.partic.2015.11.003
10. [10]
  Xu Y Y, Dang Q F, Liu CS, et al. Colloids Surf. A, 2015, 482:353-364 doi: 10.1016/j.colsurfa.2015.06.028
11. [11]
  PENG Hong-Xia, HU Chuan-Yue, WU Teng-Yan, et al. Chinese J. Inorg. Chem., 2016, 32(7):1154-1160
12. [12]
  Peng S, Meng H C, Yong O Y, et al. Ind. Eng. Chem. Res., 2014, 53:2106-2113 doi: 10.1021/ie402855t
13. [13]
  Park J, Hong Y K, Kim S G, et al. J. Magn. Magn. Mater., 2014, 355:1-6 doi: 10.1016/j.jmmm.2013.11.032
14. [14]
  YANG Run-Ping, LI Xiao-Xia, CHEN Wei, et al. Chin. J. Health Lab. Technol., 2007, 12(17):2217-2219
15. [15]
  LIU Yun-Fang, REN Sen, WU Ri-Liang, et al. Chinese J. Inorg. Chem., 2015, 31(12):2373-2378
16. [16]
  WANG Jun, CAI Wei-Quan, WU Xuan-Jun. Chinese J. Inorg. Chem., 2014, 30(11):2564-2570
17. [17]
  Lu C, Yu S, Yao T, et al. J. Porous Mater., 2015, 22(5):1255-1263 doi: 10.1007/s10934-015-0003-0
18. [18]
  Cai Y, Zheng L, Fang Z. RSC Adv., 2015, 5(118):97435-97445 doi: 10.1039/C5RA16547D
19. [19]
  Wei P, Xie Z, Ge C, et al. J. Hazard. Mater., 2015, 294:9-16 doi: 10.1016/j.jhazmat.2015.03.046
20. [20]
  Negm N A, Sheikh RE, El-Farargy A F, et al. J. Ind. Eng. Chem., 2014, 21:526-534
21. [21]
  Goze B, Evirgen O A, Acikel Y S. Desalin. Water Treat., 2014, 57(9):4059-4072
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沈阳化工大学材料科学与工程学院沈阳 110142

Magnetic Chitosan Micron Spheres: Synthesis and Adsorption Property for Cu2+

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通讯作者: 陈斌, bchen63@163.com

Magnetic Chitosan Micron Spheres: Synthesis and Adsorption Property for Cu²⁺