Citation: WANG Ying, MI Kan, XIONG Sheng-Lin. Immobilizing Sulfur in Mn₂O₃ Hollow Spheres for Lithium-Sulfur Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 243-248. doi: 10.11862/CJIC.2017.048 shu

Immobilizing Sulfur in Mn₂O₃ Hollow Spheres for Lithium-Sulfur Batteries

1.
Shandong Yuhuang New Energy Technology Co., LTD, Heze, Shandong 274000, China
2.
School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China

Corresponding author: XIONG Sheng-Lin, chexsl@sdu.edu.cn
Received Date: 1 September 2016
Revised Date: 17 November 2016

Figures(5)

Uniform Mn₂O₃ hollow spheres were synthesized by using carbon spheres as the hard template and were used as holder for Li-S batteries. The Mn₂O₃-S composites showed a high specific capacity, good cycling stability and rate performance. The final reversible capacity can remain at 657 mA·g^-1 after 100 cycles at the current density of 0.9 A·g^-1 with the 51% sulfur loading, which demonstrates that Mn₂O₃ hollow spheres could be a promising matrix for Li-S batteries.
- electrochemistry,
- hollow spheres,
- manganic oxide,
- Li-S batteries
1. [1]
  Chen L, Shaw L L. J. Power Sources., 2014, 267:770-783 doi: 10.1016/j.jpowsour.2014.05.111
2. [2]
  ZHOU Lan, YU Ai-Shui. J. Electrochem., 2015, 21(3):211-220
3. [3]
  Lin Z, Liang C. J. Mater. Chem. A, 2015, 3:936-958 doi: 10.1039/C4TA04727C
4. [4]
  Manthiram A, Fu Y, Chung, et al. Chem. Rev., 2014, 114:11751-11787 doi: 10.1021/cr500062v
5. [5]
  Pope M A, Aksay I A. Adv. Energy Mater., 2015, 5:1500124 doi: 10.1002/aenm.201500124
6. [6]
  DIAO Yan, XIE Kai, HONG Xiao-Bin, et al. Acta Chim. Sinica, 2013, 7(4):508-548
7. [7]
  WAN Wen-Bao, PU Wei-Hua. Prog. Chem., 2013, 25(11):1830-1841
8. [8]
  He G, Evers S, Liang, et al. ACS Nano, 2013, 7:10920-10930 doi: 10.1021/nn404439r
9. [9]
  Jayaprakash N, Shen J, Moganty S S, et al. Angew Chem. Int. Ed., 2011, 50:5904-5908 doi: 10.1002/anie.v50.26
10. [10]
  Qu Y, Zhang Z, Wang, et al. J. Mater. Chem. A, 2013, 1:14306 doi: 10.1039/c3ta13306k
11. [11]
  Jung D S, Hwang T H, Lee, et al. Nano Lett., 2014, 14:4418-4425 doi: 10.1021/nl501383g
12. [12]
  Wang M, Zhang H, Wang, et al. ACS Appl. Mater. Interfaces, 2015, 7:3590-3599 doi: 10.1021/am5075562
13. [13]
  徐晶晶, 李斌, 李松梅, 等.无机化学学报, 2015, 31(10):2030-2036
14. [14]
  Mi K, Jiang Y, Feng J, et al. Adv. Funct. Mater., 2016, 26:1571-1579 doi: 10.1002/adfm.v26.10
15. [15]
  Ahn W, Lee D U, Song, et al. RSC Adv., 2015, 5:29370-29374 doi: 10.1039/C5RA02548F
16. [16]
  Duan X, Han Y, Huang L W, et al. J. Mater. Chem. A, 2015, 3:8015-8021 doi: 10.1039/C4TA06097K
17. [17]
  MAO Yan, ZHANG Chuan-Hui, ZHANG Yang, et al. Chinese J. Inorg. Chem., 2013, 29(5):889-895
18. [18]
  Li J, Ding B, Xu G, et al. Nanoscale, 2013, 5:5743-5746 doi: 10.1039/c3nr01393f
19. [19]
  Wei S Z, Li W Y, Cha J J, et al. Nat. Commun., 2013, 4:1331 doi: 10.1038/ncomms2327
20. [20]
  Choi Y J, Jung B S, Lee, et al. B. Phys. Scr., 2007, T129:62-65 doi: 10.1088/0031-8949/2007/T129/014
21. [21]
  Li W, Hicks-Garner J, Wang J, et al. Chem. Mater., 2014, 26:3403-3410 doi: 10.1021/cm500575q
22. [22]
  Liang X, Hart C, Pang Q, et al. Nat. Commun., 2015, 6:5682 doi: 10.1038/ncomms6682
23. [23]
  Wang X, Li G, Li J, et al. Energy Environ. Sci., 2016, 9:2533-2538 doi: 10.1039/C6EE00194G
24. [24]
  Sun X, Li Y. Angew. Chem. Int. Ed., 2004, 43:597-601 doi: 10.1002/(ISSN)1521-3773
25. [25]
  Bongu C S, Karuppiah S, Nallathamby K, et al. J. Mater. Chem. A, 2015, 3:23981-23989 doi: 10.1039/C5TA07876H
26. [26]
  Kolathodi M S, Rao S N H, Natarajan T S, et al. J. Mater. Chem. A, 2016, 4:7883-7891 doi: 10.1039/C6TA01948J
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Immobilizing Sulfur in Mn2O3 Hollow Spheres for Lithium-Sulfur Batteries

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通讯作者: 陈斌, bchen63@163.com

Immobilizing Sulfur in Mn₂O₃ Hollow Spheres for Lithium-Sulfur Batteries