Citation: GU Wen-Jun, GU Jin-Zhong. Syntheses, Crystal Structures and Magnetic Properties of 1D and 2D Cobalt(Ⅱ) Coordination Polymers Constructed from Semir-igid Tricarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 227-236. doi: 10.11862/CJIC.2017.035 shu

Syntheses, Crystal Structures and Magnetic Properties of 1D and 2D Cobalt(Ⅱ) Coordination Polymers Constructed from Semir-igid Tricarboxylic Acid

GU Wen-Jun ¹ ,
GU Jin-Zhong ^2,,

1.
College of Animal Science and Technology, Southwest University, Chongqing 400715, China
2.
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: GU Jin-Zhong, gujzh@lzu.edu.cn
Received Date: 30 September 2016
Revised Date: 2 December 2016

Figures(14)

Two 1D and 2D cobalt (Ⅱ)coordination polymers, namely[Co (μ2-Hcpta) (phen) (H₂O)]_n (1)and[Co₃ (μ5-cpta)₂ (2, 2'-bipy)₂]_n (2), have been constructed hydrothermally using H₃cpta (H₃cpta=2-(2-carboxyphenoxy)terephthalic acid), phen (phen=phenanthroline)or 2, 2'-bipy (2, 2'-bipy=2, 2'-bipyridine), and cobalt chloride. Single-crystal X-ray diffraction analyses revealed that the two compounds crystallize in the monoclinic system, space group P2_1/c. In compound 1, the carboxylate groups of Hcpta^2- ligands bridge alternately neighboring metal ions to form a chain. Adjacent chains are assembled to a 2D supramolecular network through C-H…O hydrogen bond. Compound 2 shows a 2D sheet based on Co₃ units. Magnetic studies for compounds 1 and 2 demonstrate an antiferromagnetic coupling between the adjacent Co (Ⅱ)centers. CCDC:1507502, 1; 1507503, 2.
- coordination polymer,
- hydrogen bonding,
- tricarboxylic acid,
- magnetic properties
1. [1]
  Sun Y J, Zhou H C. Sci. Technol. Adv. Mater., 2015, 16:054202 doi: 10.1088/1468-6996/16/5/054202
2. [2]
  Li J R, Sculley J, Zhou H C. Chem. Rev., 2012, 112:869-932 doi: 10.1021/cr200190s
3. [3]
  Cui Y, Yue Y, Qian G, et al. Chem. Rev., 2012, 112:1126-1162 doi: 10.1021/cr200101d
4. [4]
  Kuppler R J, Timmons D J, Fang Q R, et al. Coord. Chem. Rev., 2009, 253:3042-3066 doi: 10.1016/j.ccr.2009.05.019
5. [5]
  Zheng X D, Lu T B. CrystEngComm, 2010, 12:324-336 doi: 10.1039/B911991D
6. [6]
  Jiang X, Liu C M, Kou H Z. Inorg. Chem., 2016, 55:5880-5885 doi: 10.1021/acs.inorgchem.6b00179
7. [7]
  Zhang W J, Yuan D Q, Liu D H, et al. Chem. Mater., 2012, 24:18-25 doi: 10.1021/cm2008889
8. [8]
  Zhang H, Yang J, Liu Y Y, et al. Cryst. Growth Des., 2016, 16:3244-3255
9. [9]
  Karmakar A, Desai A V, Ghosh S K, Coord. Chem. Rev., 2016, 07:313-341
10. [10]
  Gu J Z, Gao Z Q, Tang Y. Cryst. Growth Des., 2012, 12:3312-3323 doi: 10.1021/cg300442b
11. [11]
  Gao Q, Xie Y B, Li J R, et al. Cryst. Growth Des., 2012, 12:281-288 doi: 10.1021/cg201059d
12. [12]
  Lee J, Kang Y J, Cho N S, et al. Cryst. Growth Des., 2016, 16:996-1004 doi: 10.1021/acs.cgd.5b01544
13. [13]
  Li L, Cao X Y, Huang R D. Chin. J. Chem., 2016, 34:143-156 doi: 10.1002/cjoc.v34.2
14. [14]
  Lu W G, Su C Y, Lu T B, et al. J. Am. Chem. Soc., 2006, 128:34-35 doi: 10.1021/ja0567337
15. [15]
  Wang H H, Yang H Y, Shu C H, et al. Cryst. Growth Des., 2016, 16:5394-5402 doi: 10.1021/acs.cgd.6b00890
16. [16]
  Cui L T, Niu Y F, Han J, et al. J. Solid State Chem., 2015, 227:155-164 doi: 10.1016/j.jssc.2015.03.035
17. [17]
  Wang H L, Zhang D P, Sun D F, et al. CrystEngComm, 2010, 12:1096-1102 doi: 10.1039/B917659D
18. [18]
  Chen X, Wang Y Y, Liu B, et al. Dalton Trans., 2013, 42:7092-7100 doi: 10.1039/c3dt32556c
19. [19]
  Hu J S, Huang X H, Pan C L, et al. Cryst. Growth Des., 2015, 15:2272-2281 doi: 10.1021/acs.cgd.5b00067
20. [20]
  Zhao H W, Li B. Chin. J. Struct. Chem., 2012, 31:61-66
21. [21]
  Sheldrick G M. SHELXTL-97, University of Göttingen, Germany, 1997.
22. [22]
  Tang L, Fu F, Wang J J, et al. Polyhedron, 2015, 88:116-124 doi: 10.1016/j.poly.2014.12.023
23. [23]
  GU Jin-Zhong, GAO Zhu-Qing, DOU Wei, et al. Chinese J. Inorg. Chem., 2009, 25(5):920-923
24. [24]
  QIAO Yu, WEI Bing, WANG Lu-Yao, et al. Chinese J. Inorg. Chem., 2016, 32(7):1261-1266
25. [25]
  Marshall S R, Rheingold A L, Dawe L N, et al. Inorg. Chem., 2002, 41:3599-3601 doi: 10.1021/ic020176x
26. [26]
  Su Z, Fan J, Chen M, et al. Cryst. Growth Des., 2011, 11:1159-1169 doi: 10.1021/cg101365v
27. [27]
  Niu C Y, Zheng X F, Wan X S, et al. Cryst. Growth Des., 2011, 11:2874-2888 doi: 10.1021/cg2000427
28. [28]
  Kahn O. Molecular Magnetism. New York:VCH Publishers, 1993:258
1. [1]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
2. [2]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
3. [3]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
4. [4]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
5. [5]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
6. [6]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
7. [7]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
8. [8]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
9. [9]
  Songtao Cai , Liuying Wu , Yuan Li , Soham Samanta , Jinying Wang , Bing Liu , Feihu Wu , Kaitao Lai , Yingchao Liu , Junle Qu , Zhigang Yang . Intermolecular hydrogen-bonding as a robust tool toward significantly improving the photothermal conversion efficiency of a NIR-II squaraine dye. Chinese Chemical Letters, 2024, 35(4): 108599-. doi: 10.1016/j.cclet.2023.108599
10. [10]
  Jun Guo , Zhenbang Zhuang , Wanqiang Liu , Gang Huang . "Co-coordination force" assisted rigid-flexible coupling crystalline polymer for high-performance aqueous zinc-organic batteries. Chinese Chemical Letters, 2024, 35(9): 109803-. doi: 10.1016/j.cclet.2024.109803
11. [11]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
12. [12]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
13. [13]
  Luyan Shi , Ke Zhu , Yuting Yang , Qinrui Liang , Qimin Peng , Shuqing Zhou , Tayirjan Taylor Isimjan , Xiulin Yang . Phytic acid-derivative Co₂B-CoPO_x coralloidal structure with delicate boron vacancy for enhanced hydrogen generation from sodium borohydride. Chinese Chemical Letters, 2024, 35(4): 109222-. doi: 10.1016/j.cclet.2023.109222
14. [14]
  Xinghui Yao , Zhouyu Wang , Da-Gang Yu . Sustainable electrosynthesis: Enantioselective electrochemical Rh(III)/chiral carboxylic acid-catalyzed oxidative CH cyclization coupled with hydrogen evolution reaction. Chinese Chemical Letters, 2024, 35(9): 109916-. doi: 10.1016/j.cclet.2024.109916
15. [15]
  Jing Cao , Dezheng Zhang , Bianqing Ren , Ping Song , Weilin Xu . Mn incorporated RuO₂ nanocrystals as an efficient and stable bifunctional electrocatalyst for oxygen evolution reaction and hydrogen evolution reaction in acid and alkaline. Chinese Chemical Letters, 2024, 35(10): 109863-. doi: 10.1016/j.cclet.2024.109863
16. [16]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
17. [17]
  Zhenyang Lin . A classification scheme for inorganic cluster compounds based on their electronic structures and bonding characteristics. Chinese Journal of Structural Chemistry, 2024, 43(5): 100254-100254. doi: 10.1016/j.cjsc.2024.100254
18. [18]
  Xu-Hui Yue , Xiang-Wen Zhang , Hui-Min He , Lei Qiao , Zhong-Ming Sun . Synthesis, chemical bonding and reactivity of new medium-sized polyarsenides. Chinese Chemical Letters, 2024, 35(7): 108907-. doi: 10.1016/j.cclet.2023.108907
19. [19]
  Hongdao LI , Shengjian ZHANG , Hongmei DONG . Magnetic relaxation and luminescent behavior in nitronyl nitroxide-based annuluses of rare-earth ions. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 972-978. doi: 10.11862/CJIC.20230411
20. [20]
  Rui Wang , He Qi , Haijiao Zheng , Qiong Jia . Light/pH dual-responsive magnetic metal-organic frameworks composites for phosphorylated peptide enrichment. Chinese Chemical Letters, 2024, 35(7): 109215-. doi: 10.1016/j.cclet.2023.109215

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1662)
HTML views(30)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142