Citation: DU Jun-Chen, ZHANG Ai-Min, MA Jiang-Li, LIU Qiang, Feng FENG, CHEN Yu-Bao, ZHAO Yun-Kun. Pd-Al₂O₃-BEA Catalysts for the Preparation of Jet Fuel-Range Hydrocarbons from Oils Through One-Step Hydrogenation[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(3): 415-420. doi: 10.11862/CJIC.2017.027 shu

Pd-Al₂O₃-BEA Catalysts for the Preparation of Jet Fuel-Range Hydrocarbons from Oils Through One-Step Hydrogenation

DU Jun-Chen ^1,2 ,
ZHANG Ai-Min ^1,2,*,, ,
MA Jiang-Li ² ,
LIU Qiang ¹ ,
Feng FENG ^2,*,, ,
CHEN Yu-Bao ³ ,
ZHAO Yun-Kun ¹

1.
State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China
2.
State-Local Joint Engineer Laboratory of Precious Metals Catalytic Technology and Application, Kunming Sino-platinum Metals Catalysts Co., Ltd., Kunming 650106, China
3.
College of Energy and Environmental Science, Yunnan Normal University, Kunming 650500, China

Corresponding author: ZHANG Ai-Min, aiming.zhang@126.com Feng FENG, feng.feng@spmcatalyst.com
Received Date: 24 August 2016
Revised Date: 6 December 2016

Figures(3)

H-β zeolite modified Pd/Al₂O₃ catalysts were prepared by impregnation. Effects of adding method and content of H-β zeolite on the catalytic performance were studied by XRD, BET, NH₃-TPD and other analytical characterization techniques, as well as the reaction system with methyl oleate as model compounds studied. The results showed that the interaction among the components of Pd-Al₂O₃-BEA catalyst has a great difference because of the different adding method of H-β zeolite, thus its catalytic properties were greatly different. In the Pd/(BEA-Al₂O₃) catalysts, with H-β zeolite amount increased, its specific surface area, pore volume, acid amount of strong acid site all showed a trend of increase, while acid amount of weak acid site was first increased and decreased then, and the average pore size was decreased. Pd/(45%BEA-Al₂O₃) catalyst has the largest jet fuel-range hydrocarbons selectivity, branched alkanes selectivity, a certain proportion of naphthenes and aromatics, since it has an appropriate pore size distribution, moderate amount of strong acid site, the biggest amount of weak acid site.
- Pd/Al₂O₃ catalysts,
- H-β zeolite,
- jet fuel-range hydrocarbons,
- hydrogenation,
- oils
1. [1]
  Judit S, Güell B M. Chem. Eng., 2012, 29:1147-1152
2. [2]
  YAO Guo-Xin. Sino-Global Energy, 2011, 16(4):18-26
3. [3]
  TAO Zhi-Ping. Pet. Process. Petrochem., 2011, 42(7):91-96
4. [4]
  Liang S, Zhu L, Ming X, et al. Bioresour. Technol., 2013, 131(3):139-145
5. [5]
  Shonnard D R, Larry W, Kalnes T N. Environ. Prog. Sustain-able Energy, 2010, 29(3):382-392 doi: 10.1002/ep.10461
6. [6]
  Perego C, Bosetti A. Microporous Mesoporous Mater., 2011, 144:28-39 doi: 10.1016/j.micromeso.2010.11.034
7. [7]
  Holmgren J, Gosling C, Marinangeli R, et al. Hydrocarbon Process., 2007, 86(9):67-72
8. [8]
  NIE Hong, MENG Xiang-Kun, ZHANG Zhe-Min, et al. Scientia Sinica Chimica, 2014, 44(1):46-54
9. [9]
  DU Jun-Chen, ZHANG Ai-Min, XIA Wen-Zheng, et al. J. Funct. Mater., 2014, 45(9):9008-9012
10. [10]
  Kikhtyanin O V, Rubanov A E, Ayupov A B, et al. Fuel, 2010, 89(10):3085-3092 doi: 10.1016/j.fuel.2010.05.033
11. [11]
  Kikhtyanin O V, Vostrikova L A, Urzhuntsev G A, et al. Stud. Surf. Sci. Catal., 2008, 174(1):1227-1230
12. [12]
  Wang C, Tian Z, Wang L, et al. ChemSusChem, 2012, 5(10): 1974-1983 doi: 10.1002/cssc.v5.10
13. [13]
  Wang C, Liu Q, Liu X, et al. Chin. J. Catal., 2013, 34(6): 1128-1138 doi: 10.1016/S1872-2067(11)60524-X
14. [14]
  Verma D, Kumar R, Rana B, et al. Energy Environ. Sci., 2011, 4(5):1667-1671 doi: 10.1039/c0ee00744g
15. [15]
  Verma D, Rana B S, Kumar R, et al. Appl. Catal. A, 2014, 490:108-116
16. [16]
  Rabaev M, Landau M V, Vidruk-Nehemya R, et al. Fuel, 2015, 161:287-294 doi: 10.1016/j.fuel.2015.08.063
17. [17]
  Liu S, Zhu Q, Guan Q, et al. Bioresour. Technol., 2015, 183: 93-100 doi: 10.1016/j.biortech.2015.02.056
18. [18]
  DU Jun-Chen, ZHAO Yong-Yan, XIA Wen-Zheng, et al. Rare Metal Mater. Eng., 2015, 44(9):2210-2215
19. [19]
  LI Yu-Ping, WANG Tie-Jun, MA Long-Long, et al. J. Inorg. Mater., 2014, 29(6):599-604
20. [20]
  López C M, Guillén Y, García L, et al. Catal. Lett., 2008, 122(3):267-273
21. [21]
  Kusakari T, Tomishige K, Fujimoto K. Appl. Catal. A, 2002, 224(1/2):219-228
22. [22]
  MOU Yi-Meng, LIANG Hong, LI Shu-Hua, et al. Chinese J. Inorg. Chem., 2016, 32(4):602-608
23. [23]
  ZHAO Jia-Yue, ZHOU Yi-Ming, WU Yun-Sheng, et al. Acta Chim. Sinica, 2011, 69(10):1179-1185
24. [24]
  Ozkan U S, Kumthekar M W, Karakas G. Catal. Today, 1998, 40(1):3-14 doi: 10.1016/S0920-5861(97)00112-0
25. [25]
  Zhang X, Long E, Li Y, et al. J. Mol. Catal. A:Chem., 2009, 308(1/2):73-78
26. [26]
  PENG Peng, ZHANG Zhan-Quan, WANG You-He, et al. Prog. Chem., 2013, 25(12):2028-2037
27. [27]
  Gosselink R W, Hollak S A W, Chang S W, et al. ChemSusChem, 2013, 6(9):1576-1594 doi: 10.1002/cssc.201300370
28. [28]
  Sekizawa K, Widjaja H, Maeda S, et al. Appl. Catal. A, 2000, 200(1/2):211-217
29. [29]
  JIN Chang-Lei, MA Bo, ZHANG Xi-Wen, et al. Acta Petrol. Sin.:Pet. Process Sect., 2008, 24(05):509-514
30. [30]
  Zhu S, Liu S, Zhang H, et al. Chin. J. Catal., 2014, 35(10): 1676-1686 doi: 10.1016/S1872-2067(14)60133-9
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Pd-Al₂O₃-BEA Catalysts for the Preparation of Jet Fuel-Range Hydrocarbons from Oils Through One-Step Hydrogenation