Citation: ZHENG Zhuo, GUO Xiao-Dong, WU Zhen-Guo, XIANG Wei, HUA Wei-Bo, ZHONG Ben-He, YANG Xiu-Shan. Preparation of Carbon-Coated LiNi_1/3Co_1/3Mn_1/3O₂ Cathode for High-Rate Lithium Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(1): 106-114. doi: 10.11862/CJIC.2017.020 shu

Preparation of Carbon-Coated LiNi_1/3Co_1/3Mn_1/3O₂ Cathode for High-Rate Lithium Ion Batteries

1.
Polymer Research Institute, Sichuan University, Chengdu 610065, China
2.
School of Chemical Engineering, Sichuan University, Chengdu 610065, China
3.
College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610059, China

Corresponding author: YANG Xiu-Shan, yangxs@scu.edu.cn
Received Date: 23 August 2016
Revised Date: 18 November 2016

Figures(9)

A series of carbon-coated LiNi_1/3Co_1/3Mn_1/3O₂ cathodes (w=1.0%, 2.0%, 3.0%) have been prepared by the carbonate co-precipitation, high temperature solid state method. Powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), electrochemical impedance spectroscopy (EIS) and galvanostatic charge-discharge tests were employed to analyze the crystal structure, micromorphology and electrochemical properties of the as-prepared materials. The results indicate that carbon was successfully coated on the particle surface, and the carbon-coated LiNi_1/3Co_1/3Mn_1/3O₂ cathodes have well-ordered α-NaFeO₂ structure (Space group:R3m). The average primary particle sizes were gradually increased (from 177 to 209 nm) with the increased carbon coating. The amorphous carbon layer on the surface could enhance the electronic conductivity and decrease the side reactions between electrolyte and electrodes, thus improving the electrochemical performance. The 2.0% carbon-coated sample has the best high rate and long-term cycling stability. After 100 cycles at 1C between 2.7 and 4.3 V, the material retained 93% of its initial capacity. At 0.1C, 0.2C, 0.5C, 1C, 3C, 5C, 10C and 20C, the specific capacities of the material were 155, 148, 145, 138, 127, 116, 104 and 96 mAh·g^-1, respectively. This sample exhibits an excellent ultra-high rate performance with a high discharge capacity of 62 mAh·g^-1 (the pristine LiNi_1/3Co_1/3Mn_1/3O₂ barely delivers 30 mAh·g^-1) even at the ultra-high rate 50C (9 A·g^-1).
- carbonate co-precipitation,
- carbon-coated,
- high rate performance,
- LiNi_1/3Co_1/3Mn_1/3O₂,
- lithium-ion battery
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Carbon-Coated LiNi1/3Co1/3Mn1/3O2 Cathode for High-Rate Lithium Ion Batteries

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通讯作者: 陈斌, bchen63@163.com

Preparation of Carbon-Coated LiNi_1/3Co_1/3Mn_1/3O₂ Cathode for High-Rate Lithium Ion Batteries