Citation: XIONG Li-Long, XIAO Xiang, XU You-Long, WANG Ji-Sheng. Syntheses and Electrochemical Characterization of Li-Rich Li₂Mn_1-xTi_xO₃ Layered Materials Used for Lithium Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 269-275. doi: 10.11862/CJIC.2017.004 shu

Syntheses and Electrochemical Characterization of Li-Rich Li₂Mn_1-xTi_xO₃ Layered Materials Used for Lithium Ion Batteries

1.
Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education, Xi'an Jiaotong University, Xi'an 710049, China
2.
International Center for Dielectric Research, Xi'an Jiaotong University, Xi'an 710049, China

Corresponding author: XU You-Long, ylxuxjtu@mail.xjtu.edu.cn
Received Date: 10 May 2016
Revised Date: 15 October 2016

Figures(8)

Ti-doped Li₂MnO₃ is synthesized by a conventional solid-state reaction. Scanning electron microscopy, X-ray diffraction and X-ray photoelectric spectroscopy analyses indicate Ti is successfully doped into Li₂MnO₃ structure and the doping could suppress agglomeration of primary particlesis efficiently. Electrochemical impedance spectroscopy and galvanostatic charge/discharge results show that, in the voltage window of 2.0~4.6 V (vs Li/Li⁺), doped sample Li₂Mn_0.97Ti_0.03O₃ delivers an initial discharge capacity of 209 mAh·g^-1 with 99.5% coulombic efficiency; after 40 cycles the capacity retention is 94%. Even the current density increases to 400 mA·g^-1, the doped sample could still deliver 120 mAh·g^-1 capacity, which is more than twice of that of undoped Li₂MnO₃ (52 mAh·g^-1). Ti-doped Li₂MnO₃ show greatly improved cycling stability and rate performance, which is beneficial for promoting the commercial application of Li₂MnO₃ material.
- lithium-ion battery,
- cathode material,
- doping,
- cycling stability,
- rate performance
1. [1]
  Armand M, Tarascon J M. Nature, 2008, 451(7179):652-657 doi: 10.1038/451652a
2. [2]
  Robertson A D, Bruce P G. Chem. Mater., 2003, 15(10):1984-1992 doi: 10.1021/cm030047u
3. [3]
  Ammundsen B, Paulsen J. Adv. Mater., 2001, 13(12/13):943-955
4. [4]
  Mori D, Sakaebe H, Shikano M, et al. J. Power Sources, 2011, 196(16):6934-6938 doi: 10.1016/j.jpowsour.2010.11.150
5. [5]
  Kim S, Noh J K, Yu S, et al. J. Electroceram., 2013, 30(3):159-165 doi: 10.1007/s10832-012-9778-4
6. [6]
  Kang K W, Kim W T, Jeong Y U. J. Ceram. Process. Res., 2013, 14(4):468-471
7. [7]
  Wu X M, Li H, Fei H L, et al. New J. Chem., 2014, 38(2):584-587 doi: 10.1039/C3NJ00997A
8. [8]
  Xiong L L, Xiao X, Xu Y L, et al. J. Solid State Electrochem., 2016, 20(7):1889-1894 doi: 10.1007/s10008-015-3016-3
9. [9]
  WANG Chao, LIU Xing-Quan, LIU Hong-Ji, et al. Chinese J. Inorg. Chem., 2012, 28(9):1835-1842
10. [10]
  Xiao R J, Li H, Chen L Q. Chem. Mater., 2012, 24(21):4242-4251 doi: 10.1021/cm3027219
11. [11]
  Dong X, Xu Y L, Yan S, et al. J. Mater. Chem. A, 2015, 3(2):670-679 doi: 10.1039/C4TA02924K
12. [12]
  Bordeneuve H, Guillemet F S, Rousset A, et al. J. Solid State Chem., 2009, 182(2):396-401 doi: 10.1016/j.jssc.2008.11.004
13. [13]
  Abouimrane A, Compton O C, Deng H, et al. Electrochem. Solid State Lett., 2011, 14(9):A126-A129 doi: 10.1149/1.3597655
14. [14]
  Lim J M, Kim D, Lim Y G, et al. J. Mater. Chem. A, 2015, 3(13):7066-7076 doi: 10.1039/C5TA00944H
15. [15]
  Zhang X, Luo D, Li G, et al. J. Mater. Chem. A, 2013, 1(34):9721-9729 doi: 10.1039/c3ta11040k
16. [16]
  Yu D Y W, Yanagida K, Kato Y, et al. J. Electrochem. Soc., 2009, 156(6):A417-A424 doi: 10.1149/1.3110803
17. [17]
  Kan Y C, Hu Y, Croy J, et al. J. Power Sources, 2014, 266:341-346 doi: 10.1016/j.jpowsour.2014.05.032
18. [18]
  Jacob C, Jian J, Su Q, et al. ACS Appl. Mater. Interfaces, 2015, 7(4):2433-2438 doi: 10.1021/am5071305
19. [19]
  Johnson C S, Li N, Lefief C, et al. Chem. Mater., 2008, 20(19):6095-6106 doi: 10.1021/cm801245r
20. [20]
  Shigemura H, Tabuchi M, Sakaebe H, et al. J. Electrochem. Soc., 2003, 150(5):A638-A644 doi: 10.1149/1.1565135
21. [21]
  Kang S H, Johnson C S, Vaughey J T, et al. J. Electrochem. Soc., 2006, 153(6):A1186-A1192 doi: 10.1149/1.2194764
22. [22]
  XIONG Li-Long, XU You-Long, TAO Tao. Acta Phys.-Chim. Sin., 2013, 29(04):763-769 doi: 10.3866/PKU.WHXB201302211
23. [23]
  Tabuchi M, Nabeshima Y, Takeuchi T, et al. J. Power Sources, 2011, 196(7):3611-3622 doi: 10.1016/j.jpowsour.2010.12.060
24. [24]
  Lu Z H, Dahn J R. J. Electrochem. Soc., 2002, 149(11):A1454-A1459 doi: 10.1149/1.1513557
25. [25]
  Xiong L L, Xu Y L, Zhang C, et al. J. Solid State Electrochem., 2011, 15(6):1263-1269 doi: 10.1007/s10008-010-1195-5
26. [26]
  Xiong L L, Xu Y L, Xiao X, et al. Electron. Mater. Lett., 2015, 11(1):138-142 doi: 10.1007/s13391-014-4245-9
27. [27]
  Rana J, Stan M, Kloepsch R, et al. Adv. Energy Mater., 2014, 4(5):1-12
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沈阳化工大学材料科学与工程学院沈阳 110142

Syntheses and Electrochemical Characterization of Li-Rich Li2Mn1-xTixO3 Layered Materials Used for Lithium Ion Batteries

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通讯作者: 陈斌, bchen63@163.com

Syntheses and Electrochemical Characterization of Li-Rich Li₂Mn_1-xTi_xO₃ Layered Materials Used for Lithium Ion Batteries