Citation: SHI Chang-Dong, CHEN Sheng, CHENG Mei-Ling, RONG Hong-Ren, LAI Li-Fang, LIU Wen-Long, LIU Qi. Syntheses, Structures, and Luminescent Properties of Cadium and Copper Complexes Containing Pyrazole Carboxylic Acid of Uncoordinated Carboxyl Group[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(1): 89-96. doi: 10.11862/CJIC.2016.278 shu

Syntheses, Structures, and Luminescent Properties of Cadium and Copper Complexes Containing Pyrazole Carboxylic Acid of Uncoordinated Carboxyl Group

SHI Chang-Dong ¹ ,
CHEN Sheng ¹ ,
CHENG Mei-Ling ¹ ,
RONG Hong-Ren ¹ ,
LAI Li-Fang ¹ ,
LIU Wen-Long ^2,*,, ,
LIU Qi ^1,3,*,,

1.
School of Petrochemical Engineering and Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Changzhou University, Changzhou, Jiangsu 213164, China
2.
College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, China
3.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, Jiangsu 210093, China

Corresponding author: LIU Wen-Long, njulwl@163.com LIU Qi, liuqi62@163.com
Received Date: 31 July 2016
Revised Date: 20 October 2016

Figures(6)

Two new complexes[Cd(Hcmdpca)₂(phen)(H₂O)] (1) and [Cu₂(Hcmdpca)₂(phen)₄(NO₃)₂]·4H₂O (2) (H₂cmdpca=1-carboxymethyl-3,5-dimethyl-1H-pyrazole-4-carboxylic acid, phen=phenanthroline) have been synth-esized and characterized by IR spectra, elemental analysis, single crystal X-ray diffraction, thermogravimetric analysis. Complexes 1 and 2 all crystallize in the monoclinic system and their space group are C2/c and P2₁/c, respectively. In 1, Cd(Ⅱ) ion takes seven-coordination mode, and Hcmdpca- anion bridges adjacent Cd(Ⅱ) ions to generate a dinuclear structure; these dinuclear structure units are assembled into a 3D network via hydrogen bonds and π-π interactions. 2 is an independent unit consisted of two discrete mononuclear Cu(Ⅱ) complex cations, each Cu(Ⅱ) ion is located in a distorted octahedral geometry. These mononuclear Cu(Ⅱ) complex cations and NO₃^- ions are connected by electrostatic interactions and hydrogen bonds, producing a 3D supramolecular network, and the hollow space of the network are occupied by water molecules. The thermal stability and luminescent property of the complexes are also investigated. CCDC:1495594, 1; 1495595, 2.
- Cd(Ⅱ),
- Cu(Ⅱ),
- 1-Carboxymethyl-3,5-dimethyl-1H-pyrazole-4-carboxylic acid,
- crystal structure,
- photoluminescence,
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