Advanced Search

Citation: SHENG Shuang, ZHAO Hui, HAO Ju-Hong, SUN Li-Ping, HUO Li-Hua. Preparation and Electrochemical Properties of (Pr0.9La0.1)2(Ni0.74Cu0.21Ga0.05)O4+δ-Ce0.9Gd0.1O2-δComposite Cathode[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(12): 2143-2150. doi: 10.11862/CJIC.2016.275 shu

Preparation and Electrochemical Properties of (Pr0.9La0.1)2(Ni0.74Cu0.21Ga0.05)O4+δ-Ce0.9Gd0.1O2-δComposite Cathode

  • 1.

    1 Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China;

  • 2.

    2 Harbin Far East Institute of Technology, Harbin 150025, China

  • Corresponding author: SUN Li-Ping, 
  • Received Date: 8 July 2016
    Available Online: 14 October 2016

    Fund Project:

  • (Pr0.9La0.1)2(Ni0.74Cu0.21Ga0.05)O4+δ(PLNCG) is prepared by EDTA-citrate process, and forms composite cathode with Ce0.9Gd0.1O2-δ(CGO). XRD and SEM results demonstrate that PLNCG is chemical compatible with CGO at 1 000℃. The electrochemical measurements show that the polarization resistance (Rp) of PLNCG-30%CGO is 0.092 Ω·cm2 at 700℃. When the current density reaches 113.3 mA·cm-2, the cathode overpotential is only 39.3 mV at 700℃ in air. The oxygen partial pressure dependence of Rp indicates that the rate limiting step of the composite cathode is charge transfer process. The maximum power density of anode-support single cell (Ni-CGO/CGO/PLNCG-30%CGO) reaches 569 mW·cm-2 at 700℃ with open circuit voltage (OCV) of 0.76 V.
  • 加载中
    1. [1]

      [1] Steele B C H, Heinzel A. Nature, 2001,414:345-352

    2. [2]

      [2] Beckel D, Bieberle-Hütter A, Harvey A, et al. J. Power Sources, 2007,173(1):325-345

    3. [3]

      [3] SUN Li-Ping(孙丽萍), LI Qiang(李强), ZHAO Hui(赵辉), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014,30(5):1045-1050

    4. [4]

      [4] Li Q, Sun L P, Huo L H, et al. Int. J. Hydrogen Energy, 2010,35:9151-9157

    5. [5]

      [5] Xia T, Lin N, Zhao H, et al. J. Power Sources, 2009,192:291-296

    6. [6]

      [6] ZHANG Han(张瀚), XIA Chang-Rong(夏长荣). Chinese J. Inorg. Chem.(无机化学学报), 2010,26(10):1875-1879

    7. [7]

      [7] XIAO Hui(肖辉), SUN Li-Ping(孙丽萍), ZHAO Hui(赵辉), et al. Chinese J. Inorg. Chem.(无机化学学报), 2015,31(6):1139-1144

    8. [8]

      [8] Xu Q, Huang D P, Zhang F, et al. J. Alloys Compd., 2008, 454:460-465

    9. [9]

      [9] Liu Z, Cheng L Z, Han M F. J. Power Sources, 2011,196:868-871

    10. [10]

      [10] Shao Z P, Haile S M. Nature, 2004,431:170-173

    11. [11]

      [11] Wang F, Zhou Q J, He T M, et al. J. Power Sources, 2010, 195:3772-3778

    12. [12]

      [12] Ding H P, Lin B, Liu X Q, et al. Electrochem. Commun., 2008,10:1388-1391

    13. [13]

      [13] Zhou X D, Templeton J W, Nie Z, et al. Electrochim. Acta, 2012,71:44-49

    14. [14]

      [14] Ferchaud C, Grenier J C,Ye Z S, et al. J. Power Sources, 2011,196:1872-1879

    15. [15]

      [15] Yashima M, Yamada H, Ishihara T, et al. Chem. Mater., 2012,24:4100-4113

    16. [16]

      [16] Wang Y F, Cheng J G, Jiang Q M, et al. J. Power Sources, 2011,196:3104-3108

    17. [17]

      [17] Kovalevsky A V, Kharton V V, Yaremchenko A A, et al. J. Electroceram, 2007,18:205-218

    18. [18]

      [18] Ishihara T, Nakashima K, Okada S, et al. Solid State Ionics, 2008,179:1367-1371

    19. [19]

      [19] Peng S J,Wei Y Y, Xue J, et al. Int. J. Hydrogen Energy, 2013,38:10552-10558

    20. [20]

      [20] Zhou Q J, Wang F, Shen Y, et al. J. Power Sources, 2010, 195:2174-2181

    21. [21]

      [21] LI Qiang(李强), FAN Yong(范勇), SUN Li-Ping(孙丽萍), et al. Chinese J. Inorg. Chem.(无机化学学报), 2007,23(2):300-304

    22. [22]

      [22] Leng Y J, Chan S H, Liu Q L. Int. J. Hydrogen Energy, 2008,33:3808-3817

    23. [23]

      [23] Park Y M, Kim J H, Kim H. Int. J. Hydrogen Energy, 2011, 36:9169-9179

    24. [24]

      [24] Khandale A P, Lajurkar R P, Bhoga S S. Int. J. Hydrogen Energy, 2014,39:19039-19050

    25. [25]

      [25] Meng X W, Lü S Q, Ji Y, et al. Ceram. Int., 2015,41:12107-12114

    26. [26]

      [26] Yashima M, Sirikanda N, Ishihara T. J. Am. Chem. Soc., 2010,132:2385-2392

    27. [27]

      [27] Li Q, Fan Y, Zhao H, et al. J. Power Sources, 2007,167:64-68

    28. [28]

      [28] Sun C, Li Q, Sun L P, et al. Mater. Res. Bull., 2014,53:65-69

    29. [29]

      [29] Li Q, Zhao H, Huo L H, et al. Electrochem. Commun., 2007,9:1508-1512

    30. [30]

      [30] Dusastre V, Kilner J A. Solid State Ionics, 1999,126:163-174

    31. [31]

      [31] Simner S P, Anderson M D, Coleman J E, et al. J. Power Sources, 2006,161:115-122

    32. [32]

      [32] Martínez J P, López D M, Morales R, et al. Int. J. Hydrogen Energy, 2009,34:9486-9495

    33. [33]

      [33] Pang S L, Jiang X N, Li X N, et al. J. Power Sources, 2012,204:53-59

    34. [34]

      [34] Chen D J, Ran R, Zhang K, et al. J. Power Sources, 2009, 188:96-105

    35. [35]

      [35] Gao Z, Liu X M, Bergman B, et al. J. Power Sources, 2011, 196:9195-9203

    36. [36]

      [36] Zhao H, Huo L H, Gao S. J. Power Sources, 2004,125:149-154

    37. [37]

      [37] Li Q, Xia T, Sun L P, et al. Electrochim. Acta, 2014,150:151-156

    38. [38]

      [38] Li J, Zhang N Q, Ni D, et al. Int. J. Hydrogen Energy, 2011,36:7641-7648

    39. [39]

      [39] Lee H H, Park I Y, Park J H, et al. Int. J. Hydrogen Energy, 2015,40:11998-12002

    40. [40]

      [40] Li H, Sun L P, Li Q, et al. Int. J. Hydrogen Energy, 2015, 40:12761-12769

    41. [41]

      [41] Zhang L L, Liu M, Huang J H, et al. Int. J. Hydrogen Energy, 2014,39:7972-7979

    42. [42]

      [42] Wang Y X,Zhao X Y, Lü S Q, et al. Ceram. Int., 2014,40:7321-7327

    43. [43]

      [43] Baek S W, Jeong J, Schlegl H, et al. Ceram. Int., 2016,42:2402-2409

  • 加载中
    1. [1]

      Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO2-0.39IrOx composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459

    2. [2]

      Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo2O4/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369

    3. [3]

      Qi Li ,  Pingan Li ,  Zetong Liu ,  Jiahui Zhang ,  Hao Zhang ,  Weilai Yu ,  Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030

    4. [4]

      Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078

    5. [5]

      Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu2O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001

    6. [6]

      Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043

    7. [7]

      Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026

    8. [8]

      Jiaqi AN , Yunle LIU , Jianxuan SHANG , Yan GUO , Ce LIU , Fanlong ZENG , Anyang LI , Wenyuan WANG . Reactivity of extremely bulky silylaminogermylene chloride and bonding analysis of a cubic tetragermylene. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1511-1518. doi: 10.11862/CJIC.20240072

    9. [9]

      Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO4/NiMoS4 composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253

    10. [10]

      Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312

    11. [11]

      Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO2 cycloaddition over W18O49/NH2-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349

    12. [12]

      Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn0.8Fe0.2PO4/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252

    13. [13]

      Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075

    14. [14]

      Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162

    15. [15]

      Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe3O4@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239

    16. [16]

      Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO2 with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149

    17. [17]

      Xinxin JING , Weiduo WANG , Hesu MO , Peng TAN , Zhigang CHEN , Zhengying WU , Linbing SUN . Research progress on photothermal materials and their application in solar desalination. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1033-1064. doi: 10.11862/CJIC.20230371

    18. [18]

      Doudou Qin ,  Junyang Ding ,  Chu Liang ,  Qian Liu ,  Ligang Feng ,  Yang Luo ,  Guangzhi Hu ,  Jun Luo ,  Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034

    19. [19]

      Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447

    20. [20]

      Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(193)
  • HTML views(16)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return