Citation: LIN Sen, LI Yue, CUI Yang-Zhe, ZHANG Yan-Ru, WANG Meng-Qin, LI Zhong-Feng, JIN Qiong-Hua. Syntheses and Characterization of Silver(Ⅰ) Complexes of Bis(2-(diphenylphosphino)phenyl)ether[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(12): 2165-2171. doi: 10.11862/CJIC.2016.273
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Two novel silver(Ⅰ) complexes[Ag(DPEphos)(dppe)]2SO4 (1) and[Ag(DPEphos)(SCN)]2·CH2Cl2 (2) (DPEphos=bis(2-(diphenylphosphino)phenyl) ether, dppe=bis(diphenylphosphino)ethane) have been synthesized and characterized by IR, 1H NMR spectroscopy, elemental analysis, single-crystal X-ray diffraction and fluorescence spectra. Structure analysis shows that complex 1 has simple mono-nuclear structures, and each silver atom is chelated by four phosphines. Complex 2 has a bi-nuclear cluster of Ag(Ⅰ), showing weak argentophilic interactions. The sum of the internal angles of the four-member ring[-Ag-S-Ag-S-] in the Ag2S2 core is 360°, demonstrating that the ring is a parallelogram. The luminescent spectra of 1~2 are studied, which show that the emission peaks are assigned to the π-π* transitions of the diphosphine ligands. Thermogravimetric analysis shows that two complexes begin to decompose at around 340℃, indicating their strong stability.
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