Citation: NIU Yi-Fan, YANG Ying, YANG Wen-Tao. Hydrothermal Synthesis and Nanomechanical Performance of One-Dimensional Selenium Nanostructures[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(12): 2129-2135. doi: 10.11862/CJIC.2016.270 shu

Hydrothermal Synthesis and Nanomechanical Performance of One-Dimensional Selenium Nanostructures

1.
Sino-European Institute of Aviation Engineering, Civil Aviation University of China, Tianjin 300300, China

Corresponding author: NIU Yi-Fan,
Received Date: 25 May 2016
Available Online: 27 September 2016
Fund Project:

One-dimensional trigonal-selenium (t-Se) nanostructures were synthesized using environment-friendly and one-step hydrothermal process, using GeSe₄ glass as raw material in aqueous solution at 80℃. The morphologies and structures of these one-dimensional selenium products were characterized by transmission electron microscope (TEM), Raman spectrometry, scanning electron microscope (SEM) and atomic force microscope (AFM). The experimental results show that the Se nanofibers were grown along[001] direction with a hexagonal cross section. After 144 h of reaction, the length and diameter of Se nanofibers reached millimeter scale and 1~5 μm respectively. AFM based nanoindentation test reported that the hardness and elastic modulus of Se nanofibers were (399.5±20.4) MPa and (1.13±0.05) GPa respectively. The growth speed of Se nanofibers at pH=12.0 (80℃) was faster than that at pH=3.3 and pH=6.3. Se nanofibers were typically 344 μm long and 1.12 μm in diameter after 24 h of reaction in alkaline medium.
- trigonal-selenium;nanofiber;hydrothermal method;nanomechanical properties
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沈阳化工大学材料科学与工程学院沈阳 110142