Citation: WEN Xiao-Ling, DING Yi-Ming, OUYANG Jian-Ming. Differences in Adsorption of Anionic, Cationic and Nonionic Surfactant on Micron/nano Calcium Oxalate Monohydrate and Dihydrate Crystals[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(12): 2102-2108. doi: 10.11862/CJIC.2016.269
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In order to explore the effect of urine components with different charges on micron/nano urinary crystallites, the adsorption difference of three surfactants with different charges onto micron/nano calcium oxalate monohydrate (COM) and dihydrate (COD) was studied, including anionic surfactant sodium diisooctyl sulfosuccinate (AOT), cationic surfactant cetyltrimethylammonium bromide (CTAB), and nonionic surfactant nonylphenol ethoxylate (NP-40). The adsorption quantity of surfactants on COM and COD was ranked in the following order:AOT > CTAB > NP-40, that is, the absorption quantity of anionic surfactant is the maximum, and absorption quantity of nonionic surfactant is the minimum. The adsorption quantity of COM was greater than COD with the same size; the absolute value of ζ potential on surface of COM and COD was increased after adsorption of surfactants, it was conducive to inhibit crystal aggregation and sedimentation. The molecular models of surfactants adsorbed on crystal surface were proposed. There are different interactions between micro/nano COM, COD crystal and anionic, cationic, nonionic surfactants. The larger the adsorption quantity of surfactants is, the slower the sedimentation rate is, so the stabilizing effect on crystal suspension is more obvious.
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