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Citation: WANG Lan, GE Sheng-Song, SHAO Qian, LI Jian, DU Ling-Yu. Preparation and Adsorption Properties of Microspheres of ZnNiAl Layered Double Hydroxides[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(11): 1896-1904. doi: 10.11862/CJIC.2016.262 shu

Preparation and Adsorption Properties of Microspheres of ZnNiAl Layered Double Hydroxides

  • 1.

    1 College of Chemical and Environmental Engineering, Shandong University of Science & Technology, Qingdao, Shandong 266590, China;

  • 2.

    2 School of Materials Science and Engineering, Shandong University of Science & Technology, Qingdao, Shandong 266590, China

  • Corresponding author: GE Sheng-Song, 
  • Received Date: 30 May 2016
    Available Online: 28 September 2016

  • Uniform well-defined ZnNiAl-LDHs microspheres have been fabricated via a simple hydrothermal method with Zn(NO3)2·6H2O, Ni(NO3)2·6H2O, Al(NO3)3·9H2O and urea as materials. The phase identification and morphology of the LDHs were characterized by XRD, FTIR, SEM, TEM and N2 adsorption-desorption. And the adsorption performance of ZnNiAl-LDHs and ZnAl-LDHs toward methyl orange (MO) was compared. Results show that ZnNiAl-LDHs microspheres have a three dimensional structure which composed of nanosheets, and their particle size is in the range of 1~2.5 μm. The specific surface area of ZnNiAl-LDHs microspheres is 156 m2·g-1 which is much larger than that of ZnAl-LDHs (38 m2·g-1). The saturation adsorbance of ZnNiAl-LDHs and ZnAl-LDHs toward MO are 329.60 and 143.47 mg·g-1, respectively, which shows that ZnNiAl-LDHs exhibits excellent adsorption performance. The adsorption kinetics and adsorption isotherms of ZnNiAl-LDHs microspheres can be well described by the pseudo-second order kinetic and Langmuir isotherm.
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