Citation: LIU Xiang, HAN Jing, YU Zhong, WANG Xiao-Xiang. Three Coordination Polymer Microcrystals:Size-Controlled Syntheses and Photocatalytic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(11): 1931-1941. doi: 10.11862/CJIC.2016.253 shu

Three Coordination Polymer Microcrystals:Size-Controlled Syntheses and Photocatalytic Properties

1.
1 Department of Materials Physics and Chemistry, Xi'an University of Technology, Xi'an 710048, China;
2.
2 Department of Chemistry, Xi'an University of Technology, Xi'an 710048, China

Corresponding author: HAN Jing,
Received Date: 4 May 2016
Available Online: 27 September 2016
Fund Project:

Microcrystals of Ni(Ⅱ), Co(Ⅱ) and Zn(Ⅱ) coordination polymers based on 4,4'-oxybisbenzoic acid (oba) and 4,4'-bipyridine (4,4'-bpy) with sizes ranging from 10 to 250 μm were prepared hydrothermally by regulating the amount of NEt3, reaction time and reaction temperature. The crystal sizes, morphologies and structures were characterized and analyzed by scanning electron microscopy (SEM) and X-ray powder diffraction (XRPD). Photocatalytic measurements demonstrate that three polymers have excellent degradation capacities of organic dyes such as rhodamine B (RhB), methyl orange (MO) and methylene blue (MB) and the degradation rate increases with the decrease of catalyst sizes. Remarkably, the photocatalytic performance of Ni(Ⅱ) complex (30 μm) for RhB exceeds that of the nano-sized TiO₂ under same experimental conditions. In addition, XRPD studies show three coordination polymers are structurally stable after one cycle of photodegradation and thus can be utilized repeatedly as photocatalysts.
- hydrothemal synthesis;coordination polymers;size-controlled;photocatalysis
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