Citation: LI Jun, WANG Lu-Xiang, CAO Ya-Li, JIA Dian-Zeng. Single Adsorption Capacity of Methylene Blue on ZnO/C Nanosphere:Equilibrium, Kinetics and Mechanism[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1603-1610. doi: 10.11862/CJIC.2016.213 shu

Single Adsorption Capacity of Methylene Blue on ZnO/C Nanosphere:Equilibrium, Kinetics and Mechanism

Key Laboratory of Energy Materials Chemistry, Ministry of Education, Key Laboratory of Advanced Functional Materials, Autonomous Region, Institute of Applied Chemistry, Xinjiang University, Urumqi 830046, China

Corresponding author: JIA Dian-Zeng, jdz@xju.edu.cn
Received Date: 30 March 2016
Revised Date: 24 August 2016

Figures(7)

Carbon-inorganic ZnO/C nanosphere hybrid materials was simply prepared by arc discharge method. The hybrid materials was characterized by field-emission scanning electron microscopy(FE-SEM), X-ray diffraction(XRD) and BET surface area. The adsorption property of methylene blue (MB) on ZnO/C nanosphere was carried out under the dark conditions. Results showed that the adsorption uptake increased as the increase of initial MB concentration and contact time, and the process reached equilibrium at the time of 150 min. Langmuir, Freundlich and Temkin isotherm were employed to describe the adsorption equilibrium. The isotherm study indicated that Langmuir model fitted well with the adsorption data, and a monolayer saturation capacity of 188.68 mg·g^-1 was obtained. Kinetic models, Webbers pore diffusion model and Boyds equation were applied for the experimental data to study the adsorption mechanism. Results shows that the kinetics followed the pseudo-second order kinetic model and the adsorption process was controlled by film diffusion as opposed intraparticle diffusion mechanism. The results indicate that the ZnO/C nanosphere is also a promising material for the adsorption of MB from aqueous solutions.
- ZnO/C nanosphere,
- carbon,
- nanomaterials,
- methylene blue,
- isotherm,
- kinetics
1. [1]
  Djilani C, Zaghdoudi R, Djazi F, et al. J. Taiwan Inst. Chem. E, 2015, 53:112-121 doi: 10.1016/j.jtice.2015.02.025
2. [2]
  Lin C H, Gung C H, Wu J Y, et al. J. Taiwan Inst. Chem. E, 2015, 51:119-126 doi: 10.1016/j.jtice.2015.01.019
3. [3]
  Islam M A, Benhouria A, Asif M, et al. J. Taiwan Inst. Chem. E, 2015, 52:57-64 doi: 10.1016/j.jtice.2015.02.010
4. [4]
  Jain A, Gupta V, Bhatnagar A. J. Hazard. Mater., 2003, 101: 31-42 doi: 10.1016/S0304-3894(03)00146-8
5. [5]
  Liu X, Niu C, Zhen X, et al. J. Colloid Interface Sci., 2015, 452:116-125 doi: 10.1016/j.jcis.2015.04.037
6. [6]
  LIU Jing-Liang, ZONG En-Min, CHEN Huan, et al. Chinese J. Inorg. Chem., 2015, 31(6):1105-1111
7. [7]
  Hameed B, El-Khaiary M. J. Hazard. Mater., 2008, 157:344-351 doi: 10.1016/j.jhazmat.2007.12.105
8. [8]
  Ahmad M A, Rahman N K. Chem. Eng. J., 2011, 170:154-161 doi: 10.1016/j.cej.2011.03.045
9. [9]
  LIU Hai-Di, LI Wei-Man, YUE Ren-Liang, et al. Chinese J. Inorg. Chem., 2013, 29:1787-1792
10. [10]
  Wang L, Zhang J, Zhao R, et al. Desalination, 2010, 254:68-74 doi: 10.1016/j.desal.2009.12.012
11. [11]
  Vargas A M, Cazetta A L, Kunita M H, et al. Chem. Eng. J., 2011, 170:154-161 doi: 10.1016/j.cej.2011.03.045
12. [12]
  Cherifi H, Fatiha B, Salah H. Appl. Surf. Sci., 2013, 282:52 -59 doi: 10.1016/j.apsusc.2013.05.031
13. [13]
  Vadivelan V, Kumar K V. J. Colloid Interface Sci., 2005, 286: 90-100 doi: 10.1016/j.jcis.2005.01.007
14. [14]
  Aboua K N, Yobouet Y A, Yao K B, et al. J. Environ. Manage., 2015, 156:10-14 doi: 10.1016/j.jenvman.2015.03.006
15. [15]
  Mezohegyi G, Van der Zee F P, Font J, et al. J. Environ. Manage., 2012, 102:148-164 doi: 10.1016/j.jenvman.2012.02.021
16. [16]
  Yin Y, Zhou S, Min C, et al. J. Colloid Interface Sci., 2011, 361:527-533 doi: 10.1016/j.jcis.2011.05.014
17. [17]
  Zhai Y, Dou Y, Liu X, et al. J. Mater. Chem., 2009, 19: 3292-3300 doi: 10.1039/b821945a
18. [18]
  Feng Y, Yang W, Wang N, et al. J. Anal. Appl. Pyrolysis, 2014, 107:204-210 doi: 10.1016/j.jaap.2014.02.021
19. [19]
  Dubey S P, Dwivedi A D, Kim I C, et al. Chem. Eng. J., 2014, 244:160-167 doi: 10.1016/j.cej.2014.01.042
20. [20]
  Liu S, Sun J, Huang Z. J. Hazard. Mater., 2010, 173:377-383 doi: 10.1016/j.jhazmat.2009.08.086
21. [21]
  Eder D, Windle A H. Adv. Mater., 2008, 20:1787-1793 doi: 10.1002/(ISSN)1521-4095
22. [22]
  Bu Q, Lei H, Wang L, et al. J. Anal. Appl. Pyrolysis, 2015, 112:74-79 doi: 10.1016/j.jaap.2015.02.019
23. [23]
  Velazquez-Jimenez L H, Hurt R H, Matos J, et al. Environ. Sci. Technol., 2013, 48:1166-1174
24. [24]
  Ahmad M, Ahmed E, Hong Z L, et al. Appl. Surf. Sci., 2013, 274:273-281 doi: 10.1016/j.apsusc.2013.03.035
25. [25]
  Zhou M, Gao X, Hu Y, et al. Appl. Catal. B, 2013, 138:1-8
26. [26]
  Li J, NgD H L, Song P, et al. Mater. Sci. Eng. B, 2015, 194: 1-8 doi: 10.1016/j.mseb.2014.12.007
27. [27]
  Le H A, Linh L T, Chin S, et al. Powder Technol., 2012, 225:167-175 doi: 10.1016/j.powtec.2012.04.004
28. [28]
  Murgolo S, Petronella F, Ciannarella R, et al. Catal. Today, 2015, 240:114-124 doi: 10.1016/j.cattod.2014.04.021
29. [29]
  Matos J, Montaña R, Rivero E. Environ. Sci. Pollut. Res., 2015, 22:784-791 doi: 10.1007/s11356-014-2832-9
30. [30]
  Langmuir I. J. Am. Chem. Soc., 1916, 38:2221-2295 doi: 10.1021/ja02268a002
31. [31]
  Freundlich H M F. J. Phys. Chem., 1906, 57:1100-1107
32. [32]
  Temkin M, Pyzhev V. Acta Physiochim. URSS, 1940, 12:217-222
33. [33]
  Weber T W. Chakravorti R K. AIChE J., 1974, 20:228-238 doi: 10.1002/aic.v20:2
34. [34]
  Kumar K V. J. Hazard. Mater., 2006, 137:1538-1544 doi: 10.1016/j.jhazmat.2006.04.036
35. [35]
  Ho Y S, McKay G. Chem. Eng. J., 1998, 70:115-124 doi: 10.1016/S0923-0467(98)00076-1
36. [36]
  Weber W J, Morris J C. AmSocCivEng, 1963, 89:31-60
37. [37]
  Goswami M, Borah L, Mahanta D, et al. J. Porous Mater., 2014, 21:1025-1034 doi: 10.1007/s10934-014-9852-1
38. [38]
  Hameed B, Ahmad A, Aziz N. Desalination, 2009, 247:551-560 doi: 10.1016/j.desal.2008.08.005
39. [39]
  Xiao H, Peng H, Deng S, et al. Bioresour. Technol., 2012, 111:127-133 doi: 10.1016/j.biortech.2012.02.054
40. [40]
  Zhong Z Y, Yang Q, Li X M, et al. Ind. Crops Prod., 2012, 37:178-185 doi: 10.1016/j.indcrop.2011.12.015
41. [41]
  Tan I A W, Ahmad A L, Hameed B H. J. Hazard. Mater., 2009, 164:473-482 doi: 10.1016/j.jhazmat.2008.08.025
42. [42]
  Acharya J, Sahu J, Sahoo B, et al. Chem. Eng. J., 2009, 150: 25-39 doi: 10.1016/j.cej.2008.11.035
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