Citation: JIAO Cheng-Qi, JIANG Wen-Jing, Wen WEN, REN Yi, WANG Jia-Liang, LIU Tao, HE Cheng. Tuning Assembly and Magnetic Interactions of Cyano-bridged Fe(Ⅲ)-Mn(Ⅱ) Bimetallic Chains[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1637-1646. doi: 10.11862/CJIC.2016.210 shu

Tuning Assembly and Magnetic Interactions of Cyano-bridged Fe(Ⅲ)-Mn(Ⅱ) Bimetallic Chains

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: LIU Tao, liutao@dlut.edu.cn
Received Date: 25 May 2016
Revised Date: 4 August 2016

Figures(7)

Two cyano-bridged Fe(Ⅲ)-Mn(Ⅱ) chains were synthesized via using bidentate ligands and cyanometallate building blocks with different steric hindrance. The magnetic interactions were adjusted by the structural distortions of the two compounds. Compound {[Fe(Ⅲ)(PzTp)(CN)₃][Mn(Ⅱ)(5,5′-dmbpy)₂]ClO₄}_n (1; PzTp=tetrakis(pyrazolyl)borate; 5,5′-dmbpy=5,5′-dimethyl-2, 2′-bipyridine) shows a 1D 2, 2-CC chain-like structure with a left-and right-handed helices chains and exhibits the ferrimagnetic behavior. Compound {[Fe(Ⅲ)(Tp^*)(CN)₃]₂[Mn(Ⅱ)(dpqc)]·CH₃OH·H₂O}_n (2; Tp^*=hydridotris(3, 5-dimethylpyrazolyl)borate; dpqc=dipyrido[3, 2-a:2′, 3′-c]-(6, 7, 8, 9-tetrahydro)phenazine) has a novel 1D 4, 2-ribbon double chain-like structure with dominant antiferromagnetic interactions. CCDC: 1449127, 1; 1449128, 2.
- cyano-bridged,
- chain,
- ferrimagnetic,
- antiferromagnetic
1. [1]
  Sato O, Iyoda T, Fujishima A, et al. Science, 1996, 272:704 -705 doi: 10.1126/science.272.5262.704
2. [2]
  Shatruk M, Avendano C, Dunbar K R. Prog. Inorg. Chem., 2009, 56:155-274
3. [3]
  Ohba M, kawa H. Coord. Chem. Rev., 2000, 198:313-328 doi: 10.1016/S0010-8545(00)00233-2
4. [4]
  Wang S, Ding X H, Li Y H, et al. Coord. Chem. Rev., 2012, 256:439-464 doi: 10.1016/j.ccr.2011.10.029
5. [5]
  Wang S, Ding X H, Zuo J L, et al. Coord. Chem. Rev., 2011, 255:1713-1732 doi: 10.1016/j.ccr.2011.01.057
6. [6]
  Caneschi A, Gatteschi D, Lalioti N, et al. Angew. Chem. Int. Ed., 2001, 40:1760-1763 doi: 10.1002/(ISSN)1521-3773
7. [7]
  Coulon C, Miyasaka H, Clerac R. Struct. Bond., 2006, 122: 163-206 doi: 10.1007/b104234
8. [8]
  Miyasaka H, Julve M, Yamashita M, et al. Inorg. Chem., 2009, 48:3420-3437 doi: 10.1021/ic802050j
9. [9]
  Sun H L, Wang Z M, Gao S. Coord. Chem. Rev., 2010, 254: 1081-1100 doi: 10.1016/j.ccr.2010.02.010
10. [10]
  Lescouëzec R, Toma L M, Vaissermann J, et al. Coord. Chem. Rev., 2005, 249:2691-2729 doi: 10.1016/j.ccr.2005.09.017
11. [11]
  Nihei M, Ui M, Yokota M, et al. Angew. Chem. Int. Ed., 2005, 44:6484-6487 doi: 10.1002/(ISSN)1521-3773
12. [12]
  Shen X P, Zhou H B, Yan J H, et al. Inorg. Chem., 2014, 53:116-127 doi: 10.1021/ic401753y
13. [13]
  Liu T, Zhang Y J, Kanegawa S, et al. J. Am. Chem. Soc., 2010, 132:8250-8251 doi: 10.1021/ja1027953
14. [14]
  Wen H R, Wang C F, Zuo J L, et al. Inorg. Chem., 2006, 45: 582-590 doi: 10.1021/ic0511468
15. [15]
  Kim J I, Kwak H Y, Yoon J H, et al. Inorg. Chem., 2009, 48:2956-2966 doi: 10.1021/ic802033q
16. [16]
  Dong D P, Liu T, Kanegawa S, et al. Angew. Chem. Int. Ed., 2012, 51:5119-5123 doi: 10.1002/anie.201105987
17. [17]
  Liu T, Zheng H, Kang S, et al. Nat. Commun., 2013, 4:2826 -2833
18. [18]
  Shao D, Zhang S L, Zhao X H, et al. Chem. Commun., 2015,51:4360-4363 doi: 10.1039/C4CC10003D
19. [19]
  Hoshino N, Iijima F, Newton G N, et al. Nat. Chem., 2012, 4:921-926 doi: 10.1038/nchem.1455
20. [20]
  Liu W, Wang C F, Li Y Z, et al. Inorg. Chem., 2006, 45: 10058-10065 doi: 10.1021/ic061347r
21. [21]
  Zhang Y Z, Mallik U P, Clérac R, et al. Polyhedron, 2013, 52:115-121 doi: 10.1016/j.poly.2012.10.039
22. [22]
  Zhang Y Z, Ferko P, Siretanu D, et al. J. Am. Chem. Soc., 2014, 136:16854-16864 doi: 10.1021/ja508280n
23. [23]
  Wen H R, Tang Y Z, Liu C M, et al. Inorg. Chem., 2009, 48: 10177-10185 doi: 10.1021/ic901224f
24. [24]
  Kwak H Y, Ryu D W, Lee J W, et al. Inorg. Chem., 2010, 49:4632-4642 doi: 10.1021/ic100301q
25. [25]
  Dong D P, Zhang Y J, Zheng H, et al. Dalton Trans., 2013, 42:7693-7698 doi: 10.1039/c3dt50273b
26. [26]
  Wen H R, Wang C F, Song Y, et al. Inorg. Chem., 2006, 45: 8942-8949 doi: 10.1021/ic060928d
27. [27]
  Mitsumoto K, Ui M, Nihei M, et al. CrystEngComm, 2010, 12:2697-2699 doi: 10.1039/c004351f
28. [28]
  Kim J, Han S J, Cho I-K, et al. Polyhedron, 2004, 23:1333-1339 doi: 10.1016/j.poly.2004.02.026
29. [29]
  Li D F, Parkin S, Wang G B, et al. Inorg. Chem., 2005, 44: 4903-4905 doi: 10.1021/ic048367i
30. [30]
  Jiang L, Feng X L, Lu T B, et al. Inorg. Chem., 2006, 45: 5018-5026 doi: 10.1021/ic052168x
31. [31]
  Gheorghe R, Kalisz M, Clérac R, et al. Inorg. Chem., 2010, 49:11045-11056 doi: 10.1021/ic1015725
32. [32]
  Pardo E, Verdaguer M, Herson P, et al. Inorg. Chem., 2011, 50:6250-6262 doi: 10.1021/ic200616p
33. [33]
  ZHENG Hui, XU Yang, DUAN Chun-Ying. Chinese J. Inorg. Chem., 2015, 31 (7):1460-1466
34. [34]
  Wang S, Zuo J L, Zhou H C, et al. Eur. J. Inorg. Chem., 2004, 3681-3687
35. [35]
  Ni Z H, Kou H Z, Zhang L F, et al. Angew. Chem. Int. Ed., 2005, 44:7742-7745 doi: 10.1002/(ISSN)1521-3773
36. [36]
  Costa V, Lescouëzec R, Vaissermann J, et al. Inorg. Chim. Acta, 2008, 361:3912-3918 doi: 10.1016/j.ica.2008.03.044
37. [37]
  Gu Z G, Liu W, Yang Q F, et al. Inorg. Chem., 2007, 46: 3236-3244 doi: 10.1021/ic062267q
38. [38]
  Ma L L, Ge K, Zhang R, et al. Eur. J. Med. Chem., 2014, 87:624-630 doi: 10.1016/j.ejmech.2014.10.002
39. [39]
  SMART, SAINT and XPREP, Area Detectr and Data Integration and Reduction Software, Bruker Analytical Instruments Inc. , Madison, WI, 1995.
40. [40]
  Sheldrick G M. SHELXS-97, Program for X-ray Crystal Structure Solution and Refinement, University of Göttingen, Germany, 1997.
41. [41]
  Borrás-Almenar J J, Clemente-Juan J M, Coronado E, et al. MAGPACK, J. Comput. Chem., 2001, 22:985-991 doi: 10.1002/jcc.1059
42. [42]
  Kou H Z, Ni Z H, Liu C M, et al. New J. Chem., 2009, 33: 2296-2299 doi: 10.1039/b9nj00316a
1. [1]
  Yifei Zhang , Yuncong Xue , Laiwei Gao , Rui Liao , Feng Wang , Fei Wang . Merging non-covalent and covalent crosslinking: En route to single chain nanoparticles. Chinese Chemical Letters, 2024, 35(6): 109217-. doi: 10.1016/j.cclet.2023.109217
2. [2]
  Haoran Shi , Jiaxin Wang , Yuqin Zhu , Hongyang Li , Guodong Ju , Lanlan Zhang , Chao Wang . Highly selective α-C(sp³)-H arylation of alkenyl amides via nickel chain-walking catalysis. Chinese Chemical Letters, 2024, 35(7): 109333-. doi: 10.1016/j.cclet.2023.109333
3. [3]
  Jaeyong Ahn , Zhenping Li , Zhiwei Wang , Ke Gao , Huagui Zhuo , Wanuk Choi , Gang Chang , Xiaobo Shang , Joon Hak Oh . Surface doping effect on the optoelectronic performance of 2D organic crystals based on cyano-substituted perylene diimides. Chinese Chemical Letters, 2024, 35(9): 109777-. doi: 10.1016/j.cclet.2024.109777
4. [4]
  Yanbing Shen , Yuan Yuan , Yaxin Wang , Xiaonan Ma , Wensheng Yang , Yulan Chen . Dihydroanthracene bridged bis-naphthopyrans: A multimodal chromophore with mechano- and photo-chromic properties. Chinese Chemical Letters, 2024, 35(5): 108949-. doi: 10.1016/j.cclet.2023.108949
5. [5]
  Hui-Juan Wang , Wen-Wen Xing , Zhen-Hai Yu , Yong-Xue Li , Heng-Yi Zhang , Qilin Yu , Hongjie Zhu , Yao-Yao Wang , Yu Liu . Cucurbit[7]uril confined phenothiazine bridged bis(bromophenyl pyridine) activated NIR luminescence for lysosome imaging. Chinese Chemical Letters, 2024, 35(6): 109183-. doi: 10.1016/j.cclet.2023.109183
6. [6]
  Dan Luo , Jinya Tian , Jianqiao Zhou , Xiaodong Chi . Anthracene-bridged "Texas-sized" box for the simultaneous detection and uptake of tryptophan. Chinese Chemical Letters, 2024, 35(9): 109444-. doi: 10.1016/j.cclet.2023.109444
7. [7]
  Jing Wang , Zenghui Li , Xiaoyang Liu , Bochao Su , Honghong Gong , Chao Feng , Guoping Li , Gang He , Bin Rao . Fine-tuning redox ability of arylene-bridged bis(benzimidazolium) for electrochromism and visible-light photocatalysis. Chinese Chemical Letters, 2024, 35(9): 109473-. doi: 10.1016/j.cclet.2023.109473

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(296)
HTML views(26)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142