Citation: LI Ai-Chang, SONG Min, ZHAO Sha-Sha, GUO Ying-Jie. Photoelectrocatalytic Property and Reaction Mechanism of Ag@AgBr/Ni Thin Films at Negative Bias for Rhodamine B[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1543-1551. doi: 10.11862/CJIC.2016.205 shu

Photoelectrocatalytic Property and Reaction Mechanism of Ag@AgBr/Ni Thin Films at Negative Bias for Rhodamine B

Faculty of chemistry and Material Science, Langfang Teachers College, Langfang, Hebei 065000, China

Corresponding author: LI Ai-Chang, aichangli@hotmail.com
Received Date: 11 March 2016
Revised Date: 31 July 2016

Figures(11)

Ag@AgBr/Ni thin films plasmonic photocatalyst were prepared by electrochemical method. The surface morphology, phase structure, optical characteristics of the thin films were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS), respectively. Its photoelectrocatalytic properties and stability at negative bias under visible light were evaluated with rhodamine B (RhB) as a model compound. Using eletrochemical technique and a method of adding active species scavenger to the solution, mechanism of photoelectrocatalytic degradation of the films were explored. The results show that the Ag@AgBr/Ni thin film prepared under optimum condition are composed of AgBr microparticles whose surface has silver nanoparticles with a significant surface plasmon resonance (SPR) effects. The Ag@AgBr/Ni film is photoelectrocatalytically more active than TiO₂/ITO (indium tin oxide) film. At optimum cathodic bias and under visible light irradiation in 12 min, the photoelectrocatalytic degradation rate of Ag@AgBr/Ni film is 10.2 times as much as that of porous TiO₂(Degussa P25)/ITO film. Compared with no cathodic bias, the photoeletrocatalytic degradation rate of the Ag@AgBr/Ni thin film to RhB is increased by 2.0 times and the thin film has obvious photoelectric synergistic effect. The photoelectrocatalytic activity almost kept unchanged after five recycled experiments. The improvement in photoelectrocatalytic activity for Ag@AgBr/Ni thin films could be mainly attributed to the activation of nano Ag particles on the electrode for photocathode reaction (Conduction band reaction) with a significant SPR effects. Furthermore, the photoelctrocatalytic reaction mechanism of Ag@AgBr/Ni thin films for RhB at negative bias was proposed.
- Ag@AgBr/Ni thin film,
- surface plasmon resonance,
- photoelectrocatalysis,
- rhodamine B,
- reaction mechanism
1. [1]
  Tong H, Ouyang S, Bi Y, et al. Adv. Mater., 2012, 24(2):229-251 doi: 10.1002/adma.201102752
2. [2]
  HU Teng, YE Long-Qiang, LI Wen-Ling, et al. Chinese J. Inorg. Chem., 2014, 30 (8):1778-1782
3. [3]
  Zhang J, Wu Y, Xing M, et al. Energy Environ. Sci., 2010, 3: 715-726 doi: 10.1039/b927575d
4. [4]
  Addamo M, Augugliaro V, García-López E, et al. Catal. Today, 2005, 107/108:612-618 doi: 10.1016/j.cattod.2005.07.030
5. [5]
  Zou Z, Ye J, Sayama K, et al. Nature, 200l, 414(6864):625-627 doi: 10.1038/414625a
6. [6]
  LU Fei, MENG, Fan-Ming. Bull. Chin. Ceram. Soc., 2011, 30(1):116-119
7. [7]
  Wang P, Huang B, Dai Y, et al. Phys. Chem. Chem. Phys., 2012, 14:9813-9825 doi: 10.1039/c2cp40823f
8. [8]
  Wang Z, Liu Y, Huang B, et al. Phys. Chem. Chem. Phys., 2014, 16:2758-2774 doi: 10.1039/c3cp53817f
9. [9]
  Lou Z, Wang Z, Huang B, et al. ChemCatChem, 2014, 6:2456-2476 doi: 10.1002/cctc.201402261
10. [10]
  Tong H, Ouyang S, Bi Y, et al. Adv. Mater., 2012, 24:229-251 doi: 10.1002/adma.201102752
11. [11]
  Burda C, Chen X, Narayanan R, et al. Chem. Rev., 2005, 105(4):1025-1102 doi: 10.1021/cr030063a
12. [12]
  Brus L. Acc. Chem. Res., 2008, 41(12):1742-1749 doi: 10.1021/ar800121r
13. [13]
  ZHU Ming-Shan, CHEN Peng-Lei, LIU Ming-Hua. Prog. Chem., 2013, 25(2/3): 210-220
14. [14]
  Wang P, Huang B B, Qin X Y, et al. Angew. Chem., Int. Ed., 2008, 47:7931-7933 doi: 10.1002/anie.v47:41
15. [15]
  Wang P, Huang B B, Zhang X Y, et al. Chem. Eur. J., 2009, 15:1821-1824 doi: 10.1002/chem.v15:8
16. [16]
  Zhu M S, Chen P L, Liu M H. ACS Nano, 2011, 5(6):4529-4536 doi: 10.1021/nn200088x
17. [17]
  Kuai L, Geng B Y, Chen X T, et al. Langmuir, 2010, 26(24): 18723-18727 doi: 10.1021/la104022g
18. [18]
  AN Wei-Jia, LIU Li, LI XIN-Lei, et al. Chinese J. Inorg. Chem., 2015, 31(2): 329-337
19. [19]
  LENG Wen-Hua, ZHU Hong-Qiao. J. Electrochem., 2013, 19(5):437-443
20. [20]
  YANG Juan, DAI Jun, ZAO Jin-Cai, et al. Chin. Sci. Bull., 2009, 54:2196-2204
21. [21]
  Yang J, Chen C, Ji H, et al. J. Phys. Chem. B, 2005, 109: 21900-21907 doi: 10.1021/jp0540914
22. [22]
  YANG Juan, MIU Juan, DAI Jun, et al. J. Henan Polytechnic Univ., 2010, 29: 259-265 doi: 10.3969/j.issn.1673-9787.2010.02.024
23. [23]
  JI Hong-Wei, MA Wan-Hong, HUANG Ying-Ying, et al. Chin. Sci. Bull., 2003, 48:2199-2204 doi: 10.3321/j.issn:0023-074X.2003.21.001
24. [24]
  LI Ai-Chang, LI Jian-Fei, LIU Ya-Lu, et al. Acta Chim. Sinica, 2013, 71(5):815-821
25. [25]
  YANG Yong-Biao, ZHANG Zheng-Fu, CHEN Qing-Hua, et al. Yunnan Metallurge, 2004, 33(4):20-22
26. [26]
  LI Ai-Chang, ZHU Ning-Ning, LI Jing-Hong, et al. Chinese J. Inorg. Chem., 2015, 31(4):681-688
27. [27]
  Wang D, Duan Y, Luo Q, et al. Desalination, 2011, 270:174-180 doi: 10.1016/j.desal.2010.11.042
28. [28]
  Zhu M, Chen P, Liu M. Langmuir, 2012, 28:3385-3390 doi: 10.1021/la204452p
29. [29]
  HU Jin-Shan, WANG Huan, LIU Li, et al. J. Mol. Catal., 2013, 27(5):452-458
30. [30]
  Zhou X, Liu G, Yu J, et al. J. Mater. Chem., 2012, 22:21337-21354 doi: 10.1039/c2jm31902k
31. [31]
  Rycenga M, Cobley C M, Zeng J, et al. Chem. Rev., 2011, 111:3669-3712 doi: 10.1021/cr100275d
32. [32]
  LIU Hua-Jun, PENG Tian-You, PENG Zheng-He, et al. J. Wuhan Univ.: Nat. Sci. Ed., 2007, 53(2):127-132
33. [33]
  NIE Long-Hui, HUANG Zheng-Qing, XU Hong-Tao, et al. Chin. J. Catal., 2012, 33 (7):1209-1216
34. [34]
  LI Ai-Chang, LI Gui-Hua, ZHENG Yan, et al. Acta Phys.-Chim. Sin., 2012, 28 (2):457-464
35. [35]
  ZHOU Li, DENG Hui-Ping, ZHANG Wei. Prog. Chem., 2015, 27(4):349-360
1. [1]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
2. [2]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
3. [3]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
4. [4]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
5. [5]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
6. [6]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
7. [7]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
8. [8]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
9. [9]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
10. [10]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
11. [11]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
12. [12]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
13. [13]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
14. [14]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
15. [15]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
16. [16]
  Jiaqi AN , Yunle LIU , Jianxuan SHANG , Yan GUO , Ce LIU , Fanlong ZENG , Anyang LI , Wenyuan WANG . Reactivity of extremely bulky silylaminogermylene chloride and bonding analysis of a cubic tetragermylene. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1511-1518. doi: 10.11862/CJIC.20240072
17. [17]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
18. [18]
  Zhenhao Wang , Yuliang Tang , Ruyu Li , Shuai Tian , Yu Tang , Dehai Li . Bioinspired synthesis of cochlearol B and ganocin A. Chinese Chemical Letters, 2024, 35(7): 109247-. doi: 10.1016/j.cclet.2023.109247
19. [19]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
20. [20]
  Jun-Jie Fang , Zheng Liu , Yun-Peng Xie , Xing Lu . Superatomic Ag₅₈ nanoclusters incorporating a [MS₄@Ag₁₂]²⁺ (M = Mo or W) kernel show aggregation-induced emission. Chinese Chemical Letters, 2024, 35(10): 109345-. doi: 10.1016/j.cclet.2023.109345

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(1050)
HTML views(152)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142