Citation: ZHAO Su-Qin, GU Jin-Zhong. Syntheses, Crystal Structures and Magnetic Properties of Mn(Ⅱ) and Ni(Ⅱ)Dinuclear Coordination Compounds Constructed from Biphenyl-2, 4, 4′-Tricarboxylate and Phenanthroline[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1611-1618. doi: 10.11862/CJIC.2016.203 shu

Syntheses, Crystal Structures and Magnetic Properties of Mn(Ⅱ) and Ni(Ⅱ)Dinuclear Coordination Compounds Constructed from Biphenyl-2, 4, 4′-Tricarboxylate and Phenanthroline

ZHAO Su-Qin ^1,*,, ,
GU Jin-Zhong ^2,*,,

1.
College of Physics and Electronic Information Engineering, Qinghai University for Nationalities, Xining 810007, China
2.
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: ZHAO Su-Qin, qhzhsq@sina.com GU Jin-Zhong, gujzh@lzu.edu.cn
Received Date: 16 April 2016
Revised Date: 22 July 2016

Figures(9)

Two coordination compounds, namely [Mn₂(Hbtc)₂(phen)₄]·5H₂O (1) and [Ni₂(Hbtc)₂(phen)₄]·2H₃btc·4H₂O (2) have been constructed hydrothermally using H₃btc(H₃btc=biphenyl-2, 4, 4′-tricarboxylic acid), phen (phen =phenanthroline), MnCl₂·4H₂O and NiCl₂·6H₂O. Both compounds crystallize in the triclinic system, space group P1. The compounds possess the dinuclear structures, which are further extended into the 3D supramolecular frameworks through O-H…O hydrogen bonding. Magnetic studies for compounds 1 and 2 show a weak antiferro-magnetic coupling between the neighbouring metal centers, with J=-3.82 cm^-1 (1) and -2.35 cm^-1 (2). CCDC: 1456513, 1; 1456514, 2.
- coordination compound,
- Mn(Ⅱ)compound,
- Ni(Ⅱ)compound,
- magnetic properties
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