Citation: ZOU Xiao-Chuan, SHI Kai-Yun, WANG Cun, WANG Yue, DENG Chao-Fang, REN Yan-Rong, WANG Gui-Feng, TAN Zhi-Wen, FU Xiang-Kai. Immobilization of Chiral Mn^Ⅲ(Salen) on Phenoxyl Group Modified Zirconium Poly (Styrene-Isopropenyl Phosphonate)-Phosphate and Catalytic Performance for Epoxidation of Styrene[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1585-1595. doi: 10.11862/CJIC.2016.199 shu

Immobilization of Chiral Mn^Ⅲ(Salen) on Phenoxyl Group Modified Zirconium Poly (Styrene-Isopropenyl Phosphonate)-Phosphate and Catalytic Performance for Epoxidation of Styrene

1.
Department of Biological and Chemical Engineering, Chongqing University of Education, Chongqing 400067, China
2.
College of Chemistry and Chemical Engineering, Research Institute of Applied Chemistry, Key Laboratory of Applied Chemistry of Chongqing Municipality, Key Laboratory of Eco-environments in Three Gorges Reservoir Region Ministry of Education Southwest University, Chongqing 400715, China

Corresponding author: SHI Kai-Yun, shiky@cque.edu.cn
Received Date: 14 April 2016
Revised Date: 26 July 2016

Figures(10)

A series of chiral Mn^Ⅲ(Salen) catalysts that were axially supported onto zirconium poly (styrene-isopropenyl phosphonate)-phosphate(ZPS-IPPA) through phenoxyl linkers have been developed, and their performance as catalysts for the epoxidation of styrene has been evaluated. The catalytic results indicated that the substituents at the o-positions of the phenoxyl linkers have a critical impact on the catalytic activity, in that the o-t-Bu group provided higher levels of enantioselectivity than the o-H and o-CH₃ groups of the phenoxyl linker. At the same time, two linkages (-NH-C₆H₄-NH-, -O-C₆H₄-O-) with similar length were compared, the results demonstrated that the linkage of -O-C₆H₄-O- have more positive effect than the use of -NH-C₆H₄-NH-in absence of NMO in m-CPBA oxidant systems on the catalytic efficiency. Furthermore, the catalysts could be recycled up to five times without any significant reduction in their catalytic activity or enantioselectivity.
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Immobilization of Chiral MnⅢ(Salen) on Phenoxyl Group Modified Zirconium Poly (Styrene-Isopropenyl Phosphonate)-Phosphate and Catalytic Performance for Epoxidation of Styrene

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通讯作者: 陈斌, bchen63@163.com

Immobilization of Chiral Mn^Ⅲ(Salen) on Phenoxyl Group Modified Zirconium Poly (Styrene-Isopropenyl Phosphonate)-Phosphate and Catalytic Performance for Epoxidation of Styrene