Citation: LI Xue, DI Ke-Shu, YAO Shuang, YAN Jing-Hui, KANG Zhen-Hui. Hydrothermal Synthesis and Luminescent Properties of GdVO₄:Ln³⁺ (Ln=Eu, Tm, Dy) Phosphor[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1512-1518. doi: 10.11862/CJIC.2016.193 shu

Hydrothermal Synthesis and Luminescent Properties of GdVO₄:Ln³⁺ (Ln=Eu, Tm, Dy) Phosphor

LI Xue ¹ ,
DI Ke-Shu ¹ ,
YAO Shuang ^1,*,, ,
YAN Jing-Hui ^1,*,, ,
KANG Zhen-Hui ²

1.
School of Chemical and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, China
2.
Institute of Functional Nano & Soft Materials, Soochow University, Suzhou, Jiangsu 215123, China

Corresponding author: YAO Shuang, yaoshuang@cust.edu.cn YAN Jing-Hui, yjh@cust.edu.cn
Received Date: 22 December 2015
Revised Date: 22 June 2016

Figures(10)

A series of GdVO₄:Dy³⁺, GdVO₄:Dy³⁺, Eu³⁺ and GdVO₄:Dy³⁺, Eu³⁺, Tm³⁺ phosphors were synthesized by the facile hydrothermal method using EDTA as mineralizer. The phase structure, morphology, photoluminescence properties, the energy transfer from Dy³⁺ to Eu³⁺ ions and the ⁴F_9/2→6_15/2^H transition of the Dy³⁺ ion in GdVO₄:0.03Dy³⁺, xEu³⁺ phosphors have been investigated in detail. The X-ray diffraction (XRD) patterns reveal that GdVO₄:0.03Dy³⁺, GdVO₄:0.03Dy³⁺, 0.07Eu³⁺ and GdVO₄:0.03Dy³⁺, 0.07Eu³⁺, 0.07Tm³⁺ phosphors have pure tetragonal crystal structure. The GdVO₄:0.03Dy³⁺, 0.07Eu³⁺ and GdVO₄:0.03Dy³⁺, 0.07Eu³⁺, 0.07Tm³⁺ phosphors are nanorod morphology with a mean length of about 0.458 and 0.491 μm as shown in the SEM images. By studying the decay times of GdVO₄:Dy³⁺, Eu³⁺ phosphors, the energy transfer process from Dy³⁺ to Eu³⁺ was proved. And the mechanism of energy transfer is proved to be the dipole-dipole (d-d) interaction. By adjusting the concentration of Eu³⁺ in the GdVO₄:0.03Dy³⁺, xEu³⁺ phosphors, the quasi white light (0.424, 0.350) is obtained. By adjusting the concentration of Tm³⁺ in the GdVO₄:0.03Dy³⁺, 0.07Eu³⁺, yTm³⁺ phosphors, the white light (0.346, 0.301) is obtained.
- hydrothermal method,
- GdVO₄,
- energy-transfer,
- white light emitting diode
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Hydrothermal Synthesis and Luminescent Properties of GdVO₄:Ln³⁺ (Ln=Eu, Tm, Dy) Phosphor