Citation: YE Dan-Dan, WANG Lei, GU Xiao-Min, NI Liang, ZHANG Wen-Li. Two POMs-Modified Transition Metal Compounds Constructed by Rigid Ligands:Structures, Catalytic and Electrochemical Properties[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1629-1636. doi: 10.11862/CJIC.2016.189 shu

Two POMs-Modified Transition Metal Compounds Constructed by Rigid Ligands:Structures, Catalytic and Electrochemical Properties

School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China

Corresponding author: ZHANG Wen-Li, wlzhang@ujs.edu.cn
Received Date: 5 May 2016
Revised Date: 23 June 2016

Figures(5)

By utilizing two kinds of simply rigid organic ligands, two new polyoxometalates-modified transition metal compounds (POMs-TMC), [Cu(dmbipy)₂(SiW₁₂O₄₀)][Cu(dmbipy)(H₂O)₃]·3H₂O(1), and {(Hdmphen)₂[Ag₂(dmphen)₂(SiW₁₂O₄₀)]}_n(2) (dmbipy=4, 4′-dimethyl-2, 2′-bipyridine, dmphen=2, 9-dimethyl-1, 10-phenanthrolin), were synthesized through hydrothermal technique. In compound 1, there are two crystallographically independent Cu(Ⅱ) ions. They all exhibit penta-coordinated modes, with three water molecules embedding through Cu-O bonds. Different Cu(Ⅱ) subunits cross-link each other to build a 1D chain by hydrogen bonding interactions between coordinated water molecules and [SiW₁₂O₄₀]^4- anions. Adjacent chains also pursue to construct a 2D layer by such hydrogen bonding. In compound 2, the Keggin anions are fused by Ag(Ⅱ) ions to form a 1D chain. The adjacent chains are further linked by π…π stacking and hydrogen bonding interactions. So, 2D polyoxometalates-modified organic layer is constructed. The main traits of compounds 1 and 2 are that these simply rigid organic ligands employ noncovalent interactions to form the 2D layer. CCDC: 1033952, 1; 1053009, 2.
- polyoxometalates,
- transition metal compound,
- catalytic activity,
- electrochemical property
1. [1]
  Zhou J, Zhao J W, Wei Q, et al. J. Am. Chem. Soc., 2014, 136(13):5065-5071 doi: 10.1021/ja413218w
2. [2]
  Han X B, Li Y G, Zhang Z M, et al. J. Am. Chem. Soc., 2015, 137(16):5486-5493 doi: 10.1021/jacs.5b01329
3. [3]
  Suzuki K, Tang F, Kikukawa Y, et al. Angew. Chem. Int. Ed., 2014, 53(21):5356-5360 doi: 10.1002/anie.v53.21
4. [4]
  Tian A X, Ning Y L, Ying J, et al. Dalton Trans., 2015, 44 (22):10499-10507 doi: 10.1039/C5DT00903K
5. [5]
  Tian A X, Yang Y, Ying J, et al. Dalton Trans., 2014, 43(22): 8405-8413 doi: 10.1039/c4dt00107a
6. [6]
  Wang L, Shan Y X, Jiang Y H, et al. J. Inorg. Organomet. Polym., 2014, 24(6):954-962 doi: 10.1007/s10904-014-0088-y
7. [7]
  Ma H X, Du J, Zhu Z M, et al. Dalton Trans., 2016, 45(4): 1631-1637 doi: 10.1039/C5DT04412J
8. [8]
  Artetxe B, Reinoso S, San Felices L, et al. Inorg. Chem., 2015, 54(1):241-252 doi: 10.1021/ic502232v
9. [9]
  Wang X L, Li N, Tian A X, et al. Inorg. Chem., 2014, 53 (14):7118-7129 doi: 10.1021/ic403153f
10. [10]
  Wang X, Duan X Y, Kong C Y, et al. J. Coord. Chem., 2016, 69(5):779-787 doi: 10.1080/00958972.2016.1139105
11. [11]
  Sheldrick G M. SHELXS-97, Program for Automatic Solution of Crystal Structure, University of Göttingen, Germany, 1997.
12. [12]
  Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Germany, 1997.
13. [13]
  Wang X L, Xu C, Lin H Y, et al. CrystEngComm, 2012, 14 (18):5836-5844 doi: 10.1039/c2ce25371b
14. [14]
  WANG Lei, GU Xiao-Ming, YE Dan-Dan, et al. Chinese J. Inorg. Chem., 2016, 32(4): 691-698
15. [15]
  Zhang Z, Yang J, Liu Y Y, et al. CrystEngComm, 2013, 15 (19):3843-3853 doi: 10.1039/c3ce40210j
16. [16]
  Wang L, Shan Y X, Gu X M, et al. J. Coord. Chem., 2015, 68(11):2014-2028 doi: 10.1080/00958972.2015.1035652
17. [17]
  Tian A X, Ning Y L, Ying J, et al. CrystEngComm, 2015, 17 (29): 5569-5578 doi: 10.1039/C5CE00768B
18. [18]
  Tian A X, Hou X, Ying J, et al. RSC Adv., 2015, 5(66): 53757-53765 doi: 10.1039/C5RA07107K
1. [1]
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2. [2]
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3. [3]
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4. [4]
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5. [5]
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6. [6]
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7. [7]
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8. [8]
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9. [9]
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10. [10]
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11. [11]
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12. [12]
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13. [13]
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14. [14]
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15. [15]
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16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
  Jian Ji , Jie Yan , Honggen Peng . Modulation of dinuclear site by orbital coupling to boost catalytic performance. Chinese Journal of Structural Chemistry, 2024, 43(8): 100360-100360. doi: 10.1016/j.cjsc.2024.100360

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