Citation: GENG Kai-Ming, WU Jun-Jie, GENG Hong-Bo, HU Ya-Yun, QU Gen-Long, PAN Yue, ZHENG Jun-Wei, GU Hong-Wei. N-Doped Carbon-Encapsulated Cobalt Nanoparticles on N-Doped Graphene Nanosheets as a High-Capacity Anode Material for Lithium-Ion Storage[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1495-1502. doi: 10.11862/CJIC.2016.173 shu

N-Doped Carbon-Encapsulated Cobalt Nanoparticles on N-Doped Graphene Nanosheets as a High-Capacity Anode Material for Lithium-Ion Storage

1.
Key Laboratory of Organic Synthesis of Jiangsu Province; College of Chemistry, Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, Jiangsu 215123, China
2.
College of Physics, Optoelectronics and Energy, Soochow University, Suzhou, Jiangsu 215123, China

Corresponding author: GU Hong-Wei, hongwei@suda.edu.cn
Received Date: 18 March 2016
Revised Date: 23 May 2016

Figures(5)

A graphene-based anode material is demonstrated: N-doped carbon-encapsulated cobalt nanoparticles on N-doped graphene nanosheets (NC@Co@NG), in which cobalt nanoparticles encapsulated by N-doped carbon layer are highly dispersed on the N-doped graphene nanosheets, forming multiple sites for electrical conductivity enhancement and lithium insertion. When used as anode materials in lithium-ion batteries, the nanocomposites exhibit outstanding electrochemical performance, including a considerably large reversible capacity of 950.1 mAh·g^-1 after 200 cycles at a current density of 100 mA·g^-1 and Coulombic efficiency of 98%.
- cobalt nanoparticles,
- N-doping graphene,
- anodes,
- lithium-ion batteries
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