Citation: ZHANG Qi-Long, WANG Huan-Yu, JIANG Feng, FENG Guang-Wei, XU Hong, HUANG Ya-Li. Syntheses, Crystal Structures and Bacteriostatic Activities of Ni (Ⅱ) and Cu (Ⅱ) Complexes Based on Pentaerythrityltetramine Schiff Base[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(3): 464-468. doi: 10.11862/CJIC.2016.056 shu

Syntheses, Crystal Structures and Bacteriostatic Activities of Ni (Ⅱ) and Cu (Ⅱ) Complexes Based on Pentaerythrityltetramine Schiff Base

Department of Chemistry, Guizhou Medical University, Guizhou, Guiyang 550004, China

Corresponding author: ZHANG Qi-Long, gzuqlzhang@126.com
Received Date: 12 November 2015
Revised Date: 30 December 2015

Figures(4)

The Schiff base compound H₄L was synthesized from condensation reaction of 4-Methoxysalicylaldeh-yde with Pentaerythrityltetramine. H₄L was reacted with Ni (ClO₄)₂·6H₂O or Cu (ClO₄)₂·6H₂O to give two complexes [Ni₂(L)]·DMF (1) and [Cu₄(L)₂(DMSO)₃]·2DMSO (2). The complexes were characterized by elemental analysis, FT-IR and single crystal X-ray diffraction. The crystals of 1 and 2 belong to the triclinic system, space group P1. The complexes 1 and 2 are all binuclear complexes. The In vitro bacteriostatic activities of the ligand and complexes were tested against several kinds of bacteria. The results show that the ligand and complexes possess different bacteriostatic activities to S. aureus. CCDC: 1436577, H₄L; 1436578, 1; 1436576, 2.
- Schiff base,
- Ni (Ⅱ) complex,
- Cu (Ⅱ) complex,
- crystal structure,
- bacteriostatic activity
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