Hydrothermal Syntheses, Crystal Structures and Properties of Cadmium (Ⅱ)/Copper (Ⅱ) Complexes with Acylhydrazone and Phenanthroline Ligands
- Corresponding author: XIE Qing-Fan, xqf360@163.com
Citation: CHEN Yan-Min, WANG Jing-Mei, CHEN Fei-Peng, CHEN Ya-Xin, ZENG Qian-Ru, XIE Qing-Fan. Hydrothermal Syntheses, Crystal Structures and Properties of Cadmium (Ⅱ)/Copper (Ⅱ) Complexes with Acylhydrazone and Phenanthroline Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(3): 434-440. doi: 10.11862/CJIC.2016.043
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H atoms were omitted for clarity; Symmetry code: ⅰ-x+1, y, -z+1/2
H atoms were omitted for clarity
H atoms were omitted for clarity; In (a): Cg2…Cg3ⅱ: 0.364 4 nm; C3-H3…O2ⅱ: 0.244 0 nm, 144°; Symmetry code: ⅱ 1-x, 1-y, 1-z; In (b): C23-H23A…Cg1ⅲ: 0.308 2 nm, 140°; Symmetry code: ⅲ 1.5-x, 0.5-y, 1-z
Cg1: N1/C1/C2/C3/C4/C12; Cg2: C4/C5/C6/C7/C11/C12; Cg2…Cg2ⅰ: 0.348 07(6) nm; Cg1…Cg1ⅱ: 0.339 0 nm; Symmetry code: i-1-x, 2-y, -1-z; ⅱ-2-x, 2-y, -1-z
C23-H23…Cg2ⅲ: 0.280 5 nm, 150°; Symmetry code: ⅲ-1+x, 1+y, z
H2Brsth: λex 405 nm, λem 475 nm; 1: λex 443 nm, λem 525 nm