Citation: SUN Yin-Xia, LI Chun-Yu, YANG Cheng-Juan, ZHAO Ya-Yuan, GUO Jian-Qiang, YU Bin. Two Cu (Ⅱ) Complexes with Schiff Base Ligands: Syntheses, Crystal Structures, Spectroscopic Properties, and Substituent Effect[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(2): 327-335. doi: 10.11862/CJIC.2016.034 shu

Two Cu (Ⅱ) Complexes with Schiff Base Ligands: Syntheses, Crystal Structures, Spectroscopic Properties, and Substituent Effect

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China

Corresponding author: SUN Yin-Xia, sun_yinxia@163.com
Received Date: 8 September 2015
Revised Date: 25 November 2015

Figures(11)

Two new Cu (Ⅱ) complexes [Cu (L¹)₂](1) (HL¹=1-(3-((2-hydroxybenzylidene) amino) phenyl) ethanone O-benzyl oxime) and [Cu (L²)₂] (2) (HL² =1-(3-((2-Hydroxy-naphthalen-1-ylmethylene)-amino)-phenyl)-ethanone oxime) have been synthesized and characterized by elemental analyses, IR spectra, UV-Vis spectra, fluorescence measurement and X-ray single crystal diffraction method. X-ray crystallographic analyses have indicated that complexes 1 and 2 have the similar structure, consisting of one Cu (Ⅱ) ion, two ligand units. In the complexes, the Cu (Ⅱ) ion lying on an inversion centre, is four-coordinated in a trans-CuN₂O₂ square-planar geometry by two hydroxy O and two imine N atoms from two symmetry-related N, O-bidentate Schiff base ligands. The supramolecular structures of the two complexes 1 and 2 are also similar two-dimensional supramolecular structure linking by different intermolecular interaction. Complex 1 forms an infinite two-dimensional supramolecular structure by two π…π interaction, while that of complex 2 by intermolecular O-H…N and C-H…π hydrogen bond interactions. The fluorescence property of complex 1 and substituent effects of the two complexes are discussed. CCDC: 1003363, 1; 1043506, 2.
- Cu (Ⅱ) complex,
- crystal structure,
- Schiff base ligand,
- substituent effect
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