Citation: HU Peng, WU Yan-Ni, HUANG Qi-Xiao, LIAN Si-Mian, FU Xing-Hui, HE Gao-Peng, CHEN Xia-Min. Gd (Ⅲ), Tb (Ⅲ) and Dy (Ⅲ) Complexes Based on a Nitronyl Nitroxide Radical: Syntheses, Structures and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(2): 297-304. doi: 10.11862/CJIC.2016.032 shu

Gd (Ⅲ), Tb (Ⅲ) and Dy (Ⅲ) Complexes Based on a Nitronyl Nitroxide Radical: Syntheses, Structures and Magnetic Properties

College of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing, Guangdong 526061, China

Corresponding author: HU Peng, hp8286799@zqu.edu.cn
Received Date: 20 June 2015
Revised Date: 1 December 2015

Figures(9)

One novel nitronyl nitroxide radical and its three mononuclear tri-spin compounds Ln (hfac)₃(NIT-Ph-4-OCHCH₃CH₃)₂ (Ln=Gd (1), Tb (2), Dy (3); hfac=hexafluoroacetylacetonate; NIT-Ph-4-OCHCH₃CH₃=2-(4-isopropoxyphenyl)-4, 4, 5, 5-tetramethyl-imidazoline-1-oxyl-3-oxide) have been successfully prepared and characterized. Single crystal X-ray crystallographic analyses reveal that complexes 1, 2, and 3 shows similar radical-Ln (Ⅲ)-radical structures, which ar composed of one Ln (hfac)₃ units and two NIT-Ph-4-OCHCH₃CH₃ radicals. Magnetic studies reveal that ferromagnetic interactions (between intramolecular Ln and radical) and antiferromagnetic interactions (between the intramolecular radicals) are coexist in these complexes. CCDC: 985443, 1; 1043098, 2; 985444, 3.
- nitronyl nitroxide radical,
- lanthanides,
- crystal structure,
- magnetic properties
1. [1]
  Kahn O. Molecular Magnetism. New York: Wiley-VCH, 1993.
2. [2]
  Moller S, Perlov C, Jackson W, et al. Nature, 2003, 426:166-169 doi: 10.1038/nature02070
3. [3]
  Kahn M L, Sutter J P, Golhen S, et al. J. Am. Chem. Soc., 2000, 122:3413-3421 doi: 10.1021/ja994175o
4. [4]
  Zhang P, Guo Y N, Tang J K. Coord. Chem. Rev., 2013, 257: 1728-1737 doi: 10.1016/j.ccr.2013.01.012
5. [5]
  Ruiz-Molina D, Mas-Torrent M, Gómez J, et al. Adv. Mater., 2003, 15:42-49 doi: 10.1002/(ISSN)1521-4095
6. [6]
  Clemente-León M, Soyer H, Coronado E, et al. Angew. Chem. Int. Ed., 1998, 37:2842-2845 doi: 10.1002/(ISSN)1521-3773
7. [7]
  Cornia A, Fabretti A C, Pacchioni M, L, et al. Angew. Chem. Int. Ed., 2003, 42:1645-1651 doi: 10.1002/anie.200350981
8. [8]
  Gatteschi D, Caneschi A, Pardi L, et al. Science, 1994, 265: 1054-1058 doi: 10.1126/science.265.5175.1054
9. [9]
  Bar A K, Pichon C, Gogoi N, et al. Chem. Commun., 2015, 51:3616-3619 doi: 10.1039/C4CC10182K
10. [10]
  Liu R N, Li L C, Wang X L, et al. Chem. Commun., 2010, 46:2566-2570 doi: 10.1039/b918554b
11. [11]
  Bogani L, Wernsdorfer W. Nat. Mater., 2008, 7:179-183 doi: 10.1038/nmat2133
12. [12]
  Caneschi A, Gatteschi D, Lalioti N, et al. Angew. Chem. Int. Ed., 2001, 40:1760-1793 doi: 10.1002/(ISSN)1521-3773
13. [13]
  Bogani L, Sangregorio C, Sessoli R, et al. Angew. Chem. Int. Ed., 2005, 44:5817-5821 doi: 10.1002/(ISSN)1521-3773
14. [14]
  Bernot K, Luzon J, Bogani L, et al. J. Am. Chem. Soc., 2009, 131:5573-5579 doi: 10.1021/ja8100038
15. [15]
  Liu J L, Wu J Y, Chen Y C, et al. Angew. Chem. Int. Ed., 2014, 53:12966-12970 doi: 10.1002/anie.201407799
16. [16]
  Chatelain L, Walsh J P S, Pecaut J, et al. Angew. Chem. Int. Ed., 2014, 53:13434-13439 doi: 10.1002/anie.201407334
17. [17]
  Zhang P, Zhang L, Wang C. J. Am. Chem. Soc., 2014, 136: 4484-4489 doi: 10.1021/ja500793x
18. [18]
  Poneti G, Bernot K, Bogani L, et al. Chem. Commun., 2007 1807-1809
19. [19]
  Rinehart J D, Fang M, Evans W J, et al. J. Am. Chem. Soc., 2011, 133:14236-14239 doi: 10.1021/ja206286h
20. [20]
  Rinehart J D, Fang M, Evans W J, et al. Nat. Chem., 2011, 3:538-542 doi: 10.1038/nchem.1063
21. [21]
  Chernick E T, Casillas R, Zirzlmeier J, et al. J. Am. Chem. Soc., 2015, 137:857-863 doi: 10.1021/ja510958k
22. [22]
  Mailman A, Winter S M, Wong J W L, et al. J. Am. Chem. Soc., 2015, 137:1044-1049 doi: 10.1021/ja512235h
23. [23]
  Wang X F, Hu P, Li Y G, et al. Chem. Asian J., 2015, 10: 325-330 doi: 10.1002/asia.v10.2
24. [24]
  Zhu M, Hu P, Li Y, et al. Chem. Eur. J., 2014, 20:13356-13364 doi: 10.1002/chem.201403581
25. [25]
  Wang Z X, Zhang X, Zhang Y Z, et al. Angew. Chem. Int. Ed., 2014, 53:11567-11570 doi: 10.1002/anie.201407628
26. [26]
  Ullman E F, Osiecki J H, Boocock D G B, et al. J. Am. Chem. Soc., 1972, 94:7049-7059 doi: 10.1021/ja00775a031
27. [27]
  Sheldrick G M. SHELXS-97: Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.
28. [28]
  Sheldrick G M. SHELXL-97: Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
29. [29]
  Hu P, Zhang C, Gao Y, et al. Inorg. Chim. Acta, 2013, 398: 136-140 doi: 10.1016/j.ica.2012.12.025
30. [30]
  Zhou N, Ma Y, Wang C, et al. Dalton Trans., 2009:8489-8492
31. [31]
  Wang C, Wang Y L, Qin Z X, et al. Inorg. Chem. Commun., 2012, 20:112-117 doi: 10.1016/j.inoche.2012.02.030
32. [32]
  Zhang C X, Chen H W, Wang W M, et al. Inorg. Chem. Commun., 2012, 24:177-181 doi: 10.1016/j.inoche.2012.07.003
33. [33]
  Du F X, Hu P, Gao Y Y, et al. Inorg. Chem. Commun., 2014, 48:166-170 doi: 10.1016/j.inoche.2014.08.035
34. [34]
  Zhang C X, Qiao X M, Kong Y K, et al. J. Mol. Struct., 2015, 108:1348-1354
35. [35]
  Li L L, Liu S, Zhang Y, et al. Dalton Trans., 2015, 44:6118-6125 doi: 10.1039/C4DT03941F
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