Citation: GUO Zheng-Nan, LIU Zheng, WEI Xi, TANG Qun, LI Huan-Lin. Syntheses, Characterization and Properties of Metal-Organic Frameworks based on 1,2,4,5-Benzene Tetracarboxylic Acid or 1,2,4,5-Butane Tetracarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 9-17. doi: 10.11862/CJIC.2016.028 shu

Syntheses, Characterization and Properties of Metal-Organic Frameworks based on 1,2,4,5-Benzene Tetracarboxylic Acid or 1,2,4,5-Butane Tetracarboxylic Acid

GUO Zheng-Nan ^1,2 ,
LIU Zheng ^1,2,*,, ,
WEI Xi ^1,2 ,
TANG Qun ^1,2,*,, ,
LI Huan-Lin ^1,2

1.
Guangxi Key Laboratory of Electrochemical and Magneto-Chemical Functional Materials,Guilin, Guangxi 541004, China
2.
College of Chemical And Biological Engineering,Guilin University Of Technology,Guilin, Guangxi 541004, China

Corresponding author: LIU Zheng, lisa4.6@163.com TANG Qun, tangq@glut.edu.cn
Received Date: 28 July 2015
Revised Date: 16 November 2015

Figures(12)

Three Metal-Organic Frameworks (MOFs) materials, namely, {[Co₅(BETA)₂(OH)₂(H₂O)₂]·10H₂O}_n(1), {[Zn₅(BETA)₂(OH)₂(H₂O)₂]·10H₂O}_n(2) and {[Mn₂(BTCA)(H₂O)₃]·H₂O}_n (3), (H₄BETA=1,2,4,5-benzene tetracarboxylic acid; H₄BTCA=1,2,4,5-butane tetracarboxylic acid), have been solvothermally synthesized, and characterized by X-ray single crystal diffraction, IR spectrum, PL spectrum, and TG/DTG analyses. The results show that the three MOFs belong to monoclinic system, space group P2₁/n. Five-nuclear metal clusters in compound 1 and 2 are linked by BETA^4- ligand to form 3D framework structure, and produce 1D channel with the pore size of 0.990 nm×1.307 nm along the a axis. The framework of compound 3 is consisted of Mn²⁺ ions with BTCA^4- ligands forming 4,8-c network. CCDC: 1409602, 3; 1409603, 2; 1409601, 3.
- MOFs,
- carboxylate ligand,
- synthesis,
- property
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