Citation: LIU Guang-Xiang. Syntheses, Crystal Structures and Luminescent Properties of Zinc (Ⅱ) and Cadmium (Ⅱ) Coordination Polymers Constructed by Aromatic Carboxylates and 1, 3, 5-Tris (imidazol-1-yl) benzene[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 175-183. doi: 10.11862/CJIC.2016.024 shu

Syntheses, Crystal Structures and Luminescent Properties of Zinc (Ⅱ) and Cadmium (Ⅱ) Coordination Polymers Constructed by Aromatic Carboxylates and 1, 3, 5-Tris (imidazol-1-yl) benzene

LIU Guang-Xiang

Key Laboratory of Advanced Functional Materials of Nanjing, Department of Chemistry, Nanjing Xiaozhuang University, Nanjing 211171, China

Received Date: 28 September 2015
Revised Date: 7 November 2015

Figures(9)

Two coordination polymers, namely {[Zn (timb)(BTEC)_0.5]·H₂O}_n (1) and {[Cd (timb)(DPA)] ·H₂O}_n (2), have been obtained by the reaction of metal salt (zinc nitrate or cadmium nitrate), 1, 3, 5-tris (imidazol-1-yl) benzene (timb) with two aromatic carboxylic acids, 1, 2, 4, 5-benzenetetracarboxylic acid (H₄BTEC) and diphenic acid (H₂DPA). They were characterized by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. Complex 1 crystallizes in triclinic, space group P1 with a=0.991 32(9) nm, b=1.018 23(10) nm, c=1.112 45(11) nm, α=81.479 0(10)°, β=65.613 0(10)°, γ=62.318 0(10)°. Complex 2 belongs to monoclinic, space group C2/c with a=2.633 0(2) nm, b=0.841 96(8) nm, c=2.353 5(2) nm, β=98.027 0(10)°. Structural analyses reveal that complex 1 exhibits a novel three-dimensional (3D) (3, 4, 5)-connected framework with an unusual (4.6³·8⁶)₂(4²·8⁴)(6³)₂ topology, whereas complex 2 possesses a one-dimensional (1D) single-wall metal-organic nanotube based on double helical chains. The results show that the nature of metal ions and the carboxylic building blocks play an important role in the formation of complexes with diverse structures. The luminescent properties of two complexes have also been investigated. CCDC: 1422833, 1; 1422832, 2.
- coordination polymer,
- tris (imidazole) ligands,
- polycarboxylate,
- crystal structure,
- luminescence
1. [1]
  Du M, Li C P, Chen M, et al. J. Am. Chem. Soc., 2014, 136: 10906-10909 doi: 10.1021/ja506357n
2. [2]
  Long J R, Yaghi O M. Chem. Soc. Rev., 2009, 38:1213-1214 doi: 10.1039/b903811f
3. [3]
  Liu C S, Yang X G, Hu M, et al. Chem. Commun., 2012, 48: 7459-7461 doi: 10.1039/c2cc31905e
4. [4]
  Chen L, Chen Q, Wu M, et al. Acc. Chem. Res., 2015, 48: 201-210 doi: 10.1021/ar5003076
5. [5]
  Liu K, Shi W, Cheng P. Coord. Chem. Rev., 2015, 289-290: 74-122 doi: 10.1016/j.ccr.2014.10.004
6. [6]
  Zhou H C, Kitagawa S. Chem. Soc. Rev., 2014, 43:5415-5418 doi: 10.1039/C4CS90059F
7. [7]
  Du M, Li C P, Liu C S, et al. Coord. Chem. Rev., 2013, 257: 1282-1305 doi: 10.1016/j.ccr.2012.10.002
8. [8]
  Zhou H C, Long J R, Yaghi O M. Chem. Rev., 2012, 112: 673-674 doi: 10.1021/cr300014x
9. [9]
  Guo X M, Guo H D, Zou H Y, et al. CrystEngComm, 2013, 15:9112-9120 doi: 10.1039/c3ce41623b
10. [10]
  Zhao F H, Jing S, Che Y X, et al. CrystEngComm, 2012, 14: 4478-4485 doi: 10.1039/c2ce25272d
11. [11]
  Shen L, Gray D, Masel R I, et al. CrystEngComm, 2012, 14: 5145-5147 doi: 10.1039/c2ce25780g
12. [12]
  Stock N, Biswas S. Chem. Rev., 2012, 112:933-969 doi: 10.1021/cr200304e
13. [13]
  Guo H D, Guo X M, Zou H Y, et al. CrystEngComm, 2014, 16:7459-7468 doi: 10.1039/C4CE00664J
14. [14]
  Zhou K, Jiang F L, Chen L, et al. Chem. Commun., 2012, 48:12168-12170 doi: 10.1039/c2cc36270h
15. [15]
  Hu F L, Wang S L, Wu B, et al. CrystEngComm, 2014, 16: 6354-6363 doi: 10.1039/c3ce42545b
16. [16]
  Pan M, Su C Y. CrystEngComm, 2014, 16:7847-7859 doi: 10.1039/C4CE00616J
17. [17]
  Ding J G, Yin C, Zheng L Y, et al. RSC Adv., 2014, 4: 24594-24600 doi: 10.1039/c4ra02291b
18. [18]
  Yao X Q, Pan Z R, Hu J S, et al. Chem. Commun., 2011, 47:10049-10051 doi: 10.1039/c1cc12691a
19. [19]
  Li S, Sun W, Wang K, et al. Inorg. Chem., 2014, 53:4541-4547 doi: 10.1021/ic500224m
20. [20]
  Tian Y Q, Zhao Y M, Chen Z X, et al. Chem. Eur. J., 2007, 13:4146-4154 doi: 10.1002/(ISSN)1521-3765
21. [21]
  Phan A, Doonan C J, Uribe-Romo F J, et al. Acc. Chem. Res., 2010, 43:58-67 doi: 10.1021/ar900116g
22. [22]
  Mukherjee S, Samanta D, Mukherjee P S. Cryst. Growth Des., 2013, 13:5335-5343 doi: 10.1021/cg4011967
23. [23]
  Xu Z Z, Sheng T L, Wang Y L, et al. CrystEngComm, 2015, 17:2004-2012 doi: 10.1039/C4CE02551B
24. [24]
  Wang H, Yi F Y, Dang S, et al. Cryst. Growth Des., 2014, 14:147-156 doi: 10.1021/cg4013334
25. [25]
  Hua J A, Zhao Y, Liu Q, et al. CrystEngComm, 2014, 16: 7536-7546 doi: 10.1039/C4CE00835A
26. [26]
  Wang L, Yan Z H, Xiao Z, et al. CrystEngComm, 2013, 15:5552-5560 doi: 10.1039/c3ce40273h
27. [27]
  Sun D, Yan Z H, Blatov V A, et al. Cryst. Growth Des., 2013, 13:1277-1289 doi: 10.1021/cg3017358
28. [28]
  Hauptvogel I M, Bon V, Grünker R, et al. Dalton Trans., 2012, 41:4172-4179 doi: 10.1039/c2dt12072k
29. [29]
  Kim D, Lah M S. CrystEngComm, 2013, 15:9491-9498 doi: 10.1039/c3ce40929e
30. [30]
  Cao T, Peng Y, Liu T, et al. CrystEngComm, 2014, 16: 10658-10673 doi: 10.1039/C4CE01356E
31. [31]
  Li Y W, Li D C, Xu J, et al. Dalton Trans., 2014, 43:15708-15712 doi: 10.1039/C4DT02321H
32. [32]
  Jiang H L, Tatsu Y, Lu Z H, et al. J. Am. Chem. Soc., 2010, 132:5586-5587 doi: 10.1021/ja101541s
33. [33]
  Liu X M, Lin R B, Zhang J P, et al. Inorg. Chem., 2012, 51: 5686-5692 doi: 10.1021/ic300097y
34. [34]
  Han L W, Lu J, Lin Z J, et al. CrystEngComm, 2014, 16: 1749-1754 doi: 10.1039/c3ce42110d
35. [35]
  Kongpatpanich K, Horike S, Sugimoto M, et al. Chem. Commun., 2014, 50:2292-2294 doi: 10.1039/c3cc47954d
36. [36]
  Das M C, Guo Q, He Y, et al. J. Am. Chem. Soc., 2012, 134:8703-8710 doi: 10.1021/ja302380x
37. [37]
  Zhao W, Song Y, Okamura T A, et al. Inorg. Chem., 2005, 44:3330-3336 doi: 10.1021/ic048816e
38. [38]
  Sheldrick G M. SADABS, Program for Empirical Absorption Correction of Area Detector Data, University of Göttingen, Germany, 1996.
39. [39]
  Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, Germany, 1997.
40. [40]
  Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany, 1997.
41. [41]
  Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordinated Compounds. 5th Ed. New York: Wiley & Sons, 1997.
42. [42]
  Zhang S R, Du D Y, Qin J S, et al. Chem. Eur. J., 2014, 20: 3589-3594 doi: 10.1002/chem.v20.13
43. [43]
  Zhang M, Feng G, Song Z, et al. J. Am. Chem. Soc., 2014, 136:7241-7244 doi: 10.1021/ja502643p
44. [44]
  Zhou X, Li P, Shi Z, et al. Inorg. Chem., 2012, 51:9226-9231 doi: 10.1021/ic300661c
45. [45]
  Li L, Fan J, Okamura T A, et al. Supramol. Chem., 2004, 16: 361-370 doi: 10.1080/10610270410001713286
46. [46]
  Coropceanu E B, Croitor L, Siminel A V, et al. Polyhedron, 2014, 75:73-80 doi: 10.1016/j.poly.2014.03.008
47. [47]
  Sie M J, Chang Y J, Cheng P W, et al. CrystEngComm, 2012, 14:5505-5516 doi: 10.1039/c2ce25202c
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