Citation: ZHOU Wei-Nan, ZHAO Hong-Bin, CAI Zhuo-Di, LIAO Jun-Xu, PENG Fei, YAN Wen-Jie, YANG Nian-Fa. Synthesis and Properties of 2, 6-Modified BODIPY Sensitizers for Dye-Sensitized Solar Cells[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 81-88. doi: 10.11862/CJIC.2016.021 shu

Synthesis and Properties of 2, 6-Modified BODIPY Sensitizers for Dye-Sensitized Solar Cells

ZHOU Wei-Nan ^1,2 ,
ZHAO Hong-Bin ^2,*,, ,
CAI Zhuo-Di ³ ,
LIAO Jun-Xu ^2,3 ,
PENG Fei ^1,2 ,
YAN Wen-Jie ² ,
YANG Nian-Fa ¹

1.
College of Chemistry, Xiangtan University, Xiangtan, Hunan 411105, China
2.
School of Chemistry and Environmental Engineering, Dongguan University of Technology, Dongguan, Guangdong 523808, China
3.
Chemical Industry and Engineering Society of Dongguan, Dongguan, Guangdong 523808, China

Corresponding author: ZHAO Hong-Bin, zhaohbhanlf@163.com
Received Date: 20 July 2015
Revised Date: 30 October 2015

Figures(8)

Three novel D-π-A type organic dye sensitizers based on BODIPY derivatives featured with BODIPY as π-conjugate bridge, N-phenylcarbazole linked BODIPY unit with different active positions as electron donor and cyanoacrylic acid as electron acceptor were designed and successfully synthesized. The structures of these synthetic dyes CB1~CB3 were characterized by ¹H, ¹³C NMR and MALDI-TOF-MS. The photophysical properties, electrochemical behaviors and photovoltaic performances of these dyes were measured and the relationships between the structure and property were further studied by density functional theory calculations. The absorption spectral of CB1~CB3 ranged from 420 nm to 600 nm. Their LUMO and HOMO levels were located on about 3.7 eV and 5.2 eV respectively. CB2 exhibited more excellent photovoltaic performance than CB1 and CB3 due to the more planar structure and more suitable conjugation length, which resulting in broad absorption and better intramolecular electron transfer property. Under AM 1.5 (100 mW·cm^-2) irradiation, CB2 sensitized solar cell give 1.49% total photoelectric conversion efficiency with open circuit voltage (V_oc) 550 mV, short-circuit current density (J_sc) 3.71mA·cm^-2 and fill factor (FF) 0.73.
- dye-sensitized solar cells,
- organic dyes,
- photovoltaic performance,
- BODIPY
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