Citation: YANG Fang, DONG Bao-Xia, TANG Meng, LIU Wen-Long. Syntheses, Crystal Structures and Photoluminescence of Two Metal Coordination Polymers Constructed from 2-Mercaptobenzoic Acid and Its in situ Oxidized Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 1-8. doi: 10.11862/CJIC.2016.017 shu

Syntheses, Crystal Structures and Photoluminescence of Two Metal Coordination Polymers Constructed from 2-Mercaptobenzoic Acid and Its in situ Oxidized Ligand

College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, China

Corresponding author: LIU Wen-Long, liuwl@yzu.edu.cn
Received Date: 27 September 2015
Revised Date: 13 November 2015

Figures(5)

Two novel coordination polymers, [Cd(2-mba)(bimb)]_n(1) and [Pb(2-sb)]_n(2) [H₂(2-mba)=2-mercaptobenzoic acid, bimb=4,4-bis(1-imidazolyl)bibenzene, sb^2-=2-sulfinobenzoate] have been solvothermal synthesized and characterized by elemental analysis, IR, powder X-ray diffraction and single crystal X-ray diffraction. Complex 1 features a two-dimensional (2D) net structure in which 1D [Cd(2-mba)]_n chains are interconnected by bimb ligands. In complex 1, the ligand 2-mercaptobenzoic acid was oxidized into 2-sulfinobenzoate under solvothermal conditions via in situ ligand reactions. Complex 2 exhibits a 2D(4, 4)-connected framework bridged with carboxylate and sulfinate groups of 2-sulfinobenzoate ligands. The thermal stabilities and solid state photoluminescent properties of two compounds were also investigated. CCDC: 1056796, 1; 1056797, 2.
- cadmium(Ⅱ),
- lead(Ⅱ),
- coordination polymer,
- solvothermal synthesis in situ,
- crystal structure,
- luminescence
1. [1]
  Furukawa H, Cordova K E, O′Keeffe M, et al. Science, 2013,341:1230444-1-1230444-12 doi: 10.1126/science.1230444
2. [2]
  Cui Y, Yue Y, Qian G, et al. Chem. Rev., 2012,112:1126- 1162 doi: 10.1021/cr200101d
3. [3]
  Dang D B, An B, Bai Y, et al. Chem. Commun., 2013,49: 243-2245 doi: 10.1039/C2CC36316J
4. [4]
  Liu L J, Telfer S G. J. Am. Chem. Soc., 2015,37:3901-3909
5. [5]
  Sun H L, Wang Z M, Gao S. Coord. Chem. Rev., 2010,54: 1081-1100
6. [6]
  Adarsh N N, Kumar D K, Dastidar P. CrystEngComm, 2009, 11:796-802 doi: 10.1039/b816221b
7. [7]
  Zheng S T, Wu T, Chou C T, et al. J. Am. Chem. Soc., 2012,134:4517-4520 doi: 10.1021/ja2118255
8. [8]
  Khan N A, Jhung S H. Angew. Chem. Int. Ed., 2012,51: 1224-1227
9. [9]
  Ren Y X, Zheng X J, Jin L P. CrystEngComm, 2011,13: 5915-5923 doi: 10.1039/c1ce05303e
10. [10]
  Wang J, Wang J G, Li X H, et al. Transition Met. Chem., 2013,38:765-770 doi: 10.1007/s11243-013-9747-z
11. [11]
  Sun L, Miyakai T, Seki S, et al. J. Am. Chem. Soc., 2013, 135:8185-8188 doi: 10.1021/ja4037516
12. [12]
  Casarin M, Devic T, Famengo A, et al. Inorg. Chem., 2010, 49:4099-4108 doi: 10.1021/ic902076r
13. [13]
  Humphrey S M, Mole R A, McPartlin M, et al. Inorg. Chem., 2005,44:5981-5983 doi: 10.1021/ic050768q
14. [14]
  Chen H W, Fackler J P, Schussler D P, et al. J. Am. Chem. Soc., 1978,100:2370- 2375 doi: 10.1021/ja00476a018
15. [15]
  Humphrey S M, Mole R A, Rawson J M, et al. Dalton Trans., 2004:1670-1678
16. [16]
  Duran N, Clegg W, Cucurull-Sanchez L, et al. Inorg. Chem., 2000,39:4821-4832 doi: 10.1021/ic000223q
17. [17]
  Ma C L, Zhang Q F, Zhang R F, et al. Chem. -Eur. J., 2006, 12:420-428 doi: 10.1002/(ISSN)1521-3765
18. [18]
  Nomiya K, Noguchi R, Kato C. Chem. Lett., 2000:162-163
19. [19]
  Cave D, Gascon J-M, Bond A D, et al. Chem.Commun., 2002:1050 -1051
20. [20]
  Sun D, Liu F J, Huang R B, et al. Inorg. Chem., 2011,50: 12393-12395 doi: 10.1021/ic201746q
21. [21]
  Sun D, Wang D F, Liu F J, et al. CrystEngComm, 2011,13: 2833-2836 doi: 10.1039/c1ce05023k
22. [22]
  Sun D, Luo G G, Zhang N, et al. Inorg. Chem. Commun., 2010,13:306-309 doi: 10.1016/j.inoche.2009.12.011
23. [23]
  Sun D, Yan Z H. Acta Crystallogr. Sect. C, 2012,C68:m229- m232
24. [24]
  Ge S Z, Liu Q, Deng S, et al. J. Inorg. Organomet. Polym., 2013,23:571-578 doi: 10.1007/s10904-012-9814-5
25. [25]
  Wang H, Huo L H, Deng Z P, et al. CrystEngComm, 2012,14:3501-3508 doi: 10.1039/c2ce06584c
26. [26]
  Zheng S L, Tong M L, Yu X L, et al. Dalton Trans., 2001: 586-592
27. [27]
  Begum R A, Farah A A, Hunter H N, et al. Inorg. Chem., 2009,48:2018-2027 doi: 10.1021/ic801898t
28. [28]
  Li F Y, Xu L, Gao G G, et al. Dalton Trans., 2007:1661- 1664
29. [29]
  Fan J, Hanson B E. Chem. Commun., 2005:2327-2329
30. [30]
  Jackson W G, Rahman A F M M. Inorg. Chem., 2003,42: 383-388 doi: 10.1021/ic020207o
31. [31]
  Yue C Y, Lin Z Z, Chen L F, et al. J. Mol. Struct., 2005, 779:6-22
32. [32]
  SADABS, SMART and SAINT, Bruker AXS Inc., Madison, Wisconsin, USA, 2003.
33. [33]
  APEX2, Bruker AXS Inc., Madison, Wisconsin, USA, 2005.
34. [34]
  Sheldrick G M. Acta Crystallogr., 2008,A64:112-122
35. [35]
  Marandi F, Mirtamizdoust B, Soudi A A, et al. Inorg. Chem. Commun., 2007,10:174-177 doi: 10.1016/j.inoche.2006.10.017
36. [36]
  Mao J G, Wang Z, Clearfield A. Inorg. Chem., 2002,41: 6106-6111 doi: 10.1021/ic020396a
37. [37]
  Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. 5th Ed. Part B. New York: John Willey & Sons, 1997.
38. [38]
  Higashi L S, Lundeen M, Hilti E, et al. Inorg. Chem., 1977,16:310-313 doi: 10.1021/ic50168a017
39. [39]
  Liu W L, Ye L H, Liu X F, et al. CrystEngComm, 2008,10: 395-1403
40. [40]
  Zhang L, Qin Y Y, Li Z J, et al. Inorg. Chem., 2008,47: 8286-8293 doi: 10.1021/ic800871r
41. [41]
  Blasse G, Grabmaier B C. Luminescent Materials. Berlin: Springer Verlag, 1994:134-135
1. [1]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
2. [2]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
3. [3]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
4. [4]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
5. [5]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
6. [6]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
7. [7]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
8. [8]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
9. [9]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
10. [10]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
11. [11]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
12. [12]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
13. [13]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
14. [14]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
15. [15]
  Xin Dong , Tianqi Chen , Jing Liang , Lei Wang , Huajie Wu , Zhijin Xu , Junhua Luo , Li-Na Li . Structure design of lead-free chiral-polar perovskites for sensitive self-powered X-ray detection. Chinese Journal of Structural Chemistry, 2024, 43(6): 100256-100256. doi: 10.1016/j.cjsc.2024.100256
16. [16]
  Huijie An , Chen Yang , Zhihui Jiang , Junjie Yuan , Zhongming Qiu , Longhao Chen , Xin Chen , Mutu Huang , Linlang Huang , Hongju Lin , Biao Cheng , Hongjiang Liu , Zhiqiang Yu . Luminescence-activated Pt(Ⅳ) prodrug for in situ triggerable cancer therapy. Chinese Chemical Letters, 2024, 35(7): 109134-. doi: 10.1016/j.cclet.2023.109134
17. [17]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
18. [18]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
19. [19]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
20. [20]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(288)
HTML views(73)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142