Citation: XU Han, ZHENG He-Gen. Syntheses, Crystal Structures and Properties of Two Cobalt (Ⅱ) Complexes Based on 4, 4′-Bis (imidazol-l-yl)-diphenyl Thioether[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 184-190. doi: 10.11862/CJIC.2016.016 shu

Syntheses, Crystal Structures and Properties of Two Cobalt (Ⅱ) Complexes Based on 4, 4′-Bis (imidazol-l-yl)-diphenyl Thioether

XU Han ^1,2 ,
ZHENG He-Gen ^2,*,,

1.
School of Chemistry and Chemical Engineering, Huangshan University, Huangshan, Anhui 245041, China
2.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China

Corresponding author: ZHENG He-Gen, zhenghg@nju.edu.cn
Received Date: 4 October 2015
Revised Date: 6 November 2015

Figures(11)

Two coordination polymers {[Co (BIDPT)(oba)(H₂O)₂]}_n (1) and {[Co (BIDPT)(p-bdc)]·H₂O}_n (2) were synthesized by hydrothermal method using 4, 4′-bis (imidazol-l-yl) diphenyl thioether (BIDPT), 4, 4′-oxydibenzoic acid (H₂oba), terephthalic acid (p-H₂bdc) and Co (NO₃)₂·6H₂O. The complexes were characterized by FT-IR, elemental analysis, thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD) and their crystal structures were determined by single-crystal X-ray diffraction. Structural analyses reveal that complex 1 crystallizes in the monoclinic system, space group P2/c. Complex 2 crystallizes in the triclinic system, space group P1. Complexes 1 and 2 exhibit a two-dimensional (2D) corrugated layer structures. Through intermolecular hydrogen bonding, the two compounds are assembled into 3D supramolecular structures. Ultraviolet spectroscopy studies revealed that the two compounds exhibit ultraviolet adsorption in the solid state at room temperature. CCDC: 1058936, 1; 1420850, 2.
- Co (Ⅱ) coordination polymer,
- crystal structure,
- optical property,
- synthesis
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