Citation: WANG Hui-Sheng, YUE Lin, PAN Min, ZHONG Wen-Da, TU Wei, PAN Zhi-Quan. Synthesis, Crystal Structure and Magnetic Properties of a Heptanuclear Mn Complex with 2-(Hydroxymethyl) pyridine and 1, 1, 1-Tris (hydroxymethyl) ethane Mixed-Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 153-160. doi: 10.11862/CJIC.2016.012 shu

Synthesis, Crystal Structure and Magnetic Properties of a Heptanuclear Mn Complex with 2-(Hydroxymethyl) pyridine and 1, 1, 1-Tris (hydroxymethyl) ethane Mixed-Ligands

School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Key Laboratory for Green Chemical Process of Ministry of Education, Wuhan 430074, China

Corresponding author: PAN Zhi-Quan, wangch198201@163.com
Received Date: 2 September 2015
Revised Date: 4 November 2015

Figures(8)

One heptanuclear Mn cluster [Mn₃^ⅡMn₄^Ⅲ(Cl)₆(hmp)₆(thme)₂]·H₂O·3CH₃CN (1·H₂O·3CH₃CN, hmpH=2-(hydroxymethyl) pyridine and thmeH₃=1, 1, 1-tris (hydroxymethyl) ethane) has been synthesized by the reaction of MnCl₂·4H₂O, hmpH and thmeH₃ in MeCN. The complex was characterized by single crystal X-ray diffraction, elemental analyses, IR and magnetic investigation. Complex 1·H₂O·3CH₃CN crystallizes in the monoclinic space group I2/a and its core can be viewed as a Mn₆ hexagon of alternating Mn^Ⅱ and Mn^Ⅲ ions surrounding a central Mn^Ⅲ ion, which has previously not been seen for this topology. Magnetic studies reveal that overall ferromagnetic coupling between Mn^Ⅲ and Mn^Ⅱ or Mn^Ⅲ ions within 1·H₂O are present and weak frequency dependence of the ac-susceptibility was found. CCDC: 1045766.
- heptanuclear Mn complex,
- mixed-chelating ligand,
- multidentate chelating ligand,
- crystal structure,
- magnetic property
1. [1]
  Bagai R, Christou G. Chem. Soc. Rev., 2009, 38:1011-1026 doi: 10.1039/b811963e
2. [2]
  Milios C J, Inglis R, Vinslava A, et al. J. Am. Chem. Soc., 2007, 129:12505-12511 doi: 10.1021/ja0736616
3. [3]
  Coronado E, Forment-Aliaga A, Gaita-Arino A, et al. Angew. Chem., Int. Ed., 2004, 45:6152-6156
4. [4]
  Nicholas C H, Milissa A B, Wolfgang W, et al. Inorg. Chem., 2003, 42:7067-7076 doi: 10.1021/ic0348906
5. [5]
  Saha A, Thompson M, Abboud K A, et al. Inorg. Chem., 2011, 50:10476-10485 doi: 10.1021/ic201683p
6. [6]
  Schray D, Abbas G, Lan Y, et al. Angew. Chem., Int. Ed., 2010, 49:5185-5188 doi: 10.1002/anie.201001110
7. [7]
  Blagg R J, Ungur L, Tuna F, et al. Nat. Chem., 2013, 5:673-678 doi: 10.1038/nchem.1707
8. [8]
  ZHANG Lu, ZENG Su-Yuan, LIU Tao, et al. Chinese J. Inorg. Chem., 2015, 31(9): 1761-1773
9. [9]
  Le Roy J J, Ungur L, Korobkov I, et al. J. Am. Chem. Soc., 2014, 136:8003-8010 doi: 10.1021/ja5022552
10. [10]
  Zhu Y Y, Cui C, Zhang Y Q, et al. Chem. Sci., 2013, 4:1802-1806
11. [11]
  Stamatatos T C, Christou G. Inorg. Chem., 2009, 48:3308-3322 doi: 10.1021/ic801217j
12. [12]
  Stamatatos T C, Poole K M, Abboud K A, et al. Inorg. Chem., 2008, 47:5006-5021 doi: 10.1021/ic800268z
13. [13]
  Stamatatos T C, Foguet-Albiol D, Poole K M, et al. Inorg. Chem., 2009, 48:9831-9845 doi: 10.1021/ic901393m
14. [14]
  Zaleski C M, Depperman E C, Dendrinou-Samara C, et al. J. Am. Chem. Soc., 2005, 127:12862-12872 doi: 10.1021/ja050951i
15. [15]
  Brechin E K, Soler M, Christou G, et al. Chem. Commun., 2003:1276-1277
16. [16]
  Colacio E, Ruiz J, Mota A J, et al. Inorg. Chem., 2012, 51: 5857-5868 doi: 10.1021/ic3004596
17. [17]
  Chandrasekhar V, Bag P, Kroener W, et al. Inorg. Chem., 2013, 52:13078-13086 doi: 10.1021/ic4019025
18. [18]
  Stamatatos T C, Foguet-Albiol D, Lee S C, et al. J. Am. Chem. Soc., 2007, 129:9484-9499 doi: 10.1021/ja072194p
19. [19]
  Stamatatos T C, Luisi B S, Moulton B, et al. Inorg. Chem., 2008, 47:1134-1144 doi: 10.1021/ic7020269
20. [20]
  Milios C J, Vinslava A, Whittaker A G, et al. Inorg. Chem., 2006, 45:5272-5274 doi: 10.1021/ic0606678
21. [21]
  Wang H S, Zhang Z C, Song X J, et al. Dalton Trans., 2011, 40:2703-2706 doi: 10.1039/c0dt01588a
22. [22]
  WANG Hui-Sheng. Chinese J. Inorg. Chem., 2014, 30(3):522-528
23. [23]
  Wang H S, Song Y. Inorg. Chem. Commun., 2013, 35:86-88 doi: 10.1016/j.inoche.2013.05.016
24. [24]
  SAINT-Plus, Version 6.02, Bruker Analytical X-ray System: Madison, WI, 1999.
25. [25]
  Sheldrick G M. SADABS: An Empirical Absorption Correction Program, Bruker Analytica X-ray Systems: Madison, WI, 1996.
26. [26]
  Sheldrick G M. SHELXTL-97, University of G?ttingen, Göttingen, Germany, 1997.
27. [27]
  Zhang Z M, Yao S, Li Y G, et al. Chem. Commun., 2013, 49: 2515-2517 doi: 10.1039/c3cc38981b
28. [28]
  Borrás-Almenar J J, Clemente-Juan J M, Coronado E, et al. Inorg. Chem., 1999, 38:6081-6088 doi: 10.1021/ic990915i
29. [29]
  Shores M P, Sokol J J, Long J R. J. Am. Chem. Soc., 2002, 124:2279-2292 doi: 10.1021/ja011645h
30. [30]
  Scott R T W, Parsons S, Murugesu M, et al. Angew. Chem., Int. Ed., 2005, 44:6540-6543 doi: 10.1002/(ISSN)1521-3773
31. [31]
  Murugesu M, Habrych M, Wernsdorfer W, et al. J. Am. Chem. Soc., 2004, 126:4766-4767 doi: 10.1021/ja0316824
32. [32]
  Chen S Y, Beedle C C, Gan P R, et al. Inorg. Chem., 2012, 51:4448-4457 doi: 10.1021/ic2019154
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