Citation: FENG Yong-Lan, FANG Jing-Xian, LIU Chao, WU Xu-Meng, XU Meng, JIANG Wu-Jiu, YU Jiang-Xi, TAN Yu-Xing, KUANG Dai-Zhi. 3, 5-Dichlorosalicylaldehyde-o-rhodamine B Hydrazone: Synthesis and Highly Selective Recognition for Cu²⁺[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 56-62. doi: 10.11862/CJIC.2016.006 shu

3, 5-Dichlorosalicylaldehyde-o-rhodamine B Hydrazone: Synthesis and Highly Selective Recognition for Cu²⁺

1.
Department of Chemistry and Material Science, Key Laboratory of Functional Organometallic Materials of Hunan Provincial College; Hengyang Normal University, Hengyang, Hunan 421008, China
2.
Department of Chemistry and Life Science, Xiangnan University, Chenzhou, Hunan 423043, China

Corresponding author: FENG Yong-Lan, hnhyfyl@163.com
Received Date: 29 June 2015
Revised Date: 4 October 2015

Figures(10)

A novel colorimetric probe, 3, 5-dichlorosalicylaldehyde-o-rhodamine B hydrazone (L), for Cu²⁺ was designed, synthesized. Its structure was characterized with IR, ¹H NMR, ¹³C NMR, elemental analysis and X-ray crystal diffraction. The binding property of the probe with Cu²⁺ was examined by UV-Vis spectroscopy. The result showed in acetonitrile/methenamine (pH 5.6) buffer system, when Cu²⁺ was added to the solution of 3, 5-dichloro-salicylaldehyde-o-rhodamine B hydrazone, a dramatic color change from colorless to rose red was observed, while the other metal ions did not cause noticeable changes, which indicates that 3, 5-dichlorosalicylaldehyde-o-rhodamine B hydrazone had a high sensitivity single selectivity colorimetric recognition for Cu²⁺. The detection limit for Cu²⁺ was 9.30×10^-8 mol·L^-1 by UV-Vis spectroscopy.
- 3, 5-dichlorosalicylaldehyde-o-rhodamine B hydrazone,
- crystal structure,
- copper ion,
- recognition
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沈阳化工大学材料科学与工程学院沈阳 110142

3, 5-Dichlorosalicylaldehyde-o-rhodamine B Hydrazone: Synthesis and Highly Selective Recognition for Cu2+

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通讯作者: 陈斌, bchen63@163.com

3, 5-Dichlorosalicylaldehyde-o-rhodamine B Hydrazone: Synthesis and Highly Selective Recognition for Cu²⁺