Citation: LIU Mei-Pin, HU Yu-Xiang, DU Hong-Bin. Layered Titanosilicates as Energy Storage Anode Materials for Lithium Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2425-2431. doi: 10.11862/CJIC.2015.315 shu

Layered Titanosilicates as Energy Storage Anode Materials for Lithium Ion Batteries

1.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: DU Hong-Bin,
Received Date: 21 August 2015
Available Online: 13 October 2015
Fund Project: 国家重点基础研究发展计划(No.2011CB808704) (No.2011CB808704)国家自然科学基金(No.21471075) (No.21471075)

Rechargeable lithium-ion batteries (LIBs) have become the dominant power source for portable devices. In search for new and better electrode materials for LIBs for future stationary storage, electronic devices and equipments, people have recently started to look over crystalline ion-exchange materials with open channels that facilitate fast lithium ion transportation through the porous network. Herein, the use of Li-exchanged titanosilicate Na-JDF-L1 with a layered structure as anode materials for LIBs was reported. It shows a discharge capacity of 364 mAh·g^-1 after the 200th cycle with ca. 100% Coulombic efficiency and negligible loss of capacity, comparable with the lithium titanate anode. Furthermore, the incorporation of TiO₂ in Li(Na)-JDF-L1 improves the electrochemical performance of the electrode with better initial Coulombic efficiency and higher rate performance.
- titanosilicates;lithium ion batteries;ion-exchange
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