Citation: LIU Mei-Pin, HU Yu-Xiang, DU Hong-Bin. Layered Titanosilicates as Energy Storage Anode Materials for Lithium Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2425-2431. doi: 10.11862/CJIC.2015.315 shu

Layered Titanosilicates as Energy Storage Anode Materials for Lithium Ion Batteries

1.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: DU Hong-Bin,
Received Date: 21 August 2015
Available Online: 13 October 2015
Fund Project: 国家重点基础研究发展计划(No.2011CB808704) (No.2011CB808704)国家自然科学基金(No.21471075) (No.21471075)

Rechargeable lithium-ion batteries (LIBs) have become the dominant power source for portable devices. In search for new and better electrode materials for LIBs for future stationary storage, electronic devices and equipments, people have recently started to look over crystalline ion-exchange materials with open channels that facilitate fast lithium ion transportation through the porous network. Herein, the use of Li-exchanged titanosilicate Na-JDF-L1 with a layered structure as anode materials for LIBs was reported. It shows a discharge capacity of 364 mAh·g^-1 after the 200th cycle with ca. 100% Coulombic efficiency and negligible loss of capacity, comparable with the lithium titanate anode. Furthermore, the incorporation of TiO₂ in Li(Na)-JDF-L1 improves the electrochemical performance of the electrode with better initial Coulombic efficiency and higher rate performance.
- titanosilicates;lithium ion batteries;ion-exchange
1. [1]
  [1] (a)Tarascon J M, Armand M. Nature, 2001,414:359-367 (b)Choi N S, Chen Z H, Freunberger S A, et al. Angew. Chem. Int. Ed., 2012,51:9994-10024
2. [2]
  [2] (a)Chan C K, Patel R N, O'Connell M J, et al. ACS Nano, 2010,4:1443-1450 (b)Hatchard T D, Dahn J R. J. Electrochem. Soc., 2004,151: A838-A842 (c)Idota Y, Kubota T, Matsufuji A, et al. Science, 1997,276: 1395-1397 (d)Park C M, Sohn H J. Adv. Mater., 2007,19:2465-2466
3. [3]
  [3] (a)Wu Y P, Holze R. J. Solid State Eletrochem., 2003,8:73- 78 (b)Chang J C, Tzeng Y F, Chen J M, et al. Electrochim. Acta, 2009,54:7066-7070
4. [4]
  [4] (a)Jung H G, Jang M W, Hassoun J, et al. Nat. Commum., 2011,2:516 (b)Shen L F, Uchaker E, Zhang X G, et al. Adv. Mater., 2012,24:6502-6506
5. [5]
  [5] Fleischhammer M, Waldmann T, Bisle G, et al. J. Power Sources, 2015,274:432-439
6. [6]
  [6] Fulvio P F, Brown S S, Adcock J, et al. Chem. Mater., 2011, 23:4420-4427
7. [7]
  [7] (a)Schnorr J M, Swager T M. Chem. Mater., 2011,23:646- 657 (b)Goodenough J B, Kim Y. Chem. Mater., 2010,22:587-603 (c)Manthiram A. J. Phys. Chem. Lett., 2011,2:176-178
8. [8]
  [8] (a)Prakash A S, Manikandan P, Ramesha K, et al. Chem. Mater., 2010,22:2857-2863 (b)Wang Y Q, Gu L, Guo Y G, et al. J. Am. Chem. Soc., 2012,134:7874-7879 (c)Li C C, Li Q H, Chen L B, et al. ACS Appl. Mater. Interfaces, 2012,4:1233-1238
9. [9]
  [9] Amine K, Belharouak I, Chen Z, et al. Adv. Mater., 2010, 22:3052-3057
10. [10]
  [10] (a)Koudriachova M V, Harrison N M, de Leeuw S W. Solid State Ionics, 2003,157:35-38 (b)Vu A, Qian Y, Stein A. Adv. Energy Mater., 2012,2:1056 -1085
11. [11]
  [11] (a)Rangappa D, Murukanahally K D, Tomai T, et al. Nano Lett., 2012,12:1146-1151 (b)Ellis B L, Makahnouk W R M, Makimura Y, et al. Nat. Mater., 2007,6:749-753 (c)Recham N, Chotard J N, Dupont L, et al. Nat. Mater., 2010,9:68-74 (d)Barpanda P, Ati M, Melot B C, et al. Nat. Mater., 2011, 10:772-779 (e)Tripathi R, Ramesh T N, Ellis B L, et al. Angew. Chem. Int. Ed., 2010,49:8738-8742
12. [12]
  [12] Patoux S, Masquelier C. Chem. Mater., 2002,14:5057-5068
13. [13]
  [13] Milne N A, Griffith C S, Hanna J V, et al. Chem. Mater., 2006,18:3192-3202
14. [14]
  [14] (a)Roberts M A, Sankar G, Thomas J M, et al. Nature, 1996, 381:401-403 (b)Du H, Fang M, Chen J, et al. J. Mater. Chem., 1996,6: 1827-1830
15. [15]
  [15] (a)Anderson M W, Terasaki O, Oshuna T, et al. Philos. Mag. B, 1995,71:813-841 (b)Lin Z, Rocha J, Brando P, et al. J. Phys. Chem., 1997, 101:7114-7120
16. [16]
  [16] Rubio C, Casado C, Gorgojo P, et al. Eur. J. Inorg. Chem., 2010,1:159-163
17. [17]
  [17] Aurbach D, Zaban A. J. Electroanal. Chem., 1995,393:43- 53
18. [18]
  [18] Cao Y, Xiao L, Ai X, et al. Electrochem. Solid State, 2003, 6:A30-A33
19. [19]
  [19] (a)Tang M, Newman J. J. Electrochem. Soc., 2012,159:A1922 -A1927 (b)Park M S, Kim J H, Jo Y N, et al. J. Mater. Chem., 2011, 21:17960-17966
20. [20]
  [20] Yan N, Wang F, Zhong H, et al. Sci. Rep., 2013,3:1568
21. [21]
  [21] (a)Spotnitz R, Franklin J. J. Power Sources, 2003,113:81- 100 (b)Lee S B, Pyun S I. Carbon, 2002,40:2333-2339 (c)He Y B, Liu M, Huang Z D, et al. J. Power Sources, 2013,239:269-276
22. [22]
  [22] Jouan P Y, Peignon M C, Cardinaud C, et al. Appl. Surf. Sci., 1993,68:595-603
1. [1]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
2. [2]
  Xintong Zhu , Bin Cao , Chong Yan , Cheng Tang , Aibing Chen , Qiang Zhang . Advances in coating strategies for graphite anodes in lithium-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(9): 100096-0. doi: 10.1016/j.actphy.2025.100096
3. [3]
  Jingshuo Zhang , Yue Zhai , Ziyun Zhao , Jiaxing He , Wei Wei , Jing Xiao , Shichao Wu , Quan-Hong Yang . Research Progress of Functional Binders in Silicon-Based Anodes for Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2306006-0. doi: 10.3866/PKU.WHXB202306006
4. [4]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-0. doi: 10.3866/PKU.WHXB202309028
5. [5]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-0. doi: 10.3866/PKU.WHXB202311030
6. [6]
  Ying Li , Yushen Zhao , Kai Chen , Xu Liu , Tingfeng Yi , Li-Feng Chen . Rational Design of Cross-Linked N-Doped C-Sn Nanofibers as Free-Standing Electrodes towards High-Performance Li-Ion Battery Anodes. Acta Physico-Chimica Sinica, 2024, 40(3): 2305007-0. doi: 10.3866/PKU.WHXB202305007
7. [7]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 2408007-0. doi: 10.3866/PKU.WHXB202408007
8. [8]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
9. [9]
  Feng Liang , Desheng Li , Yuting Jiang , Jiaxin Dong , Dongcheng Liu , Xingcan Shen . Method Exploration and Instrument Innovation for the Experiment of Colloid ζ Potential Measurement by Electrophoresis. University Chemistry, 2024, 39(5): 345-353. doi: 10.3866/PKU.DXHX202312009
10. [10]
  Xinyu Liu , Weiran Hu , Zhengkai Li , Wei Ji , Xiao Ni . Algin Lab: Surging Luminescent Sea. University Chemistry, 2024, 39(5): 396-404. doi: 10.3866/PKU.DXHX202312021
11. [11]
  Liangliang Song , Haoyan Liang , Shunqing Li , Bao Qiu , Zhaoping Liu . Challenges and strategies on high-manganese Li-rich layered oxide cathodes for ultrahigh-energy-density batteries. Acta Physico-Chimica Sinica, 2025, 41(8): 100085-0. doi: 10.1016/j.actphy.2025.100085
12. [12]
  Chenyue Huang , Hongfei Zheng , Ning Qin , Canpei Wang , Liguang Wang , Jun Lu . Single-Crystal Nickel-Rich Cathode Materials: Challenges and Strategies. Acta Physico-Chimica Sinica, 2024, 40(9): 2308051-0. doi: 10.3866/PKU.WHXB202308051
13. [13]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
14. [14]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
15. [15]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
16. [16]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
17. [17]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
18. [18]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . Rational Design of Bimetallic Oxide Anodes for Superior Li⁺ Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-0. doi: 10.3866/PKU.WHXB202311005
19. [19]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . Nucleation Regulation and Mechanism of Precursors for Nickel Cobalt Manganese-based Cathode Materials in Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(1): 100009-0. doi: 10.3866/PKU.WHXB202404042
20. [20]
  Xuechen Hu , Qiuying Xia , Fan Yue , Xinyi He , Zhenghao Mei , Jinshi Wang , Hui Xia , Xiaodong Huang . Electrochemical Characteristics of LiNbO₃ Anode Film and Its Applications in All-Solid-State Thin-Film Lithium-Ion Battery. Acta Physico-Chimica Sinica, 2024, 40(2): 2309046-0. doi: 10.3866/PKU.WHXB202309046

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(496)
HTML views(133)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142