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Citation: HAN Li-Min, ZHAO Rui-Xia, WU Le, GAO Yuan-Yuan, ZHU Ning, SU Qian, HONG Hai-Long, SUO Quan-Ling. Structural Stability of Ferracyclopentadiene Complex (μ2, η4-C4Ph4)Fe2(CO)6[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2349-2357. doi: 10.11862/CJIC.2015.312 shu

Structural Stability of Ferracyclopentadiene Complex (μ2, η4-C4Ph4)Fe2(CO)6

  • 1.

    College of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China

  • Corresponding author: SUO Quan-Ling, 
  • Received Date: 24 June 2015
    Available Online: 22 September 2015

    Fund Project: 国家自然科学基金(No.21266019, 21062011)资助项目。 (No.21266019, 21062011)

  • The crystal structures of hexa-carbonyl-di-iron complex with ferratetraphenyl cyclopentadiene ring (μ2, η4-C4Ph4)Fe2(CO)6 (1) and tetraphenyl substituted cyclopentadienone ligand (Ph4C4CO) (2) were characterized by spectroscopic determination and X-ray single crystal diffraction technique. The decomposition products and process of ferrole complex 1 were studied by FTIR, using sun light and xenon lamp with four filters as light source, respectively. The results show the light decomposition rate of ferrole complex 1 relates to light source and wavelength. The decomposition rate of sun light source is the fastest, and the decomposition rate of whole wavelength (320~780 nm) is correspondingly faster than that of other wavelengths under irradiation of the same xenon lamp. Ligand 2 is the main product from three decomposition reactions of ferrole complex 1 in the presence of light, heat and Br2 in acetic acid, respectively.
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