Citation: WANG Gui-Xian, CAO Ke-Li, XIA Yan, FENG Yun-Long. Syntheses and Crystal Structures of Mn(Ⅱ) and Ca(Ⅱ) Coordination Polymers Based on 5-(4-(2,6-Di(pyrazin-2-yl)pyridin-4-yl)phenoxy)isophthalic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2337-2342. doi: 10.11862/CJIC.2015.311
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Two new metal-organic coordination polymers {[MnL]·0.5H2O}n (1),{[CaL(H2O)2]·H2O}n (2) (H2L=5-(4-(2,6-di(pyrazin-2-yl)pyridin-4-yl)phenoxy)isophthalic acid) have been synthesized under solvothermal reaction and characterized by single crystal X-ray diffraction analysis. 1 features a novel 3D supramolecular network built by different monochiral sheets with (3,3)-connected 2D net. 2 displays a 1D inorganic-chain linked by carboxylate oxygen atoms of L2- with Ca(Ⅱ) ions. Thermogravimetric analyses (TGA) have been measured for 1 and 2. Luminescent properties of 2 were investigated.
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