Citation: GUO Hai-Fu, LEI Jia-Mei, MA De-Yun. Syntheses, Crystal Structures and Fluorescent Properties of Two 2D Cadmium(Ⅱ) Coordination Polymers[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2385-2392. doi: 10.11862/CJIC.2015.307 shu

Syntheses, Crystal Structures and Fluorescent Properties of Two 2D Cadmium(Ⅱ) Coordination Polymers

GUO Hai-Fu ^1,, ,
LEI Jia-Mei ^1,2 ,
MA De-Yun ¹

1.
1 College of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing, Guangdong 526061, China;
2.
2 Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051, China

Corresponding author: GUO Hai-Fu,
Received Date: 14 July 2015
Available Online: 9 October 2015
Fund Project: 广东省自然科学基金(No.2015A030310407) (No.2015A030310407) 粤西林产化工技术开发与应用研究中心项目(No. 2014KTSPT040)资助。 (No. 2014KTSPT040)

Two new 2D cadmium(Ⅱ) coordination polymers, [Cd₂(FDCA)₂(DMA)₂(DMF)]_n (1) and [Cd₃(FDC)₃(DMF)₄(H₂O)]_n (2) (H₂FDC=2,5-furandicarboxylic acid, DMA=N, N-dimethylacetamide, DMF=N, N-dimethylformamide), have been successfully synthesized under solvothermal conditions and characterized by elemental analysis, IR-spectroscopy, thermogravimetric analysis, and single-crystal X-ray diffraction. The results reveal that both complexes 1 and 2 form 2D net structures, which are further linked to form 3D supramolecular structures via intermolecular C-H…O hydrogen bonding interactions. In solid state, 1 and 2 emit the intensely indigotin photoluminescence (501 and 476 nm) at room temperature.
- solvothermal syntheses;cadmium ions;crystal structure;characterization;photoluminescence
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