Citation: LIU Jia-Bin, ZHANG Hui, CUI Yan-Hua, LIU Xiao-Jiang, LIU Jin-Song. Pulsed Laser Deposited NiCo₂S₄ Thin Films and Investigation of Their Electrochemical Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2331-2336. doi: 10.11862/CJIC.2015.306 shu

Pulsed Laser Deposited NiCo₂S₄ Thin Films and Investigation of Their Electrochemical Properties

1.
1 Institute of Electronic Engineering, China Academy of Engineering Physics, Mianyang, Sichuan 621000, China;
2.
2 School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang, Sichuan 621000, China

Corresponding author: CUI Yan-Hua, LIU Xiao-Jiang,
Received Date: 10 March 2015
Available Online: 16 September 2015
Fund Project: 中国工程物理研究院科学技术基金(No.2013A0302014) (No.2013A0302014)中国工程物理研究院超精密加工技术重点实验室基金(No.ZZ13007)资助项目。 (No.ZZ13007)

NiCo₂S₄ thin films have been successfully prepared by pulsed laser deposition. The structural, electrochemical properties and reaction mechanism of the NiCo₂S₄ thin film anodes for lithium ion batteries have been investigated by transmission electron microscopy (TEM), selected-area electron diffraction measurements (SAED), the charge/discharge measurements and cyclic voltammetry (CV). The charge/discharge results suggested that in the range of 0~3.0 V(vs Li⁺/Li), the reversible discharge capacity was 698 mAh·g^-1 at a current density of 3 μA·cm^-2. After 200 cycles, the discharge capacity was 365 mAh·g^-1. Multistep reactions are revealed by the CV data of NiCo₂S₄ thin films. Ex situ TEM results showed that NiCo₂S₄ could react with Li to form Li₂S, Co and Ni during initial discharging and NiS and CoS formed upon charging. The reversible electrochemical reacting occurred between NiS, CoS and Li₂S, Co, Ni during the following cycles. NiCo₂S₄ was believed to be a promising anode material for rechargeable lithium batteries due to its good cycle performance.
- NiCo₂S₄ thin films;pulsed laser deposition;anode;lithium ion batteries
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Pulsed Laser Deposited NiCo₂S₄ Thin Films and Investigation of Their Electrochemical Properties