Citation: HUANG Ting-Hong, YAN Jie, YANG Hu, ZENG Xian-Guang, YANG Yan. Copper(Ⅰ) Coordination Polymers with Extended π…π Interactions: Syntheses, Structures, Characterization and Luminescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2393-2400. doi: 10.11862/CJIC.2015.305 shu

Copper(Ⅰ) Coordination Polymers with Extended π…π Interactions: Syntheses, Structures, Characterization and Luminescent Properties

1.
Material Corrosion and Protection Key Laboratory of Sichuan province, College of Materials and Chemical Engineering, Sichuan University of Science & Engineering, Zigong, Sichuan 643000, China

Corresponding author: HUANG Ting-Hong,
Received Date: 29 May 2015
Available Online: 29 September 2015
Fund Project: 四川理工学院人才引进项目(No.2014RC29) (No.2014RC29)四川省教育厅重点项目(No.15ZA0223) (No.15ZA0223)材料腐蚀与防护四川省重点实验室开放基金 (No.2015CL03)资助。 (No.2015CL03)

Two copper(Ⅰ) coordination polymers, {[Cu₂(4-bpo)₂(CH₃CN)₂(PPh₃)₂](BF₄)₂}_n (1), {[Cu(4-bpo)(CH₃CN)(dppe)_0.5]BF₄}_n (2) (PPh₃=triphenylphosphine, dppe=1,2-bis(diphenyl phosphino)ethane, 4-bpo=2,5-bis(4-pyridyl)-1,3,4-oxadiazole), have been synthesized and characterized by IR, ¹H NMR, ¹⁹F NMR, ¹¹B NMR, elemental analysis and X-ray crystal structure analysis. The structural analysis shows that complexes 1 and 2 consist of diverse and interesting 2D supramolecular structures formed by inter-chain interactions. For 1, π-stacking interactions result in the construction of 1D bilayer chain and 2D supramolecular network. Compound 2 exhibits a 1D ladder-like chain and a 1D+1D→2D/3D supramolecular structure formed by π-stacking interactions. Solid-state emission spectra of complexes 1 and 2 have been studied, displaying the existence of ILCT/MLCT excited states.
- copper(Ⅰ) coordination polymers;crystal structures;π…π interaction;luminescent properties 0 Introduction
1. [1]
  [1] Doherty S, Knight J G, Ellison J R, et al. Green Chem., 2014, 16(3):1470-1479
2. [2]
  [2] Dronova M S, Bilyachenko A N, Yalymov A I, et al. Dalton Trans., 2014,43(2):872-882
3. [3]
  [3] Hou Y L, Sun R W Y, Zhou X P, et al. Chem. Commun., 2014,50(18):2295-2297
4. [4]
  [4] Jiang L, Wang Z, Bai S Q, et al. Dalton Trans., 2013,42(26): 9437-9443
5. [5]
  [5] Falcaro P, Ricco R, Doherty C M, et al. Chem. Soc. Rev., 2014,43(16):5513-5560
6. [6]
  [6] Mao Y, Su B, Cao W, et al. ACS Appl. Mater. Int., 2014,6 (18):15676-15685
7. [7]
  [7] Sandroni M, Maufroy A, Rebarz M, et al. J. Phys. Chem. C, 2014,118(49):28388-28400
8. [8]
  [8] Dominguez-Martin A, Choquesillo-Lazarte D, Dobado J A, et al. Dalton Trans., 2013,42(17):6119-6130
9. [9]
  [9] Park K H, Noh T H, Shim Y B, et al. Chem. Commun., 2013, 49(38):4000-4002
10. [10]
  [10] Santos-Figueroa L E, Moragues M E, Climent E, et al. Chem. Soc. Rev., 2013,42(8):3489-3613
11. [11]
  [11] Cheng J K, Yao Y G, Zhang J, et al. J. Am. Chem. Soc., 2004,126(25):7796-7797
12. [12]
  [12] Huang T H, Yan J, Liu Y F, et al. Aust. J. Chem., 2015,68 (7):1144-1151
13. [13]
  [13] Huang T H, Yan J, Yang H, et al. J. Mol. Struct., 2015,1101: 66-72
14. [14]
  [14] Zhan S Z, Li M, Zhou X P, et al. Inorg. Chem., 2011,50(18): 8879-8892
15. [15]
  [15] Zhang J, Xiong R G, Chen X T, et al. Organometallics, 2002,21(1):235-238
16. [16]
  [16] Dong Y B, Cheng J Y, Huang R Q, et al. Inorg. Chem., 2003,42(18):5699-5706
17. [17]
  [17] Jin F, Zhang Y, Wang H Z, et al. Cryst. Growth Des., 2013, 13(5):1978-1987
18. [18]
  [18] Wu J Y, Chao T C, Zhong M S. Cryst. Growth Des., 2013,13 (7):2953-2964
19. [19]
  [19] Brozek C K, Dinc M. J. Am. Chem. Soc., 2013,135(34): 12886-12891
20. [20]
  [20] Tu B, Pang Q, Wu D, et al. J. Am. Chem. Soc., 2014,136 (41):14465-14471
21. [21]
  [21] Xu Z, Meng W, Li H, et al. Inorg. Chem., 2014,53(7):3260- 3262
22. [22]
  [22] Hashemi L, Morsali A. CrystEngComm, 2013,15(44):8894- 8897
23. [23]
  [23] Lee L M, Elder P J W, Dube P A, et al. CrystEngComm, 2013,15(37):7434-7437
24. [24]
  [24] Niu C Y, Zheng X F, He Y, et al. CrystEngComm, 2010,12 (10):2847-2855
25. [25]
  [25] Thorp-Greenwood F L, Kulak A N, Hardie M J. Cryst. Growth Des., 2014,14(11):5361-5365
26. [26]
  [26] Du M, Li C P, Liu C S, et al. Coord. Chem. Rev., 2013,257 (7/8):1282-1305
27. [27]
  [27] Han L, Zhou Y, Zhao W N, et al. Cryst. Growth Des., 2009, 9(2):660-662
28. [28]
  [28] Martin D P, Supkowski R M, LaDuca R L. Dalton Trans., 2009:514-520
29. [29]
  [29] Wang X L, Lin H Y, Mu B, et al. CrystEngComm, 2011,13 (6):1990-1997
30. [30]
  [30] Wu Y P, Li D S, Fu F, et al. Inorg. Chem. Commun., 2010, 13(9):1005-1008
31. [31]
  [31] Yuan X, Zhang X, Zhao H, et al. Cryst. Growth Des., 2013,13 (11):4859-4867
32. [32]
  [32] Cao X, Meng L, Li Z, et al. Langmuir, 2014,30(39):11753- 11760
33. [33]
  [33] Das A, Choudhury S R, Dey B, et al. J. Phys. Chem. B, 2010, 114(15):4998-5009
34. [34]
  [34] González-Rodríguez D, Schenning A P H J. Chem. Mater., 2011,23(3):310-325
35. [35]
  [35] Henze W, Gärtner T, Gschwind R M. J. Am. Chem. Soc., 2008,130(41):13718-13726
36. [36]
  [36] Shishkin O V, Zubatyuk R I, Shishkina S V, et al. Phys. Chem. Chem. Phys., 2014,16(14):6773-6786
37. [37]
  [37] Guan Y, Ni M, Hu X, et al. Chem. Commun., 2012,48(68): 8529-8531
38. [38]
  [38] Harada A, Takashima Y, Nakahata M. Acc. Chem. Res., 2014,47(7):2128-2140
39. [39]
  [39] Ji X, Yao Y, Li J, et al. J. Am. Chem. Soc., 2013,135(1):74- 77
40. [40]
  [40] Ogoshi T, Kayama H, Yamafuji D, et al. Chem. Sci., 2012,3 (11):3221-3226
41. [41]
  [41] Zheng B, Wang F, Dong S, et al. Chem. Soc. Rev., 2012,41 (5):1621-1636
42. [42]
  [42] Zou G D, He Z Z, Tian C B, et al. Cryst. Growth Des., 2014, 14(9):4430-4438
43. [43]
  [43] Fang Z L, He J G, Yu R M, et al. CrystEngComm, 2011,13 (20):6243-6250
44. [44]
  [44] Riesgo E C, Hu Y Z, Bouvier F, et al. Inorg. Chem., 2001, 40(14):3413-3422
45. [45]
  [45] Zhang L, Li B, Su Z. Langmuir, 2009,25(4):2068-2074
46. [46]
  [46] Bentiss F, Lagrenée M. J. Heterocycl. Chem., 1999,36(4): 1029-1032
47. [47]
  [47] Du M, Chen S T, Bu X H. Cryst. Growth Des., 2002,2(6): 625-629
48. [48]
  [48] Ma J P, Dong Y B, Huang R Q, et al. Inorg. Chem., 2005, 44(18):6143-6145
49. [49]
  [49] Sheldrick G M. Acta Cryst., 2008,A64:112-122
50. [50]
  [50] Huang T H, Zhang M H, Yan J, et al. Inorg. Chim. Acta, 2015,437:47-53
51. [51]
  [51] Zink D M, Volz D, Baumann T, et al. Chem. Mater., 2013, 25(22):4471-4486
52. [52]
  [52] Du M, Wang Q, Li C P, et al. Cryst. Growth Des., 2010,10 (7):3285-3296
53. [53]
  [53] Li C P, Yu Q, Chen J, et al. Cryst. Growth Des., 2010,10(6): 2650-2660
54. [54]
  [54] Bergmann L, Friedrichs J, Mydlak M, et al. Chem. Commun., 2013,49(58):6501-6503
55. [55]
  [55] Linfoot C L, Leitl M J, Richardson P, et al. Inorg. Chem., 2014,53(20):10854-10861
56. [56]
  [56] Crestani M G, Manbeck G F, Brennessel W W, et al. Inorg. Chem., 2011,50(15):7172-7188
57. [57]
  [57] Hsu C W, Lin C C, Chung M W, et al. J. Am. Chem. Soc., 2011,133(31):12085-12099
1. [1]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
2. [2]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
3. [3]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
4. [4]
  Botao QU , Qian WANG , Qian WANG , Ruiping ZHANG . Synthesis, crystal structures, and luminescence properties of zinc coordination polymers based on 2,5-dibromoterephthalate. Chinese Journal of Inorganic Chemistry, 2026, 42(5): 917-924. doi: 10.11862/CJIC.20260357
5. [5]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
6. [6]
  Ruiying WANG , Hui WANG , Fenglan CHAI , Zhinan ZUO , Benlai WU . Three-dimensional homochiral Eu(Ⅲ) coordination polymer and its amino acid configuration recognition. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 877-884. doi: 10.11862/CJIC.20250052
7. [7]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
8. [8]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
9. [9]
  Kaimin WANG , Na HE , Shiyi LI , Xuling BAI , Weiqing SUN , Yanqing YE , Yulu MA . Synthesis, Hirshfeld surface analysis and properties of two Zn(Ⅱ)/Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 55-64. doi: 10.11862/CJIC.20250178
10. [10]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
11. [11]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258
12. [12]
  Jia JI , Tengqi YAO , Wenqian DENG , Wenjing SHI , Xuan LÜ , Lin TIAN , Xiaoyan XIN , Yinling HOU . Structures, antibacterial activities, and interactions with DNA of two nickel complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 78-86. doi: 10.11862/CJIC.20250141
13. [13]
  Wenjuan SHI , Yuxuan LEI , Lei HOU , Yaoyu WANG . Synthesis, structure, and luminescence properties of trinucluear Cu(Ⅰ)-pyrazole complexes containing different substituent groups. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 543-550. doi: 10.11862/CJIC.20250270
14. [14]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
15. [15]
  Xiaoqi LAN , Wei LI , Long JING , Mengyu SU , Xiaoling LUO , Zheng LIU , Qun TANG . Synthesis, crystal structure, and spectral properties of transition-metal-organic frameworks based on thiophene carboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 309-316. doi: 10.11862/CJIC.20250212
16. [16]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
17. [17]
  Longfei MA , Fang SI , Congjie PAN , Xinhua WANG . Synthesis and crystal structure of extended tetrathiafulvalene derivatives and cupric bromide charge transfer complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(6): 1229-1236. doi: 10.11862/CJIC.20250355
18. [18]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
19. [19]
  Chengyan XU , Jiangnan YU , Yu LI , Xizhen PAN , Yinlin HOU , Wenmin WANG . Synthesis, structure, and bioactivity of a Ho₄ complex bridged by azide group. Chinese Journal of Inorganic Chemistry, 2026, 42(7): 1453-1462. doi: 10.11862/CJIC.20260033
20. [20]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(951)
HTML views(85)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142