Citation: LI Xiao-Jing, WU Wei-Na, XU Zhou-Qing, LI Shou-Jie, ZHAO Liang. Two Cadmium(Ⅱ) Complexes of an Acylhydrazone Ligand Bearing Quinoline Unit: Syntheses, Structures and Fluorescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2265-2271. doi: 10.11862/CJIC.2015.303 shu

Two Cadmium(Ⅱ) Complexes of an Acylhydrazone Ligand Bearing Quinoline Unit: Syntheses, Structures and Fluorescent Properties

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Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Corresponding author: WU Wei-Na, XU Zhou-Qing,
Received Date: 10 July 2015
Available Online: 6 October 2015
Fund Project: 国家自然科学基金(No.21404033,21401046,21001040) (No.21404033,21401046,21001040)河南省教育厅自然科学基金(No.12B150011,14B150029)资助项目。 (No.12B150011,14B150029)

Two complexes [Cd(L)(H₂O)(NO₃)₂] (1) and [Cd(L)I₂]·CH₃OH (2) (L=4-hydroxy-N-((quinolin-8-yl)methylene)benzohydrazide) have been synthesized and structurally determined by single-crystal X-ray diffraction. The results show that the Cd(Ⅱ) ion in 1 with a mono-capped trigonal prismatic geometry is surrounded by one acylhydrazone ligand with N₂O donor set, one water molecule, one mono-dendate and one bidendate nitrate anions. However, the coordination geometry of the Cd(Ⅱ) ion in 1 is a distorted tetragonal pyramid with oxygen and two nitrogen atoms provided by the ligand L and two iodide anions. The thermal stabilities and luminescent properties of both complexes are also investigated in detail.
- quinoline;Cd(Ⅱ) complex;fluorescence;crystal structure;thermostability
1. [1]
  [1] Yang Z Y, Yang R D, Li F S, et al. Polyhedron, 2000,19: 2599-2604
2. [2]
  [2] Yang Z Y, Wang B D, Li Y H. J. Organomet. Chem., 2006, 691:4159-4166
3. [3]
  [3] Zhai Q G, Li S N, Gao X, et al. Inorg. Chem. Commun., 2010,13:211-214
4. [4]
  [4] Wang Y, Yang Z Y. J. Lumin., 2008,128:373-376
5. [5]
  [5] HUANG Chao(黄超), WU Juan(吴娟), CHEN Dong-Mei(陈冬梅), et al. Chinese J. Inorg. Chem.(无机化学学报), 2015, 31:109-113
6. [6]
  [6] Ye X P, Zhu T F, Wu W N, et al. Inorg. Chem. Commun., 2014,47:60-62
7. [7]
  [7] Costes J P, Duhayon C, Vendier L. Inorg. Chem., 2014,53: 2181-2187
8. [8]
  [8] Liu S G, Zuo J L, Li Y Z, et al. J. Mol. Struct., 2004,705: 153-157
9. [9]
  [9] Chandrasekhar V, Azhakar R, Zacchini S, et al. Inorg. Chem., 2005,44:4608-4615
10. [10]
  [10] CHENG Mei-Ling(程美令), CAO Xiang-Qian(曹向前), WANG Chun-Lan(王春兰), et al. Chinese J. Inorg. Chem. (无机化学学报), 2006,22:1222-1226
11. [11]
  [11] Ye X P, Zhu T F, Wu W N, et al. Inorg. Chem. Commun., 2014,47:60-62
12. [12]
  [12] Sheldrick G M. SADABS, University of Göttingen, Germany, 1996.
13. [13]
  [13] Sheldrick G M. SHELX-97, Program for the Solution and the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
14. [14]
  [14] YE Xing-Pei(叶行培), WU Wei-Na(吴伟娜), LI Fei-Fei(李飞飞), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013, 29:2678-2682
15. [15]
  [15] Wang Y, Wu W N, Wang Q, et al. J. Coord. Chem., 2010, 63:147-155
16. [16]
  [16] Addison A W, Rao T N. J. Chem. Soc. Dalton Trans., 1984,5 (11):1349-1356
17. [17]
  [17] YE Xing-Pei(叶行培), WANG Guan-Jie(王冠杰), PAN Peng (潘鹏), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014, 30:2789-2795
18. [18]
  [18] Song X Q, Zang Z P, Liu W S, et al. J. Solid State Chem., 2009,182:841-848
19. [19]
  [19] ZHUO Xin(卓馨), PAN Zhao-Rui(潘兆瑞), WANG Zuo-Wei (王作为), et al. Chinese J. Inorg. Chem.(无机化学学报), 2006,22:1847-1851
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沈阳化工大学材料科学与工程学院沈阳 110142