Citation: ZHANG Qi-Long. Anion-Controlled Assembly of Ag(Ⅰ) Coordination Polymers Based on trans-Bis (benzoylacetone)-1,4-cyclohexanediimine Ligands: Syntheses, Structures, and Solid State Luminescence[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2213-2220. doi: 10.11862/CJIC.2015.295 shu

Anion-Controlled Assembly of Ag(Ⅰ) Coordination Polymers Based on trans-Bis (benzoylacetone)-1,4-cyclohexanediimine Ligands: Syntheses, Structures, and Solid State Luminescence

ZHANG Qi-Long ^,

1.
Department of Chemistry, Guizhou Medical University, Guiyang 550004, China

Corresponding author: ZHANG Qi-Long,
Received Date: 23 July 2015
Available Online: 23 July 2015
Fund Project: 国家自然科学基金(No.21061003) (No.21061003)贵州省科技厅-贵阳医学院联合基金(黔科合LH字[2014]7090) (黔科合LH字[2014]7090)贵州省教育厅青年项目(黔教合KY字[2015])资助。 (黔教合KY字[2015])

Four complexes, {[Ag(L)]NO₃}_n (1), {[Ag(L)(H₂O)]BF₄}_n (2), {[Ag₂(L)₃](SbF₆)₂}_n (3), {[Ag(L)]ClO₄}_n (4), were synthesized by treating chelating ligand trans-bis(benzoylacetone)-1,4-diaminocyclohexane (L) with AgX (X=NO₃^-, BF₄^-, SbF₆^-, ClO₄^-). The structures of these complexes were characterized by elemental analysis, infrared spectroscopy, and X-ray single-crystal diffraction. In the solid state, the ligands in the 2D networks of 1 and 2 exhibited two types of coordination modes: in 1, the CN bonds of the bridging ligand, 1,4-diaminocyclohexane, were axial, while in 2, the CNbonds were equatorial. On the other hand, the ligands in 3 exhibited two types of coordination modes, which formed only 1Dcomplexes. Moreover, the ligands in 4 exhibited only one type of coordination mode, which formed a 2D network. Anions in 2,3 were not coordinated to Ag(Ⅰ); However, 1 and 4 were coordinated to Ag(Ⅰ). Meanwhile, the solid-state fluorescence of ligands and complexes was studied at room temperature.
- ions-controlled;silver coordination polymers;luminescent property;crystal structure
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