Citation: LI Xiao-Jing, XU Zhou-Qing, XU Jun, WU Wei-Na, FAN Yun-Chang. Cu(Ⅱ), Zn(Ⅱ) and Cd(Ⅱ) Complexes with Picolinamide Azine Derived from 2-Acetyl Pyridine and 2-Picolinamide Hydrazone: Crystal Structures and Fluorescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2418-2424. doi: 10.11862/CJIC.2015.292
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Three complexes [(Cu)(L)(Cl)2](1), [(Zn)(L)(Cl)2](2) and {[(Cd)2(L)(I)4]}n(3) (L is derived from 2-acetyl pyridine and picolinamide hydrazone) have been synthesized and characterized by single-crystal X-ray diffraction, elemental analysis and IR spectroscopy. X-ray diffraction analysis results show that complexes 1 and 2 are isostructural. The coordination geometry of the metal ion in each complex is a distorted trigonal biyramid with three nitrogen atoms from the ligand L and two chloride anions. However, in complex 3, two adjacent five-coordinated Cd(Ⅱ) ion are connected by two bridged μ2-I- anions, resulting in the formation of one-dimensional chain along c axis. In addition, the thermal stability and luminescent properties of the complexes are also studied in detail.
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-
[1]
[1] HUANG Chao(黄超), WU Juan(吴娟), CHEN Dong-Mei (陈冬梅), et al. Chinese J. Inorg. Chem. (无机化学学报), 2015,31:109-113
-
[2]
[2] CHEN Yan-Min(陈延民), XIE Qing-Fan(解庆范), LIU Jin- Hua(刘金花), et al. Chinese J. Inorg. Chem. (无机化学学 报), 2015,31:74-80
-
[3]
[3] CHEN Yan-Min(陈延民), CHU Zhao-Hua(储召华), HAO Gui-Xia(郝桂霞), et al. Chinese J. Inorg. Chem. (无机化学 学报), 2015,31:317-322
-
[4]
[4] CHEN Xiao-Hua(陈小华), WU Qiong-Jie(吴琼洁), Lü Wei (吕玮), et al. Chinese J. Inorg. Chem. (无机化学学报), 2013,29:1521-1526
-
[5]
[5] LI Shi-Xiong(李石雄), LIAO Bei-Ling(廖蓓玲), LUO Pei (罗培), et al. Chinese J. Inorg. Chem. (无机化学学报), 2015,31:291-296
-
[6]
[6] Yang Z Y, Yang R D, Li F S, et al. Polyhedron, 2000,19: 2599-2604
-
[7]
[7] Yang Z Y, Wang B D, Li Y H, J. Organomet. Chem., 2006,691:4159-4166
-
[8]
[8] Wang Y, Yang Z Y. Transition Met. Chem., 2005,30:902-906
-
[9]
[9] Zhou X Y, Li P X, Shi Z H, et al. Inorg. Chem., 2012,51: 9226-9231
-
[10]
[10] Wu Z K, Chen Q Q, Yang G Q, et al. Sens. Actuators B, 2004,99:511-515
-
[11]
[11] Zhang G Q, Yang G Q, Zhu L N, et al. Sens. Actuators B, 2006,114:995-1000
-
[12]
[12] Sali S, Grabchev I, Chovelon J M, et al. Spectrochim. Acta A, 2006,65:591-597
-
[13]
[13] Kulatilleke C P, Silva S A, Eliav Y. Polyhedron, 2006,25: 2593-2596
-
[14]
[14] Xu Z Q, Laurence K, Thompson, et al. Inorg. Chem., 1997, 36:3985-3995
-
[15]
[15] Sheldrick G M. SADABS, University of Göttingen, Germany, 1996.
-
[16]
[16] Sheldrick G M. SHELX-97, Program for the Solution and the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
-
[17]
[17] Addison A W, Rao T N. J. Chem. Soc. Dalton Trans., 1984,5:1349-1356
-
[18]
[18] Song X Q, Zang Z P, Liu W S, et al. J. Solid State Chem., 2009,182:841-848
-
[19]
[19] ZHUO Xin (卓馨), PAN Zhao-Rui (潘兆瑞), WANG Zuo- Wei (王作为), et al. Chinese J. Inorg. Chem.( 无机化学学 报), 2006,22:1847-1851
-
[1]
-
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