Citation: XU Han, ZHENG He-Gen. Syntheses, Crystal Structures and Fluorescent Properties of Two Coordination Polymers Based on 4,4'-Bis(imidazol-l-yl)diphenyl Thioether and Phthalic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2272-2278. doi: 10.11862/CJIC.2015.284 shu

Syntheses, Crystal Structures and Fluorescent Properties of Two Coordination Polymers Based on 4,4'-Bis(imidazol-l-yl)diphenyl Thioether and Phthalic Acid

XU Han ^1,2 ,
ZHENG He-Gen ^2,,

1.
1 School of Chemistry and Chemical Engineering, Huangshan University, Huangshan, Anhui 245041, China;
2.
2 State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China

Corresponding author: ZHENG He-Gen,
Received Date: 3 August 2015
Available Online: 11 September 2015
Fund Project: 国家重点基础研究发展计划(No.2010CB923303) (No.2010CB923303)国家自然科学基金(No.21371092) (No.21371092)安徽高校省级自然科学研究基金(No.KJ2013B274)资助项目。 (No.KJ2013B274)

Two coordination polymers {[Zn(BIDPT)(pht)]₂·2H₂O·CH₃OH}_n (1) and {[Cd₅(BIDPT)₄(pht)₅]·H₂O}_n (2) based on mixed-ligands, BIDPT (4,4'-bis(imidazol-l-yl)diphenyl thioether) and H₂pht (phthalic acid), have been synthesized by mild hydrothermal method and characterized by single-crystal X-ray diffraction, elemental analysis, IRspectra. The results show that 1 and 2 feature 2D networks. Compound 1 crystallizes in the orthorhombic system, space group Pbcn. Compound 2 crystallizes in the monoclinic system of the P2₁/c space group. The thermal stability and luminescent properties of compounds 1 and 2 are also investigated.
- coordination polymer;crystal structure;photoluminescence;synthesis
1. [1]
  [1] Zhang C L, Li Y L, Wang T, et al. Chem. Commun., 2015,51: 8338-8341
2. [2]
  [2] Jiang H L, Makal T A, Zhou H C, et al. Coord. Chem. Rev., 2013,257:2232-2249
3. [3]
  [3] Hu Z, Deibert B J, Li J. Chem. Soc. Rev., 2014,43:5815- 5840
4. [4]
  [4] Zhao X, Wang X, Wang S, et al. Cryst. Growth Des., 2012, 12:2736-2739
5. [5]
  [5] Lin Z J, Huang Y B, Liu T F, et al. Inorg. Chem., 2013,52: 3127-3132
6. [6]
  [6] Zhang W, Xiong R G. Chem. Rev., 2011,112:1163-1195
7. [7]
  [7] Liu J, Chen L, Cui H, et al. Chem. Soc. Rev., 2014,43:6011- 6061
8. [8]
  [8] Zheng M X, Gao X J, Zhang C L, et al. Dalton Trans., 2015, 44:4751-4758
9. [9]
  [9] Qin L, Ju Z M, Wang Z J, et al. Cryst. Growth Des., 2014, 14:2742-2746
10. [10]
  [10] Stock N, Biswas S. Chem. Rev., 2011,112:933-969
11. [11]
  [11] Ding R, Huang C, Lu J J, et al. Inorg. Chem., 2015,54:1405-1413
12. [12]
  [12] Shi Z Q, Guo Z J, Zheng H G. Dalton Trans., 2014,43:13250- 13258
13. [13]
  [13] Deng M L, Yang P, Liu X F, et al. Cryst. Growth Des., 2015, 15:1526-1534
14. [14]
  [14] Hu J S, Shang Y J, Yao X Q, et al. Cryst. Growth Des., 2010, 10:4135-4142
15. [15]
  [15] Sheldrick G M. SHELXL-97, Program for Refinement of Crystal Structure, University of Göttingen, Germany, 1997.
16. [16]
  [16] Cui Y J, Yue Y F, Qian G D, et al. Chem. Rev., 2012,112: 1126-1162
17. [17]
  [17] Ju Z M, Cao D P, Qin L, et al. CrystEngComm, 2014,16: 3917-3925
18. [18]
  [18] Wang Z J, Qin L, Zhang X, et al. Cryst. Growth Des., 2015, 15:1303-1310
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