Citation: WANG Zhao-Dong. Syntheses and Structural Characterization of Copper Complexes with Thioether-Containing Pyridylalkylamide Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2243-2248. doi: 10.11862/CJIC.2015.283 shu

Syntheses and Structural Characterization of Copper Complexes with Thioether-Containing Pyridylalkylamide Ligands

WANG Zhao-Dong ^,

1.
Chongqing Key Laboratory of Environmental Materials & Remediation Technologies, Chongqing University of Arts and Sciences, Chongqing 402160, China

Corresponding author: WANG Zhao-Dong,
Received Date: 26 May 2015
Available Online: 16 September 2015
Fund Project: 重庆文理学院人才引进项目(No.R2012CH12) (No.R2012CH12)重庆市教委科学技术研究项目(No.KJ131215)资助。 (No.KJ131215)

Thioether-containing pyridylalkylamide ligands 2-(methylsulfanyl)-N-[2-(pyridine-2-yl)methyl]acetamide (HL1) and 2-(methylsulfanyl)-N-[2-(pyridine-2-yl)ethyl]acetamide (HL2) were synthesized and fully characterized. Three copper complexes {[Cu(L1)(CH₃OH)](OTf)}_n (1), (OTf=triflate), {[Cu(L2)(OTf)]·CH₃OH}_n (2) and [Cu(HL2)(CH₃OH)Cl] (3) were synthesized and characterized with X-ray diffraction methods. The single-crystal X-ray analyses indicate that complex 1 and 2 form 1Dcoordination polymers, while complex 3 is a mononuclear copper complex. The coordination modes of the copper ion are analyzed and the reasons are interpreted.
- pyridylalkylamide ligand;copper complex;coordination polymer
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