Citation: Lotfia El Majdoub, LI Jun, ZHANG Yue-Juan, LI Ni-Li, XU Qing-Hong. Photoelectrode of Polyanilines/n-Si(111) Crystalline: Preparation and Photoelectric Property[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2257-2264. doi: 10.11862/CJIC.2015.282 shu

Photoelectrode of Polyanilines/n-Si(111) Crystalline: Preparation and Photoelectric Property

1.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Corresponding author: XU Qing-Hong,
Received Date: 6 July 2015
Available Online: 31 August 2015
Fund Project: 国家自然科学基金(No.U1362113)资助项目。 (No.U1362113)

The self-assembled monolayers (SAMs) of aniline and alkyl substituted anilines grafted on n-Si(111) crystalline surface were prepared in the presence of lauroyl peroxide, and the photoelectrodes of polyanilines/n-Si(111) crystalline were prepared based on polymerizations between the SAMs and anilines. Additionally, the polyanilines with sulfonic acid group (SPANI) substituted n-Si(111) crystalline photoelectrodes were prepared via the above samples to fabricate SPANI/n-Si(111) electrodes (Si-SPANIs). Electrochemical studies indicate that the electrode based on 4-bromoaniline (Si-PANI) is better than that of 4-ethynylaniline (Si-C=C-PANI), and the electrode from 4-vinylaniline (Si-C-C-PANI) is the poorest. In addition, anion ring substitution is important in promoting photoelectric conversion of the electrodes. An electrode with high photocurrent density of 15.4 mA·cm^-2 and photoelectric transformation efficiency of 13% was obtained.
- semiconductors;surface chemistry;thin films;synthesis design;electrochemistry
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